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Examples are provided by the following preparations: arsenious sulphide from arsenious acid and hydrogen sulphide: gold or silver sols by reduction of the corresponding salts of gold or silver, silver chloride from very dilute solutions of silver nitrate and sodium chloride.

例子由以下准备提供:亚砷硫化物从亚砷酸和氢化硫:金或银sols 由金子或银,银色氯化物对应的盐的减少从非常硝酸银和氯化钠的稀溶液。

In the present study, Hartree-Fock and Density Functional Theory with different basis sets were employed to calculate the structural and thermodynamic parameters of 66 thiophenyl, phenyl sulfoxide and phenylsulfonyl cycloalkane carboxylates. With the statistic software SPSS11.5 for windows and GQSARF2.0, the QSAR models relating physicochemical properties of these compounds to their structural and thermodynamic parameters were successfully obtained, using multiple stepwise regression method. The physicochemical properties observed in this work include octanol/water partition coefficient, chromatographic capacity index, toxicity (EC50 and LC50), and solubility etc.

本文采用从头算方法中的Hartree-Fock 方法、密度泛函理论方法(Density functional theory,简称DFT)中的不同基组,计算了苯硫基、苯亚砜基和苯砜基含硫芳香羧酸酯三类共66 个化合物的结构参数和热力学参数,利用SPSS11.5 for windows 统计软件和GQSARF2.0 软件,采用多元逐步回归法拟合得到与溶质-溶剂相互作用有关的物理化学性质与结构参数和热力学参数之间的QSAR 方程,这些物理化学性质包括辛醇/水分配系数、色谱容量因子、毒性(EC50和LC50)、溶解度等。

The method is based on the oxidation-reduction reaction between potassium iodide and nitrite.

建立了碘化钾与亚硝酸根氧化还原反应生成游离碘使异硫氰酸荧光素荧光猝灭测定痕量亚硝酸根的新方法。

Via the reacher on LJ-1, we know its water solubility is good,without emulsion inclination, has temperature&salt-resistant ability,when it used with Zinc dihydrogen phosphate, sodium sulfite and scale inhibitors, the corrosion inhibitor effectiveness can enhanced,when used with Thiourea the corrosion inhibitor effectiveness can decrease,so it can not used with thiourea.

通过对LJ-1缓蚀剂进行性能评价,发现本品水溶解性较好;无乳化倾向性;具有一定的抗温性和抗盐性;将它与磷酸二氢锌、亚硫酸钠和阻垢剂进行复配时,能提高缓蚀剂的缓蚀效果,说明它的配伍性良好,当与硫脲复配时,它的缓蚀效果有所降低,说明它与硫脲不能复配使用。

The iron sulfide cleaning formulation with the surfactant, allene diamine, citric acid and EDTA as the main ingredients could react rapidly with the iron sulfide to form ethylene and element sulfur in the presence of catalyst.

一种以表面活性剂、丙二烯二胺和柠檬酸、EDTA为主要组分的硫化亚铁清洗配方,在催化剂存在的条件下能迅速与硫化亚铁发生反应,生成乙烯和单质硫。

This thesis includes five parts as follows.1. The backgrounds and some relative concepts of this work are briefly introduced. The photochemistry of benzamides and compounds with thiourea functional group is also concisely reviewed.2. Total of fourteen benzamides with different substituted groups have been synthesized and structurally characterized. Better photoreaction time for that kind of compounds at given concentrations is confirmed by tracking its'UV spectrum and GC chromatogram. A representative dibenzophenone photoproduct has been determined by X-ray crystallography. The mechanisms of photoreaction of benzamide have been proposed.3. Total of seven N-chloro(phenylmethylenebenzenamines with different substituted groups and sixty-one thiourea derivatives have been synthesized and structurally characterized.

论文的主要内容如下:1、简要介绍本论文工作的研究背景,并对苯甲酰胺和具有硫脲官能团类化合物的光化学研究进展进行简要的总结。2、合成与表征了14个具有不同取代基的苯甲酰胺类化合物,利用紫外光谱和气相色谱确定了此类化合物较佳光照时间,测定了一个具有代表性光解产物的单晶结构,提出了苯甲酰胺类化合物的光反应机理。3、合成与表征了7个带有不同取代基的氯代苯甲酰亚胺中间体及61个硫脲衍生物,测定了两个具有代表性化合物的单晶结构。

On the other hand, a method for the synthesis of-vinyl chalcogenides by the coupling of vinyl bromides with thiols or diphenyl diselenide using copper salts as catalysts in ionic liquids based on amino acids also has been described. The ionic liquids play multiple roles in the reaction: they act as solvent, base, and excellent promoter for the copper-catalyzed coupling reactions.

在新型的氨基酸负离子的离子液体中,开发了一个亚铜盐催化的Z-型溴代烯烃与硫族元素的交叉偶联反应,为立体选择性的制备Z-型烯基硫醚或烯基硒醚类化合物提供了一个新的方法;在此反应体系中,离子液体不仅起到了反应溶剂的作用,而且还起到了金属催化剂的配体和中和反应副产物的碱的作用。

The compounds which contain sulfur in the residual oil were oxidized into sulphone and sulphoxide, which were extraced by using the DMF as the extraction agent.

渣油中的含硫化合物被氧化成砜和亚砜,用DMF为萃取剂萃取砜和亚砜。

Bioleaching, by means of natural populations of Thiobacillus ferrooxidans and related Thiobacilli, for example, allows recovery of up to 70% of the copper in low-grade ores.

生物萃取,例如应用天然的氧化亚铁硫杆菌菌群和相关的硫杆菌,使低品级的矿石中铜的收率达到70%。

The individual subunits are not necessarily covalently connected, but might be connected by a disulfide bond.

亚基之间不一定要共价连接,但有一些亚基之间是通过二硫键来连接的。

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Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

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