二金属的

Nowadays, such metal as steel has been widely used as tube material, but the corrosiveness of secondary refrigerant to metal tube has negative effect on the long-term stability.

目前，钢材等金属材料由于其具有较高的热导率而被广泛地用作盘管材料，但乙二醇溶液对钢等金属的腐蚀性会对盘管工作的长期稳定性产生严重影响。

Result showed that tetrasubstituted calix [4] arenes in lower rim were stronger complex abilities than bisubstituted calix [4] arene with transition metal, heavy metal and rare earth ions. But when introducing the aminephenolicalcohols in the 1, 3-bisubstituted calix [4] arenes, the complex abilities were improved.

结果表明：在Lower rim上四取代的杯[4]芳烃配体比1，3-二取代的杯[4]芳烃配体对过渡金属离子，重金属离子及稀土离子有更好的配位能力，但当1，3-二取代的取代基上引入醇胺链型配体时，对金属离子也有很好的配位能力。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

The reaction performance of Pt-Sn-Li/Al_2O3/FeCrAl catalyst was measured,and the properties of the catalyst were characterized.It was found that reaction temperature,LHSV and the molar ratio of hydrogen to alkane have greatly affected on the catalytic performance of the Pt-Sn-Li/Al_2O_3/FeCrAl catalyst.Under a set of optimal reaction conditions,at 0.1 MPa,470℃,the molar ratio of hydrogen to alkane of 4 and LHSV of 0.14 mL·m~(-2)·h~(-1),the dodecane conversion is 6%,and the dodecene selectivity is about 72%.

结果表明：工业催化剂的催化性能比至今实验室制备的γ-Al_2O_3和SBA-15颗粒负载型颗粒状催化剂的性能好；反应温度、液时空速和氢烃摩尔比对Pt-Sn-Li/Al_2O_3/FeCrAl金属基整体式催化剂脱氢性能都有重要影响，最适宜的反应条件是压力为0.1 MPa，反应温度为470℃，进料氢烃摩尔比为4和LHSV为0.14 mL·m~(-2)·h~(-1)，此时十二烷的转化率约为6%，十二烯的选择性约为72%；活性组分涂层与金属基体结合良好。

From the structural analysis of three praseodymium complexes, we could draw a conclusion that as the dentate arms of carboxyl group on ligands elongating, the coordination numbers of Pr and the coordination modes of ligands increase, and the mean distances between metallic atoms of metallic helices existing in these complexes augment.2. By altering 5-substituting group of isophthalic acid three series of lanthanide complexes 8～19 with 5-methylisophthalic acid and 5-nitroisophthalic acid have been prepared.

从得到的三个配体的镨配合物的结构分析可以看出，随配体的羧基齿臂的增长，Pr的配位数逐渐增大，配体的配位模式增多，配合物中存在的螺旋金属链中的金属间平均距离增大。2、通过改变间苯二甲酸配体的5位取代基，制备了5-甲基间苯二甲酸和5-硝基间苯二甲酸的三个系列稀土羧酸配合物8～19。

In this paper,the discussion is emphasized on the following process flowsheets in Chinese nickel metallurgy,such as the current smelting of low nickel matte with electric furnace and flash furnace concerting of high nickel matte with concterer separation of nickel from copper in grinding and flotation process anode electrolyting of nickel sulphide;two stage counter current ...

本文重点论述了我国镍冶金现有的电炉、闪速炉熔炼低冰镍－转炉吹炼高冰镍－铜镍磨浮分离－硫化镍阳极电解；高冰镍两段逆流硫酸选择性浸出－黑镍沉钴－电积；二次镍精矿制粒－沸腾焙烧生产氧化镍等工艺流程。同时，介绍了我国自行研究开发的高冰镍氯化精炼；焙烧－氨浸－氢还原；镍精矿微波脱硫－热等离子体熔炼高冰镍；大洋多金属结核常压氨浸和硫酸选择性浸出回收镍等有价金属的新工艺新技术。

When diaryl ketones were treated in DMF promoted by samarium metal with TMSCl as activator, diaryl ketones react with DMF followed by a carbene rearrangement to afford benzoins unexpectedly, with benzils were obtained as byproducts, the formation of which may be explained as a result arising from the auto-oxidation of benzoins. Further investigation found the reaction could also proceed smoothly when I〓 was used as an activator. The reaction could occur as well in SmI〓/THF, though benzoins were obtained in relatively low yields.

发现当有活化剂TMSCl存在时，金属钐能有效的促进二芳酮和DMF的发生反应，偶联后发生卡宾重排，意外地得到苯偶姻类化合物，同时伴随着少量的二芳基二酮副产物生成，我们推测二芳基二酮的生成可能从苯偶姻的自氧化而来；进一步的研究表明，用一定量的I〓活化金属钐，该反应也可以顺利的进行，并且可以得到相对更好的实验结果。

The reaction of sodium alkylcycloperitadienide with metal chlorides gave derivatives of bisdichlorides of titanium, zirconium and hafnium where alkyls were n-propyl and n-butyl.

本文报导烷基环戊二烯基钠与金属氯化物反应合成钛、锆和铪的双金属二氯化物以及通过卤素交换制备双钛的二氟化物的方法。

The equations for two-conductor coupled-line Marchand baluns are derived. The analysis and systematic design procedure for multi-conductor coupled-line Marchand baluns are also presented, and verified with a few fabricated multi-conductor coupled-line Marchand baluns. Two MMIC broadband diode frequency doublers using multi-conductor coupled-line Marchand baluns are implemented to demonstrate the design procedure of multi-conductor coupled-line Marchand baluns. The MMICs achieve miniature chip areas with broadband performances in millimeter-wave regime.

二金属耦合线马逊平衡不平衡转换器的方程式推导及多金属耦合线马逊平衡不平衡转换器的分析及系统化设计流程也在此论文中被提出，并且用许多实际制作的平衡不平衡转换器做验证，此外，两个微波单晶积体电路的宽频二极体倍频器包含多金属耦合线马逊平衡不平衡转换器也用来验证此多金属耦合线马逊平衡不平衡转换器的系统化设计流程，这两个微波单晶积体电路在毫米波的频段内都达到微小的晶片面积与宽频的响应。

The intensive discussion, about the competitive reactions in the y-irradiation process of the stock solution, and experimental results indicate the stability constants of the metal chelates with ethylenediamine, the solubility product constants of the metal sulfides, and the standard electrode potentials of the metal ions directly control the formation of metal sulfides.

深入讨论了金属盐和硫粉在γ—射线辐照乙二胺溶液形成的还原气氛中存在的多种竞争反应，以及金属离子和乙二胺的配位常数、金属硫化物的溶度积常数和金属单质的标准电极电势对制备纳米硫化物的影响。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。