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One kind of composite with redox activity was prepared by ammonolysis of 3,4,9,10-perylenetetracarboxylic dianhydride,o-phenylenediamine and variable valence transition metal ions of Co~(2+).

利用苝四甲酸酐与1,3-丙二胺的胺解产物、邻苯二胺、变价过渡金属离子Co~(2+)制备了新型具有电化学活性的物质,该物质电子传输性能好,电极反应可逆,可以作为电化学活性探针使用,而且因其含有很多氨基,便于进一步结合纳米金。

In this article, Fe3-Al3 was first used to catalyze copolymerization of maleic anhydride and isoprene.

研究了双金属体系Fe3-Al3催化马来酸酐与异戊二烯的共聚反应。

A dimeric catalyst is formed from titanium main catalyst and alkylauminium cocatalyst and the copolymerization catalyst is formed from metallocene catalyst and corespondent cocatalyst, and the above-mentioned both catalysts are formed into the invented double-function catalytic system which can directly make ethylene implement dimerization in same polymerization system, and at the same time, produce copolymerization reaction to form linear low-density polyethylene.

一种用于由乙烯合成线性低密度聚乙烯的双功能催化体系,二聚催化剂由钛系主催化剂和烷基铝助催化剂组成,共聚催化剂由茂金属催化剂和相应的助催化剂组成,这两种催化剂组成的双功能催化体系,可在同一聚合体系中,直接使乙烯二聚的同时就地发生共聚反应,生成线性低密度聚乙烯。

The metal bar inserted in the collar came from a motor shaft which is 2mm in diameter.

金属酒吧插入在衣领来自电机轴是二毫米的直径。

At first, this paper gave the definition of real efficient secondary electron emission coefficient and discussed its relation the incident energy of high energy primary electron in metal in theory.

提出有效真二次电子发射系数的概念,并从理论上论述了高能原电子的能量与金属的有效真二次电子发射系数的关系,然后用实验数据证明了该理论的正确性,最后对结果进行了讨论。

The results of this study are summarized below.1 A variety of additives such as proteins,glyoxal / glycerol,alcohols,metal salts,as well as ethylene monomer were used in this study and all of them could improve the leaching resistance of the three kinds of borate(boric acid,borax,disodium octaborate tetrahydrate) in different extents through variety forms.

本研究的结果归纳如下:(1)本研究中所使用的多种助剂如蛋白质、乙二醛/丙三醇、醇类化合物、金属盐以及乙烯单体等都能通过各种形式,不同程度的提高三种硼酸盐(硼酸、硼砂、四水合八硼酸二钠)的抗流失性,但效果均不是特别明显。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1获得了多个文献首报和罕见的特殊结构的配合物:两个同时含有碱金属-过渡-稀土金属的独特的九核配合物;两个具有孔道的稀土-过渡金属异四核配合物;草酰胺类〓四核配合物;两个由双核配合物通过叠氮和单个氯原子连成的四核配合物,尤其是以单个氯桥相连的化合物非常少见;一个由弱配键和氢键连成的具有一维波浪形结构的配合物;一个通过配位键和氢键连成的二维配位聚合物。

By a charge-spin transformation, it is shown that there should be a dimerized metallic phase at U<-8W.

由电荷-自旋变换给出在U<-8W时基态应该是一个二聚化的金属。

Synthesis of methylene-4,4'-di catalyzed by zinc oxide Various metal oxide were investigated in the synthesis of methylene-4,4'-di from ethyl carbamate, and a serious of ZnO/SiO2 catalysts were prepared by deposition-precipitation method.

氧化锌为催化剂合成4,4'-二环己基甲烷二氨基甲酸乙酯以氨基甲酸乙酯和4,4'-二环己基甲烷二胺的反应体系为研究对象,在考察多种金属氧化物活性的基础上,使用沉积沉淀法制备了一系列硅胶负载氧化锌催化剂,并对其催化性能进行了研究。

The formal potentials in cyclic voltammograms of these 3+ valence complexes are followed: Co〓-TPPS (-0.08V )>Fe〓TPPS (-0.14V)>Mn〓-TPPS (-0.23V). The electrochemical reaction of Mn〓-TPPS is reversible, and both of Co〓-TPPS and Fe〓-TPPS are quasi-reversible. The standard heterogeneous rate constants of Co〓-TPPS and Fe〓-TPPS were determined to be 1. 4×10〓cm/s and 1.4×10〓cm/s respectively. The rates of electrode reaction are as followed: Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS, e.i. Mn〓-TPPS is the most easily oxidized by the dissolved oxygen, and Fe〓-TPPS is oxidized slower than Co〓-TPPS. Ni〓-TPPS can not be oxidized. It is considered that oxygen plays an important role in the valence change of central metal atom and the rate of electron transfer in some metalloporphyrins.

三价金属卟啉络合物在循环伏安图上可得到三价到二价的还原和氧化响应,电极电位从大到小排列为:Co〓-TPPS(-0.08V)>Fe〓-TPPS(-0.14V)>Mn〓-TPPS(-0.23V),电极反应可逆性也不相同,Mn〓-TPPS是可逆过程,Co〓-TPPS、Fe〓-TPPS是准可逆过程,实验测得Co〓-TPPS的标准电极反应速率常数ks=1.4×10〓cm/s,Fe〓-TPPS的ks=1.4×10〓cm/s,电极反应的速率从大到小为:Mn〓-TPPS>Co〓-TPPS>Fe〓-TPPS,即Mn〓-TPPS最容易被溶解氧所氧化,Fe〓-TPPS被氧化的速度最慢,Ni〓-TMPyP不能被氧化,因此我们认为溶解氧对金属卟啉中心离子的价态和电子转移速率起着重要作用。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。