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The preparation method comprises monomer synthesis and polymer synthesis. The polymer synthesis is that cyclopentadienyl sodium monomer is added into metallic cobalt complex-triphenyl phosphorus cobalt chloride under strict oxygen-free and water-free conditions, and then double inner alkyne or outer alkyne conjugate monomer is added in, and after reaction, the precipitation, filtering, abstersion and vacuum-drying are carried out, the large molecules polymer containing cyclopentadienyl cobaltocenium organometallic cobalt is obtained.

制备方法,包括单体合成和聚合物的合成,聚合物的合成是在严格无氧无水条件下,在金属钴配合物三-三苯基磷氯化钴,加入环戊二烯钠单体,随后加入双内炔或双外炔共轭单体,反应后沉淀,过滤,洗涤,真空干燥,得到含环戊二烯茂钴有机金属钴的大分子聚合物。

The electrochemical property of PDT and PDT metal complexes were characterized by CV, from the result of CV, it can be found that PDT and PDT metal complexes possesses electrochemical activity, which arised from the heteroatom of molecules.

我们用循环伏安表征了对二苯甲醛缩氨基硫脲及其金属络合物的电化学性质,从循环伏安的结果来看,对二苯甲醛缩氨基硫脲及其金属络合物具有一定的电化学活性,并且这些电化学活性主要来自于分子中的杂原子。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章,我们研究了在水相介质中金属铟促进的烯丙基溴对1,1-二氰基-2-芳基乙烯的Michael加成反应,生成一个含碳碳双键和二个碳氮叁键的三官能团化合物,另外,金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联,生成砜。

Ten kinds of metal and three kinds of organic templates, including ethylenediamine, 1,4-butylenediamine and pyrazine were used in the synthesis of metal phosphonate coordination polymers.

在所合成的16种金属有机膦酸盐配位聚合物中,有机配体为2-羟基乙酰基膦酸,用于配位的金属离子共10种,模板剂3种分别为乙二胺(en,1,4-丁二胺,哌嗪。

On terms that the metal products were supposed to be scrapped according to the normal distribution with service life,the calculation method for the theoretical value of reclamation resource of depreciated metal was studied for the conditions that the relation between consumption volume of metal and time was linear and quadratic respectively.

在假设金属制品报废概率随时间呈正态分布的条件下,研究了金属消费量随时间变化呈线性函数或二次函数两种情况下,金属折旧再生资源量理论值的计算方法。

In the hope of helping innovative formulators contemplating the use of novel electrolytes like dithionic acid , this paper presents a brief summary of some recent developments in dithionate based electroplating.

在电镀溶液中使用连二硫酸和连二硫酸金属盐作为可溶性金属离子和电解质的来源具有潜在的应用。

The selective linear dimerization of isoprene to formate myrcene in a single phase catalyst solution prepared by mixing two metals, amine, solvent and a small content of isoprene was studied.

摘 要:研究了异戊二烯在两种金属催化作用下均相线性二聚生成月桂烯的影响因素,得到优惠工艺条件:反应温度 13℃,催化剂∶异戊二烯=0 。0 5∶1 0 ,胺∶异戊二烯=0 。0 7∶1.0。

The molecular designs and synthesis of triarylamine-based picolinic acid derivatives used as ancillary ligands, and their cyclometalated iridium complexes used as red-and green-emitters, as well as optoelectronics properites of these compounds were investigated in order to solve current problems of organic/polymeric electroluminescent materials and devices.

本论文针对目前有机/聚合物电致磷光材料和器件存在的问题,开展了新型三芳胺吡啶羧酸类辅助配体及其红光和绿光环金属铱配合物电致磷光材料的分子设计、合成和光电性能研究,主要包括:(1)设计、合成了三种新型的三芳胺吡啶羧酸类双齿阴离子型辅助配体;(2)以三芳胺吡啶羧酸衍生物作为双齿阴离子型辅助配体,合成得到了两个系列的红光和绿光环金属铱配合物;(3)研究了三芳胺吡啶羧酸类辅助配体分子结构对环金属配合物的紫外吸收和光致发光性能的影响;(4)以环金属配合物为客体,聚芴和恶二唑衍生物为主体,制作了聚合物电磷光器件,研究了含三芳胺吡啶羧酸类辅助配体、环金属配合物客体材料和聚合物主体材料等分子结构对电致发光性能的影响。

With the in-situ single-stage self-metallization protocol,surface-silvered polyimide film has been prepared using pyromellitic dianhydride/ 4,4\'-oxydianiline-based polyimide as the matrix and (1,1,1-trifluoro-2,4-pentadionato)silveras the silver precursor.

在原位一步自金属化法中,以均苯四甲酸酐/4,4\'-二胺基二苯醚基聚酰亚胺为基体,以三氟乙酰丙酮银作为银的母体制备出了表面金属化的聚酰亚胺银复合薄膜。

Accordingly a further feature of the invention is a combined process wherein a dialkyl phenylethylmalonate is made from an alkyl phenylacetate and a dialkyl carbonate by a process comprising adding to a quantity of sodium which is covered with a hydrocarbon solvent boiling above 100°C, at least a chemically equivalent proportion of a lower aliphatic alcohol, subsequently adding an approximately equivalent proportion of a dialkyl carbonate and of an alkyl phenylacetate, heating the mixture to induce reaction and continuously distilling out the alcohol formed from the reaction zone and finally causing the sodio diethyl phenylmalonate so obtained to interact with an ethylating agent, such as ethyl halide, diethyl sulphate of ethyl p-toluene-sulphonate.

因此,本发明的另一个应用是一个组合工艺过程:二烷基苯基乙基丙二酸酯由烷基乙酸苯酯和二烷基碳酸酯得到,具体工艺过程是:向覆盖有沸点超过一百摄氏度的团庆化合物溶剂的金属钠中添加至少化学平衡的低级脂肪族醇,然后加入大约相同当量的二烷基碳酸酯和烷基乙酸苯酯,加热混合物引导反应进行,持续蒸馏把形成的醇类从反应区域移出,最后使获得的二乙基苯基丙二酸酯和乙基化试剂如卤代乙烷,二乙基硫酸酯形成乙基p-甲苯磺酸酯。

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