二金属的

Process for the preparation of phosphatidylserine of formula wherein R and R independently represent a saturated, mono-unsaturated or polyunsaturated acyl C10-C30, X=OH or OM where M=alkaline or alkaline earth metal, ammonium, alkylammonium including the transphosphatidylation reaction between phosphatidylcholine of the general formula wherein R and R and X have the above specified meanings, R=CH2-CH2- NH2 o CH2-CH2-N(CH3)3 and Serine in D, L or racemic form catalysed by the phospholipase D enzyme, characterised in that said reaction is carried out in a hydroalcoholic medium containing an aliphatic alcohol and in the presence of bivalent metal oxide.

本发明涉及制备式CH 2 OR 1 CHOR 2 CH 2 O-P-OCH 2 -CH(NH 2 )-COOHX的磷脂酰丝氨酸的方法，其中R 1 和R 2 独立地表示饱和的、单不饱和的和/或多不饱和的酰基C 10 -C 30 ，X＝OH或OM，其中M＝碱或碱土金属、铵、烷基铵，该方法包括通式CH 2 OR 1 CHOR 2 CH 2 O-P-OR 3 X的磷脂酰胆碱其中R 1 和R 2 以及X具有上述特别的含义，R 3 ＝CH 2 -CH 2 -NH 2 或CH 2 -CH 2 -N (CH 3 3 与D、L或外消旋形式的丝氨酸之间的转磷脂酰化反应，该反应是通过磷脂酶D酶催化的，其特征在于所述的反应是在包含脂族醇的含水醇介质中并且在二价金属氧化物的存在下进行的。

Two times hydrolyzation of Fe~(3+) and Cr~(3+) was firstly pointed out in the process of pillar preparation with hydrothermal method. In order to improve the thermal stability, Fe/Cr-Si-pillaring agent solution was synthesized by hydrolyzing Fe~(3+) and Cr~(3+) solution on the surface of silica sol, and Fe/Cr-Si-pillared montmorillonite (Fe/Cr-Si-PILM) was prepared with conventional method and hydrothermal method. Because the technical innovation of preparation is the best way to improve the PILM properties, two novel methods (Microwave method and Ultrasonication method) have been studied to synthesize Fe/Cr-PILM.In order to expand PILMs new application in the field of coal conversion, catalytic activity of Fe/Cr-Si-PILM catalyst in LongKou lignite and ShenHua coal residue liquefaction was discussed and characterized in the last part of this paper.

研究证明：蒙脱石的预处理是可行的，我们以预处理后的Ca-M为原料，研究并优化了PILM的水热法制备工艺，提出了金属离子的二次水解法；为了提高PILM的热稳定性，我们自制了硅溶胶，合成了Fe／Cr-Si三元复合柱化剂，并制备了Fe／Cr-Si-PILM；在PILM合成中，制备技术的革新是改进PILM性能的重要方法，为此我们探索了微波合成法和超声波合成法在制备Fe／Cr-PILM中的应用；最后，我们选择龙口褐煤和神华煤液化残渣为研究对象，探索了Fe／Cr-Si-PILM催化剂在煤炭液化中的应用，希望能开拓PILM应用的新领域。

Work 工作:(1) feasible process development for high-pure tetraalkyphosphonium salt as catalysts for polymerizations, potential sale 2-4 million us$;(2) simple and feasible preparation process for phosphonium salt as ionic liquids, biocides and phase transfer catalysts;(3) new and industrially feasible processes for highly sterically hindered alkylphosphines as catalyst ligands, these include tricyclohexyl-phosphine, phosphorinanes and dsmphos2,3- bis(9-phosphabicyclononylbutane;(4) sterically hindered dialkylphosphinic acid as new generation of co/ni extractant;(5) alkylphosphonium wittig reagents and the wittig reactions with them;(6) exploration of the application of borane chemistry in the synthesis of highly sterocally hindered organophosphines;(7) customer preparation of samples of a variety of organophosphorus compounds for customers all over the world.

用作高分子聚合反应催化剂的高纯度四烷基瞵盐的实用生产流程。产品销售前景 2-4 百万美元；(2)用作离子化液体，杀菌剂和相转移催化剂的烷基瞵盐的简单实用合成方法；(3)高位阻烷基磷化氢催化剂配体的工业实用合成路线的研究，这包括，三环己烷基磷， phosphorinanes 和 dsmphos 2，3-bis(9-phosphabicyclononylbutane ；(4)高位阻二烷基膦酸金属萃取剂的工业实用合成路线的研究；(5)烷基膦 wittig 反应试剂的研究；(6)硼化学在高位阻烷基磷化氢合成中的应用；(7)为世界各地提供顾客合成服务。

Advances on the development of new oxidation reagents and methodologies and their applications in both target-and diversity-oriented synthesis have been regularly surveyed and constituted one of the most extensively and actively investigated areas of current organic synthesis.1 In this context,a plethora of oxidants,including those small organic molecule-based reagents (such as Dess-Martin periodinane,Swern oxidation,Moffatt oxida- tion,Corey-Kim oxidation,and 三氧化硫/pyridine)and metal-based systems(such as Jones reagent,Collins reagent,pyridinium chlorochromate,pyridinium dichromate,barium permanganate, manganese dioxide,ruthenium tetroxide,silver carbonate,and Oppenauer oxidation),have been identified to be powerful tools promoting conversion of various alcohols into their corresponding aldehyde or ketone products and thus evolved as a most important class of tools in synthetic chemists'arsenal.

关于新的氧化试剂和方法，在两个目标和多样性为导向的发展及其应用合成的进步定期调查，构成一个最广泛，积极探讨在这方面，过多的地区目前有机合成。1氧化剂，包括有机小分子为基础的试剂（如Dess - Martin氧化剂，斯文氧化反应，氧化法特，科里，金氧化，三氧化硫/吡啶）和金属为基础的系统（如琼斯试剂，柯林斯试剂，吡啶氯铬，吡啶铬，钡锰，二氧化锰，四氧化钌，银碳酸盐和开瓶器氧化），已被证实为推动中相应的醛或酮醇转化的各种产品，功能强大的工具，因而作为一个最重要的阶级演变在阿森纳的工具合成化学家。

As the distances between coordination sites of auxiliary ligands increasing, the distances between adjacent two-dimensional [Er(5-NO_2-bdc)_2]~- anion layers enlarged. As the bulks of auxiliary ligands largening, the coordination configuration of Er optimized and the dimensions of coordination polymers increased.

增大辅助配体的配位点之间的距离，增大了二维[Er(5-NO_2-bdc)_2]~-阴离子层之间的距离；增大辅助配体的空间位阻，优化了金属离子的配位几何构型，使配位聚合物的维度增大。

Because of the filtering property suggested, two-dimensional periodic screens which were named the frequency selective surfaces have attracted a great deal of attention for many years and have been found various applications, such as band-pass radomes, reflectors of antenna system, polarizers and so on.

「频率选择表面」是由一群在空间中呈周期性排列的金属所组成的二维阵列。由於其滤波的特性，多年来，吸引了大量研究工作的投入。研究中发现，频率选择平面在电磁波的许多频段中，具有广泛的应用。例如在微波中可用於雷达或天线系统，在红外光的频段中则可用於极化器或提升分子雷射的效率。

Employing high-dilute method and 5-fold excess amine prepared two new "two-armed" acyclic diamine intermediates I_a and I_b, which are also intermediates of synthesizing microcyclic compounds, and eight aromatic Schiff bases, II_, were synthesized from reaction of I_a or I_b condensing with different aromatic aldehydes. Their composition and structure were characterized by Elemental analysis, IR, UV-Vis, LIF,~1HNMR and MS. The hydrogen bond interactions and MS fragmental patterns were also discussed.3. Several novel transition metal complexes using II_a as ligand were synthesized and identified by Elemental analysis, IR, UV-Vis,~1HNMR and molar conductivity.

1，采用高度稀释及胺过量五倍的方法合成了两个具有吡啶双酰胺臂的非环二胺Ⅰ_a和Ⅰ_b，并以它们为中间体进一步合成了八个芳香席夫碱Ⅱ_a-Ⅱ_h，通过元素分析及各种波谱测试鉴定了它们的组成与结构，对化合物的UV-Vis、LIF、IR、~1HNMR及MS进行了较为详细的讨论，还探讨了席夫碱的氢键相互作用及质谱裂解方式； 2，以席夫碱Ⅱ_a为配体合成了几个新型的过渡金属配合物，并通过元素分析、UV-Vis、IR、~1HNMR、摩尔电导及DTA—TG对其进行了表征，讨论了化合物的配位情况及配体在配位中的脱质子行为。

No weld plastic storage tanks, motor transport tank, tank transport ship products using the international advanced one-time model of rotating plastic molding process, the product has a total of polyethylene forming a seamless, impact resistance, anti-aging, weight Light, non-leakage, acid, long life, consistent with the health standards, etc., the use of the performance is much better than the traditional glass containers steel, PVC welding containers, polypropylene containers welded, steel-lined rubber, steel-lined steel containers such as glass, ordinary life is a traditional more than twice the FRP, GRP impact is more than three times, to a large extent can be replaced by stainless steel, titanium and other m e t al containers, is the best of today's new generation of high-performance corrosion-resistant chemical liquid storage transportation equipment, and cheap.

无焊缝塑料储罐、汽车运输贮罐、船舶运输贮槽系列产品采用国际先进的旋塑工艺一次性模式成型，产品具有整体聚乙烯一次成型无接缝、抗冲击、抗老化、重量轻、不渗漏、耐酸碱、寿命长、符合卫生标准等优点，使用性能大大优于传统的普通玻璃钢容器、聚氯乙烯焊接容器、聚丙烯焊接容器、钢衬橡胶、钢衬玻璃钢等容器，使用寿命是传统普通玻璃钢的二倍以上，抗冲击是玻璃钢的三倍以上，在相当大的范围内可取代不锈钢、钛等金属制品容器，是当今最理想的新一代高效的化工液体耐腐蚀贮运设备，且价廉物美。

This series of products adopt international advanced one-time model of rotating plastic molding process, the product has a total polyethylene forming a seamless, impact resistance, anti-aging, light weight, non-leakage, acid, long life, consistent with the health standards advantages, the use of the performance is much better than the traditional glass containers steel, PVC welding containers, polypropylene containers welded, steel-lined rubber, steel-lined steel containers such as glass, ordinary life is a traditional glass fiber reinforced plastic for more than twice, impact glass steel more than tripled, to a large extent can be replaced by stainless steel, titanium and other m e t al containers, is the best of today's new generation of high-performance liquid chemical storage and transportation equipment, corrosion resistance, and good value for money.

本系列产品采用国际先进的旋塑工艺一次性模式成型，产品具有整体聚乙烯一次成型无接缝、抗冲击、抗老化、重量轻、不渗漏、耐酸碱、寿命长、符合卫生标准等优点，使用性能大大优于传统的普通玻璃钢容器、聚氯乙烯焊接容器、聚丙烯焊接容器、钢衬橡胶、钢衬玻璃钢等容器，使用寿命是传统普通玻璃钢的二倍以上，抗冲击是玻璃钢的三倍以上，在相当大的范围内可取代不锈钢、钛等金属制品容器，是当今最理想的新一代高效的化工液体耐腐蚀贮运设备，且价廉物美。

For the calculations of Mon (n= 2-55) clusters, the linear and planar clusters have a strong tendency to form diatomic pairs to assemble short-long bonds alternation structures which makes them like non-metallic clusters, the short bonds are characterized as covalent non-metallic bonds and the long ones are much like weak metal bonds.

本文首先计算了各种不同结构的Mon（n=2-55）原子簇，发现一维和二维Mo原子簇表现出了一定的非金属原子簇的性质，簇中原子有明显的成双原子对趋势，致使原子簇具有短-长键交替的几何结构，短键和长键分别呈现强共价键和弱金属键的特性。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。