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The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法,包括单体合成和聚合物的合成,聚合物的合成是在严格无氧无水条件下,在金属钴配合物三-三苯基磷氯化钴,加入环戊二烯钠单体,随后加入双内炔或双外炔共轭单体,反应后沉淀,过滤,洗涤,真空干燥,得到含环戊二烯茂钴有机金属钴的大分子聚合物。

According to the properties of acrylic acid series polymer of scale inhibition. A kind of amphiprotic tercopolymer of acrylic acid, acrylamide and dimethyldiallylammonium chloride is synthesised, with water as solvent, persulfate and hypophosphate as initiator. Through the tests, the copolymer can show the good scale inhibiting effect and bactericidal action, and become a multifunctional scale inhibition.

本研究根据丙烯酸聚合物阻垢剂的特点,使用过硫酸铵(NH_4_2S_2O_8、次亚磷酸钠(Na_2PO_3)构成的氧化——还原型引发剂,水为溶剂,合成了新型可用于处理工业循环冷却水的丙烯酸—丙烯酰胺—二甲基二烯丙基氯化铵两性型三元共聚物。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物,通过2-氨基-5-(3-吡啶基)-1,3,4-噻二唑与酰基叠氮化物反应,设计合成了7个新的N-[5-(3-吡啶基)-1,3,4-噻二唑-2-基]-N'-取代苯基脲,其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

The article adopted the method of orthogonal design using Polyethylene Glycol and Methacrylic Acid to esterify Polythylene-glycol-mono Methacrylate, then using PMA, MAA and Methacrylic Acid Sulfonic Sodium as raw material to synthesize Polycarboxylic type water-reducer.

用正交实验法研究了聚乙二醇和甲基丙烯酸酯化合成聚乙二醇单甲基丙烯酸酯的合成工艺,以该酯化物与MAA和甲基丙烯酸磺酸钠为原料,在引发剂的作用下合成聚羧酸系减水剂。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist"s attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What"s more, PILM was mainly studied as a catalyst in oil refining process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Pillared montmorillonite, as a representative of Sandwich like pillared interlayered clays ,caught many scientist's attention not only because of its special structure of two-dimensional sheets but also its excellent activity of catalysis and adsorption. It is well documented that the method to prepare PILM, ion-exchanging, needed a long periods and was affected by many factors, and that the product had low thermal stability especially hydro-thermal stability which was the primary obstruction of its using in large-scale production. At the same time, PILM was well documented prepared with Na-montmorillonite, while there were a few documents about PILM prepared with Ca-montmorillonite. The large cost of remodel of Ca-montmorillonite to Na-montmorillonite was another obstacle of the application of PILM, while Ca-montmorillonite was widely distributed in nature, as a result, to prepare PILM with Ca-montmorillonite has practical significance. What's more, PILM was mainly studied as a catalyst in oil refinin g process till now, but rarely documented in other catalysis reactions, especially in coal liquification filed which also needed high activity catalyst.

以柱撑蒙脱石为代表的具有&三明治&结构的柱撑粘土矿物因其特殊的二维孔道结构和优良的催化和吸附性能近年来成为国内外广泛关注和研究的热点,但是目前国内外大量报道的PILM制备大多采用离子交换法,生产周期很长,影响因素很多,并且产物热稳定性不够高,特别是水热稳定性较差,这是其不能在实际中大规模生产和应用的主要障碍,因此制备一种高稳定性的PILM意义非常;文献中大量报道的都是钠基蒙脱石合成的柱撑粘土矿物,传统的离子交换法必须将钙基蒙脱石钠化改型,其成本相当高,而自然界中大量存在的却是钙基蒙脱石,直接用钙基蒙脱石合成柱撑粘土矿物有很现实的意义,但目前这方面的报道却很少见;另外,迄今为止,PILM作为催化剂的研究领域主要在石油的炼制中应用,而在煤炭的液化中却鲜有报道,如果能在煤炭转化领域应用这一成果,其影响也将是相当大的。

Abstract— When the solution of sodium sebacate from sebacic acid manufacture is decolorised with activated carbon adsorption,the productivity was low and the cost was high.

由蓖麻油为原料生产癸二酸过程中,传统的脱色工艺是用粉末活性炭吸附,活性炭在脱除溶液中有机色素和混酯的同时,也吸附了部分癸二酸单钠盐,使产品得率较低,生产成本高。

Make comprison of SGS concerning lathering power and foam stability. Test shows that N,N'-Difatty acid acyl hexamethylene-diamine-ethylene sulfonate(SGS-12)has better lathering performance and foam stability.

对SGS系列双子表面活性剂的起泡性能和稳泡性能进行了比较,其中N,N'-双月桂酰基己二胺二乙基磺酸钠(即SGS-12)具有更好的起泡性和稳泡性。

Alkyl diphenyl ether disulfonate is a serie of anionic surfactants with many functions. It has two hydrophilic head groups and different from conventional surfactants.

烷基二苯醚二磺酸钠是一类在结构和性能上有别于传统表面活性剂的多功能性双亲水基型阴离子表面活性剂,具有卓越的表面化学性能及应用性能。

The cyclization of carbodiimides 2 and 6 with phenol or alcohol was studied and the results showed that the cyclization of carbodiimides 2 and 6 with phenol in the presence of solid potassium at room temperature to 40℃, the cyclization of carbodiimides 2 and 6 with alcohol should in the presence of RONa.

进一步研究了碳二亚胺2和6与酚和醇的成环反应,结果表明该碳二亚胺与酚反应在碱(固体K_2CO_3)催化条件下,室温或加热到40℃便可顺利关环,与醇反应需要用到更强的碱醇钠催化才可以顺利关环。

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