亚胺

The structural characteristics of the ligand of the chiral Schiff base are that the ligand has phenol hydroxyl, alcoholic hydroxyl and an imine group, one to three bromine atoms are provided on the framework of double benzene nucleus, and chiral carbon is connected with the nitrogen atom of imine.

手性西佛碱配体的结构特征为含有酚羟基、醇羟基和亚胺基团，在萘环骨架上带有一至三个溴原子，手性碳与亚胺的氮原子相连。

The present invention discloses the structure and application of one new kind of sulphurous heterocyclic naphthyl imides. The said compounds feature that the naphthyl imide has conjugated plane enlarged via the added five- or six-element aromatic heterocycle and introdued sulphurous heterocyclic atom.

本发明公开一类新的含硫杂环并萘酰亚胺化合物的结构及其用途，本发明所说的化合物的特征是萘酰亚胺的共轭平面通过并入的五元芳杂环得以扩大，并引入含硫杂原子。

The Strecker reactions and the addition reactions with diethylzinc of imines in the presence of organophosphine were also studied.

发现在有机膦的参与下，多种亚胺的Strecker反应和普通亚胺与二乙基锌的加成反应都能顺利的进行。

Recent advances in addition,reduction,and asymmetric reactions of imines were reviewed.

亚胺是一类羰基化合物与氨的缩合产物，作者综述了近年国内外亚胺在加成、还原和不对称反应等方面的研究进展

Thus if we control the reaction temperature at somesolvent we can obtain the products either by the reaction of phosphoryl-stabilizedcarbonanion with N-tosyl imines or by the reaction of methoxycarbonyl-stabilizedcarbanion with N-tosyl imines.

在一定溶剂中，如果控制反应的温度可以控制得到由膦酰基稳定的碳负离子和亚胺反应或由甲氧羰基稳定的碳负离子和亚胺反应。

In the fifth part, asymmetric synthesis of β,γ-trans-alkenyl α-amino esters was achieved by chiral phosphoric acid catalyzed transfer hydrogenation of β,γ-alkynyl α-imino esters. Utilizing Hantzsch ester as the hydrogen donor, both the alkyne and imine moieties of β,γ-alkynyl α-imino esters were reduced to yield β,γ-trans-alkenyl α-amino esters with up to 96% ee.

第五部分工作中，使用手性磷酸作为催化剂，Hantzsch酯作为氢源，β，γ-炔烃取代的α-酮酸酯亚胺中的炔键和亚胺官能团均被还原，以中等的收率和优秀的对映选择性（up to 96% ee）得到β，γ-反式烯烃取代的α-氨基酸衍生物。

The coupling reaction of aryl iodides, bromides and chlorides with differentolefins catalyzed by catalyst 2 and 4 was studied. It was found that compounds 2 and 4 anchored on active carbon are efficient catalyst for the Heck reaction in the case of aryl bromides and aryl chlorides as substrates (Scheme 3). It is notable that catalyst 4 has higher efficiency for aryl chlorides.___^H Cat.2 or 4, Base HXSolution, 100C or 140

以化合物2和4为代表，重点研究了活性炭负载的二茂铁亚胺环钯化合物催化碘代苯、溴代苯和氯代苯与活泼烯烃之间的偶联反应(Scheme 3)，发现活性炭负载的二茂铁亚胺环钯化合物2和4均可用于催化多种溴代和氯

In this thesis, the design, synthesis and application of substituted 1,8-naphthalimides and napthopyrones conjugated with uridine, substituted 1,3,5-triazine, 1,2-dibromoethane, ethyl bromoacetate have been studied.

本论文研究了取代l，8-萘酰亚胺和萘并吡喃酮与尿苷、取代均三嗪、二溴乙烷、溴乙酸乙酯偶合和双l，8-萘酰亚胺之间偶合的设计、合成及应用。

The cyclization of carbodiimides 2 and 6 with phenol or alcohol was studied and the results showed that the cyclization of carbodiimides 2 and 6 with phenol in the presence of solid potassium at room temperature to 40℃, the cyclization of carbodiimides 2 and 6 with alcohol should in the presence of RONa.

进一步研究了碳二亚胺2和6与酚和醇的成环反应，结果表明该碳二亚胺与酚反应在碱(固体K_2CO_3)催化条件下，室温或加热到40℃便可顺利关环，与醇反应需要用到更强的碱醇钠催化才可以顺利关环。

A flocculant polyethyleneimine-sodium xanthogenate was prepared, The effects of PEX on removing copper ions and turbidity of wastewater was studied.

以聚乙烯亚胺和二硫化碳制备聚乙烯亚胺基黄原酸钠，研究了PEX对废水中浊度及铜的去除效果。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。