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五碘化物

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Polyfluoroalkyl iodides could react with unsaturated olefin acids in the presence of sodium dithionite by radical addition to give adducts. It was found that these adducts could form polyfluoroalkyl substituted γ or δ-lactones due to intramolecular nucleophilic substitution in the alkali solution.

研究发现:多氟烷基碘化物在连二亚硫酸钠存在下与不饱和烯酸经自由基加成得到的产物,能在碱性条件下进行分子内亲核取代反应形成五元或六元环的含氟内酯类化合物。

And Smakula was also involved in the development of crystals grown from solutions in a laboratory environment. By the end of the 1930's he had developed the first KRS five mixed crystal (thallium iodide-thallium bromide) which remains in use in infrared technology applications.

斯马库拉也参与了实验室环境下的人工水晶合成的技术研发,到二十世纪三十年代末,他就研发了第一种五种混合物的KRS混合水晶(含铊、碘化铊、嗅化物等),此种水晶现在还在红外技术中应用。

The oil yield was 28.35% under the optimal conditions. The characters of the oil were: refractive index 1.4681, acid value 9.65 mgKOH/g, iodine value 66.74 g/100 g, peroxide value 14.56 mmol/kg, unsaponifiable matters 1.93%, moisture and volatile matters 0.28%.

最佳条件下超临界CO2萃取的五叶瓜藤种子油的收率为28.35%;油的理化指标为:折光率1.4681、酸值 9.65 mg/g、碘值 66.74/100g、过氧化值14.56 mmol/kg、不皂化物1.93%、水分及挥发物0.28%。

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