二金属的

This dissertation divides into seven chapters and the main contents and conclusions are listed as following:1. Three series binuclear lanthanide carboxylate coordination polymers 1～7 have been synthesized under hydrothermal conditions by altering the length of carbon chains between carboxyl group and phenyl ring on ligands, which are isophthalic acid, 1,3-phenylenediacetic acid and 1,3-phenoxydiacetic acid, and lanthanide ions such as Pr~(3+), Eu~(3+)and Ho~(3+).

论文共分七章，主要研究内容和结论如下：1、通过改变间苯二甲酸配体的羧基和苯环之间的碳链长度，从间苯二甲酸、间苯二乙酸到间苯二氧乙酸，以及改变稀土离子半径Pr~(3+、Eu~(3+)和Ho~(3+)出发，在水热条件下制备了三个系列双核金属单元的稀土羧酸二维配位聚合物1～7。

Metallic ion effects on DNA stretching were investigated. It is found that the effects of monovalent and divalent cations were significantly different.

研究了金属离子对DNA拉伸的影响，发现一价金属离子和二价金属离子对DNA的影响有显著的差别。

To solve the problems of the limescale ,the oxidation which are produced by the direct contact between a metallic conductor and water, the detecting reliability and the service life, the utility model adopts the technical proposal as below: the proposal comprises a monostable controllable trigger, a second low-pass filter, a voltage follower and a display circuit, the power circuit links with the monostable controllable trigger, the second low-pass filter, the display circuit and a timebse pulse circuit separately, the utility model is characterized in that the monostable controllable trigger, the second low-pass filter and the display circuit sequentially links, the monstable controllable trigger separately links with a water lever sensor and the timebase pulse circuit.

为了解决金属导体与水直接接触会产生水垢和氧化，影响检测可靠性和使用寿命的问题，本实用新型采用了以下技术解决方案：它包括单稳可控触发器，二阶低通滤波器，电压跟随器和显示电路，电源电路分别与单稳触发器，二阶低通滤波器，显示电路和时基脉冲电路相接，其特征在于单稳可控触发器，二阶低通滤波器，电压跟随器和显示电路依次相接，单稳可控触发器分别与水位传感器和时基脉冲电路相接。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

In the presence of catalytic rhodium acetate, ethyl 2-diazo-3-oxo-per fluoroalkanoates, reacted readily with nitriles to give a series of 5-fluoroalkyl substituted 1, 3oxazoles with high regio-selectivity through a metal carbenoid intermediate. The reactions of carbenoids with noncyclic vinyl ethers or cyclic vinyl ethers afforded dihydrofuroates in good to excellent yields. Interestingly, only vinyl C-H insertion compound was obtained concerning of the reaction of carbenoids with 2, 5dimethylfuran due to the steric hindrance of methyl group

醋酸铑分解2-重氮-3-氧代-全氟羧酸乙酯形成的金属卡宾作为1，3-偶极体，可以与一系列芳基或烷基取代的腈反应，高度区域选择性地生成一系列4-乙氧羰基-5-氟烷基取代的噁唑化合物；也可以与富电子的链状和环状的烯基醚反应，以优良的产率得到一系列氟烷基取代的二氢呋喃类化合物；而与2，5-二甲基呋喃的反应，由于甲基的位阻作用，只得到金属卡宾对呋喃3-位烯基碳氢键插入产物。

The results of Raman, SEM and EPMA tests show that the microstructure defects of the chalcogenide glasses play an important part in their second-order nonlinear optical properties. The glasses show large SNOP because of Sb2S3 microcrystal or the mental antimony in the glasses even before they were polarized. After the electrical/thermal polarized, GeSbS glasses show larger SNOP with the increase and growth of the microcrystal. The glasses show larger SNOP because of the existence of Sb2S3 microcrystal or the mental antimony in the glasses.

通过研究玻璃的拉曼光谱、扫描电镜和电子探针显微分析后发现，硫系玻璃内部的微结构缺陷对其二阶非线性光学性能有显著影响，玻璃体系内存在的Sb2S3微晶或金属锑颗粒能使硫系玻璃在未经极化处理前就具有较大的二阶非线性光学性能；经电场温度场极化处理后，随着微晶的增多和进一步长大，导致GeSbS玻璃具有更高的非线性光学性能；由于Sb2S3微晶或金属锑的存在，导致玻璃具有较高的二阶非线性光学性能。

In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物，为无机药物合成及应用提供基础信息，本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物，并解析了它们的晶体结构：其中包括首例μ〓-草酸根的四核铜配合物；合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物；以HCBP衍生物为配体合成了七个过渡金属配合物；以SCN〓、N〓，C〓O〓等为桥联配体，以dmpyen为端基配体合成了十一个配合物。

By Obtaining the absorption spectra of the metalloporphyrins at different potentials in deoxygenated solution and then following the spectra changes while the solution was being oxygenated, we were able to reveal the interaction of metalloporphyrins with O_2 at different valence states.

要了解金属大环化合物氧化还原型催化剂作用机制的一个重要问题，即是查明中心金属离子在什么价态下能与o：作用，以及相应价态的氧化还原电位。多数作者认为大环化合物中心金属离子为正二价M。

Advances in Research on Plants Reactions under Phosphate Starvation;2. Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述，综述重点是这类化合物的官能团M≡M参键的化学活性，全文包括R_2M_2_4的合成及结构，M≡M叁键与亲核试剂、与碳-碳重键，与氧或与金属羰基物等试剂的反应及其应用。

Topics discussed in this article includes synthesis and structures of R2M24, the reactions of its metal-metal triple bond with various reagents such as nucleophiles, carbon-carbon mu.

本文对一类重要的ⅥB族金属叁键化合物R_2M_2_4(R为环戊二烯基及类环戊二烯基)近年来的研究成果进行了综述，综述重点是这类化合物的官能团M≡M参键的化学活性，全文包括R_2M_2_4的合成及结构，M≡M叁键与亲核试剂、与碳-碳重键，与氧或与金属羰基物等试剂的反应及其应用。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。