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At the same time, the SEM study shows that gibbsite occurs on the sample surface. At 200 ℃, as dawsonite sandstone is being dissolved authigenic siderite forms. At 300℃, chlorite deposit on parts of the sample surface. The weak solution of dawsonite sandstone at 100℃ and the formation of siderite at 200℃ illuminate that CO2 being in carbonates in the strata can not be released when CO2 phase is adding to the system.

同时,各温度下样品表面均有一水软铝石放射状集合体沉淀。200℃时,随着片钠铝石的溶解有自生菱铁矿生成,300℃时样品局部有绿泥石沉淀。100℃下片钠铝石的微弱溶解及200℃下菱铁矿的形成表明,在地层条件下以碳酸盐矿物形式捕获的CO2,不会由于CO2的二次注入而重新释放。

The main steps include as follows: CO2 is led into the mother liquor of sodium meta-aluminate to carry out carbon content decomposing; the primary separation between the aluminum and the gallium is realized by primary carbonatation to filter out sodium hydroxide; secondary carbonatation is carried out on the filtrate to obtain the deposit of the complex salt of gallium and aluminum; a sodium carbonate crystal is obtained after the filtered filtrate is condensed and vaporized; the deposit of the complex salt of gallium and aluminum is dissolved in the mother liquor of sodium meta-aluminate; the processes are repeated until the proportion of gallium and aluminum in the complex salt of gallium and aluminum is larger than 1/340; then the complex salt of gallium and aluminum is added into the NaOH liquor and electrolyzed, thus obtaining the metal gallium with a purity larger than 99.9 percent which reaches the level of 3; simultaneously, the byproducts of the aluminum hydroxide and the sodium carbonate during the process of carbonatation by steps are obtained.

主要步骤包括:向铝酸钠母液中通入CO 2 进行碳分分解,一次碳酸化实现铝镓的初次分离;过滤出氢氧化钠,滤液进行二次碳酸化获得镓铝复盐沉淀,过滤后滤液经浓缩蒸发获得碳酸钠晶体,铝镓复盐沉淀溶解在偏铝酸钠母液中,重复上述过程直至铝镓复盐中的镓铝比例大于1/340,将其加入到NaOH溶液中,电解可获得纯度>99.9%的金属镓,达到3N级水平同时在分步碳酸化的过程中获得氢氧化铝和碳酸钠副产品。

In the presence of acetic acid and polyethylene glycol, anthracene reacted with ammonium ceric nitrate and sodium bromate to form anthraquinone.

在醋酸、聚乙二醇存在下,蒽与硝酸铈铵和溴酸钠反应生成蒽醌,聚乙二醇作为相转移催化剂可以提高反应的选择性。

The chemical structure of the product was characterized by means of the melting point and IR. The results show that tetraethylammonium bromide which was used as a phase transfer catalyst in this reaction had optimization effect on the interfacial diffusive reaction of BTC and PNP. Higher concentration of sodium hydroxide, lower temperature and a higher dosage of BTC produced a small amount of 4-nitrophenyl chloroformate, while lower concentration of sodium hydroxide and a lower dosage of BTC made reaction incomplete, which affected the yield.

结果表明,在碳酸二(4-硝基苯基)酯合成中使用的相转移催化剂四乙基溴化铵对受界面扩散控制的BTC气与对硝基酚钠反应有良好的相转移催化效果;氢氧化钠质量分数较低时,酚钠盐向溶有BTC的油相扩散速度较小,较高时会产生氯甲酸对硝基苯酯;温度较低、BTC量较高时,会产生少量氯甲酸对硝基苯酯,BTC用量较低会使反应不完全,这些都影响着收率。

Ib was synthesized by condensation of phthalic anhydride with 2-methylresorcinol in fused AlCl〓/NaCl (5∶1), followed by selective acetylation, methylation, NBS bromination and condensation with sodium ethoxide.

邻苯二甲酸酐在熔融的三氯化铝-氯化钠(5:1)中和-2,6-二羟基甲苯环合得1,3-二羟基-2-甲基蒽醌〓后经选择性乙酰化、甲基化、NBS溴化、乙醇钠缩合得1-甲氧基-2-乙氧甲基-3-羟基蒽醌。

At present, the company mainly produces: potassium dihydrogen phosphate, monoammonium phosphate, diammonium phosphate, phosphoric acid (85% industrial grade), potassium nitrate,Sodium Tripolyphosphate(Industrial-grade, Food-grade),NPK and other phosphorus products.

目前,公司主要生产:磷酸二氢钾、磷酸一铵、磷酸二铵、磷酸(85%工业级)、硝酸钾、三聚磷酸钠、各种规格的NPK复合肥等磷化工系列产品。

Based on seed-emulsion polymerization, the stable silicon-acralyte core/shell latex with little coagulum were synthesized at lower temperature with potassuim persulphate, sodium formaldehyde sulfoxylate and V-044 as composite initiators.

选用过硫酸钾、甲醛合次亚硫酸氢钠和2, 2'-偶氮二[2-(2-咪唑啉-2-代)丙烷]二氢氯化物(V-O44)为复合引发剂,在低温下通过种子乳液聚合技术合成了生成凝聚物少的硅-丙核/壳乳液。

The degree of the plumping of the cattle hide and the removal of the hair were evaluated during the li- ming process;the protein,suspending substance,sodium sulfide and effective calcium oxide contents in the liming liquor and the fat content in the limed hide were measured;also,the tissue slice of the limed hide was observed by optic microscope.

将不同量的十二烷基硫酸酯钠、十二烷基三甲基氯化铵和平平加O分别添加到浸灰液中,观察浸灰过程中皮膨胀情况和毛脱除情况,测定浸灰废液中蛋白质、悬浮物、硫化钠和有效氧化钙含量及浸灰皮油脂含量,并对浸灰皮组织切片进行显微镜观察。

The results showed 3 types of aluminum compound prepared in this paper all had good poison protection effectiveness on such impurities as stannous chloride,lead oxide,sodium hydrogen sulfate,and so on.Moreover,the mechanism of the poison of catalyst was also discussed.

结果表明,合成的3种防中毒剂即防-1、防-2(主要成分为乙酰丙酮合铝)及防-3(主要成分为二乙酰丙酮基异丙氧基铝)对二月桂酸二丁基锡、氯化亚锡、二正丁胺、硫脲、氧化铅及硫酸氢钠等杂质均有较好的防中毒作用;不同防中毒剂对不同杂质的防中毒作用有一定的选择性。

Experimental study on the metal surface cleaning agent re-oil preparation process of the series,Obtained by experiment the optimum cleaning process conditions:2g respectively SDBS,2g sodium silicate,2g sodium nitrite dissolved in 100 ml of distilled water,making the steel sheet coated with oil immersed in cleaning agents,under the conditions which keeping the washing temperature 30℃,Stirring rate of 2 files,Cleaning time for 5 min of the cleaning Cleaning the oil to achieve the highest rate of 99.62%,Corrosion rate can be controlled below 0.006%.

实验研究了金属表面重油污清洗剂制备的系列工艺,通过实验得出其最佳的清洗工艺条件:分别取2g十二烷基苯磺酸钠、 2g硅酸钠、2g亚硝酸钠溶于100毫升蒸馏水中,将涂有油污的钢片浸入清洗剂中,在清洗温度为30℃,搅拌速率为2档,清洗时间为5 min的条件下清洗,其油污清洗率最高能达到99.62%,腐蚀率能控制在?以下。

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