亚乙烯基

Most importantly, the LUMO energies of PFCN are around 1 eV lower than those of PF, which results in the decrement of EA about 0.9 eV, indicating that the 1,2-bis( p -phenylene)-1-cyanovinylene unit has significantly improved the electron-accepting properties of the copolymer PFCN.

更重要的是，PFCN和PPhCN的最低空轨道比聚芴低近1 eV，直接导致电子亲和势降低0.9 eV。这意味着含氰基亚乙烯基共聚物的电子注入能力大大提高。

From comparison with poly(2,7-fluorenylene), the 1,2-bis( p -phenylene)-1-cyanovi- nylene unit was found to be a good electron-withdrawing moiety for electronic materials and the incorporation of 1,2-bis( p - phenylene)-1-cyanovinylene resulted in a narrow band gap and a red shift of both the absorption and photoluminescence emission peaks.

通过与聚芴对比，发现对于电致发光材料来说，由于氰基的强吸电子能力使得氰基亚乙烯基成为一个很好的吸电子基团，与之结合使得能隙变窄，吸收和发射光谱发生红移。

This article reviews recent progress in nucleophilic reactions of theα- carbon in vinylidene ruthenium complexes.

综述了近几年钌亚乙烯基络合物中间体α碳的亲核反应。

This article reviews recent progress in nucleophilic reactions of the α-carbon in vinylidene ruthenium complexes.

文摘：综述了近几年钌亚乙烯基络合物中间体α-碳的亲核反应。

The present invention relates to a thermoplastic interpolymer product comprising an alpha -olefin interpolymerized with at least one vinyl or vinylidene aromatic monomer and/or at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene aromatic monomer and, in at least one aspect, is characterized as having substantially synergistic thermal properties.

本发明涉及一种包含与至少一种乙烯基或亚乙烯基的芳族单体和/或至少一种受阻的脂族或环脂族的乙烯基或亚乙烯基芳族单体共聚的α－烯烃热塑性共聚体产物，及至少一方面，其特征为具有实质协同热性质。

The chiral polymer P-1 shows strong blue fluorescence due to the extended π-electronic structure between the chiral repeating unit-6,6'-di(4-trifluoromethyl-phenyl)-2,2'-bisoctoxy-1,1'-binaphthyl and the conjugated linker 2,2'-bipyridyl group via vinylene bridge.

手性高分子P-1能发射强的蓝色荧光，这是由于手性重复单元-6，6′-二(4-三氟甲基苯基)-2，2′-二正辛氧基-1，1′-联萘和单元2，2′-联吡啶通过亚乙烯基桥连形成共轭高分子结构造成的。

Compounds were determined from more than 3 stages, including germacrene D, caryophyllene, phenol, 2, 6-bis (1, 1-dimethylethyl)-4-methyl-,β-elemene,γ-elemene, 1-octanol, 2-butyl-, dibutyl phthalate, cyclohexane, 1-ethenyl-1-methyl-2-(1-methylethenyl)-4(1-methylethylidene)-and butyl caprylate.

其中，3个时期以上能检测到相同的化学成分有9种，分别是大牻牛儿烯D、丁香烯、2，6-二叔丁基－4-甲基苯酚、β-榄香烯、γ-榄香烯、2-丁基－1-辛醇、邻苯二甲酸二丁酯、1-乙烯基－1-甲基－2-（1-甲基乙烯基）－4-（1-甲基亚乙烯基）环己烷和辛酸丁酯。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

A new functional electroluminescent copolymer is reported in which chromophores and hexa segments alternate along the polymer backbone.

采用Wittig反应合成了一种分子主链由烷氧基取代的1，4二苯乙烯基苯聚对亚苯基亚乙烯基(PPV的三个单元的齐聚物与柔性隔离链段五缩六乙二醇组成的交替型蓝绿色发光共聚物。

The devices of sandwiched structure were prepared by compounding poly[2-methoxy-5-(2-ethyl-hexyloxy)-l,4-phenylene vinylene] with SiO_2. The thickness of MEH-PPV of these devices are different. We found the suitable frequency of drive voltage to obtain the greatest brightness. The device of cascade structure was prepared based on this work.

采用共轭高分子聚2-甲氧基-5-(2′-乙基-己氧基)-1，4-亚苯基亚乙烯基与SiO_2制成夹层结构器件，研究了不同发光层厚度的器件的发光特性，发现长波峰的发光强度随驱动电压频率的增大而增强、短波峰的发光强度随驱动电压频率的增大而减弱，进一步分析了其机理。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。