二酸的

Combining the performance evaluation (activity, selectivity and stability) and the characterization of the catalysts (XRD, TPD, FTIR and the pore structure measure), it can be concluded that :(1)The activity of modified β is higher than MCM-22, but the selectivity of ethylbenzene is lower about 3% than that of MCM-22;(2)The mounts of diethylbenzene and the other by-products are higher 1.7 times and 1.5 times than these of MCM-22 respectively;(3)The catalytic performance of zeolite mixture is nearly equal to modified β, but the selectivity of ethylbenzene is higher about 0.5% than that of modified β;(4)The catalytic activity of zeolite is mainly correlated with the number of acid sites, strength and distribution, and the distribution of products is determined by the binding energy of ethylbenzene and the pore structure, while the stability of catalyst is affected by the amount of poly-ring aromatic alkylate and the pore structure.

以性能评价和特性表征（XRD、TPD、FTIR和孔结构测定）相结合的方式，对上述三种催化剂性能比较的结果表明：（1）改性的活性明显高于MCM-22，但乙苯选择性却低于MCM-22绝对差约3%；（2）改性(上二乙苯和其他副产物的生成量分别约为MCM-22上对应值的1.7和1.5倍左右；（3）混合型催化剂的性能与改性相仿，但乙苯选择性提高0.5%左右；（4）对乙苯合成，沸石催化剂的活性主要取决于其B酸中心数、酸强度及酸分布，产物分布则取决于催化剂表面的乙苯脱附能垒值和孔道结构，而稠环芳烃的生成量和催化剂孔道结构是影响催化剂稳定性的主要因素。

The cis novel bisoxazoline ligands L1-L4 have been synthesized through the treatment of new cis dihydroxy diamide with p-toluenesulfonyl chloride in the presence of catalytic quantity of 4--pyridine, and the cis dihydroxy diamide could be achieved from the condensation of the amino alcohols and cis cyclopropane dicarbonyl chloride prepared via oxidation and halogenation from cis-2,2-dimethyl-3-formylcyclopropanecarboxylate with DCC.

我们以蒈醛酸内酯为起始原料，经过氧化反应、酰氯化反应得到顺式环丙烷二酰氯，然后在二环己基碳二亚胺的催化下与相应的氨基醇反应合成了顺式二羟基酰胺，再用对甲苯磺酰氯将羟基活化，最后在二甲氨基吡啶的催化下关环合成顺式双噁唑啉配体L1～L4。

Effect of heat treatment on the ndcrophase separation of a segmented poly copolymer based on poly diol, 3, 5 dithyltoluene diandne and 4,4'-diphenylmethane diisocyanate has been studied bymeans of fourier transform infrared spectroscopy.

用傅里叶变换红外光谱方法研究了热处理对由聚环氧丙烷聚醚多元醇、3.5－二乙基甲苯二胺和4，4－二苯基甲烷二异氰酸酯组成的多嵌段聚氨酯脲的微相分离行为的影响。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas containing 1, 3, 4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1, 3, 4-thiodiazoles with terephthaloyl diisothiocyanate.

摘 要：为寻找高活性的含杂环农药，由中间体5-烷基-2-氨基-1， 3， 4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1， 3， 4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲaf。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas Ⅲ(subscript a-f containing 1,3,4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1,3,4-thiodiazoles with terephthaloyl diisothiocyanate.

为寻找高活性的含杂环农药，由中间体5-烷基－2-氨基－1，3，4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1，3，4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲ。

As a precursive work of polymerization directly from vesicles, a polymerizable surfactant, allyl dodecyl dimethylammonium bromide was synthesized, and spontaneous stable vesicles were formed from aqueous solutions of ADDB and sodium dodecyl sulfonate in equimolar composition.

作为可聚合囊泡制备的前期基础工作，研究了一种可聚合的囊泡体系：1-丙烯基－2，2，二甲基－十二烷基溴化胺和ADDB与十二烷基磺酸钠的等摩尔比混合体系。

There was a little difference betweenphotosynthesis characteristic of the two varieties,response of Jiamusi to low temperature andpoor light was more sensitive than that of Longjiao No.2 and decreased pronouncedly withdecreasing light.6.EC and MDA of pepper leaves increased under low temperature and poor light,therewere no significant differences between them with decreasing light at 21-23℃/8-10℃,butthey were increased dramatically at 15-20℃/5-6℃.So we can speculate that lowertemperature was the direct reason resulted in cell membrane lipid peroxidation.7.No significant difference of SOD activity was observed under suboptimal temperatureand poor light21-23℃/8-10℃;150μmol·m~(-2·s~(-1),but SOD and POD activity substantiallydeclined with lowering temperature and light as well as treatment time.8.Under suboptimal temperature and lower light,proline accumulated to increaseosmotic regulation capacity and alleviate chilling damage.Soluble carbohydrate of pepper leaves decreased progressively and significantly with decreasing temperature and lightintensity as well as longer treatment time.So we think that synthesis and transport ofphotosynthetic product were inhibited by low temperature and poor light as solublecarbohydrate was important component of photosynthetic product.

两个供试辣椒品种之间的光合特性略有差异，佳木斯对低温弱光的反应比陇椒2号敏感，尤其随光照降低，其光合作用显著降低。6、低温弱光胁迫下，辣椒叶片的相对电导率和丙二醛含量都有不同程度的提高，在偏低温下，随着光照减弱，相对电导率和丙二醛含量差异不显著；在极端低温下，随着光照进一步减弱，相对电导率和丙二醛含量明显提高，随着处理时间延长，同一温度下，随着光照降低，叶片丙二醛含量也显著增加，由此可初步判断，低温是导致细胞膜脂过氧化的直接原因。7、经偏低温较弱光21～23℃／8～10℃、150μmol·m~(-2·s~(-1)处理后，辣椒叶片的超氧化物歧化酶活性变化与对照无显著差异，但随着温度、光强的逐步降低和处理时间的延长，SOD、POD活性显著降低。8、在偏低温较弱光下，辣椒能积累更多的脯氨酸，增强渗透调节，减轻低温冷害。

Synthesis of Antidote of N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane BI Hong-mei, ZHANG Jin-yan, LIANG Ying, SHEN Yong (College of Arts and Sciences Heilongjiang August First Reclamation University, Daqing 163319, Heilongjiang, China) Abstract: N-Dichloroacetyl-2-methyl-1-oxa-4-aza-spiro-4.4-nonane was synthesized by one pot method with isopropanolamine, cyclopentanone and dichloroacetyl chloride. The optimum reaction conditions obtained are as follows:the proportion in moles of the above materials is 1∶1∶1.2, reaction solvent is toluene, reaction temperature is -15 to -10 ℃,reaction time is 3 h, under the optimum condition, the yield of the compound is 50.0%.

除草剂解毒剂N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷的合成毕洪梅，张金艳，梁英，沈勇(黑龙江八一农垦大学文理学院，黑龙江大庆 163319)摘要：以33%的氢氧化钠水溶液为缚酸剂，异丙醇胺、环戊酮和二氯乙酰氯为原料，采用&一锅法&合成了N-二氯乙酰基-2-甲基-1-氧杂-4-氮杂-螺[4.4]壬烷，采用正交实验法得到最佳反应条件：反应原料摩尔比为1∶1∶1.2，苯作溶剂，反应的温度为-15 ℃~-10 ℃，搅拌时间为3 h，产率达到50.0%。

For determination of pyruvic acid, we used the ferrocene as an electron transfer mediator and pyruvate oxidase as a catalyzer, and had a systemic research for the immobilization of ferrocene and enzyme on the gold electrode. At last, a pyruvic acid biosensor with good stability and activity of electrochemistry and biocatalysis was constructed. There are two aspects of contents in the paper. The first step, we had an in-depth research for the immobilization of ferrocene on the gold electrode, and fabricated a modified gold electrode by glutaric dialdehyde cross-linked egg white as the matrix of ferrocene immobilization.

本文以研制一种通过对酶催化反应引起的电化学响应进行检测，从而实现对丙酮酸浓度进行检测的方法为目的，选择了二茂铁为电子传递介体，丙酮酸氧化酶为酶催化剂，并对将上述物质固定到金电极表面从而制成一种新型的生物传感器的方法进行了系统而全面的研究，并制得了一种全新的具有良好电化学与生物催化活性和稳定性的丙酮酸生物传感器。

AtDFA is dihydrofolate synthase localized in mitochondria, it catalyzes one glutamate added to the dihydropteroate and produces dihydrofolat. AtDFB, AtDFC and AtDFD are folylpolyglutamate synthase localized in plastid, mitochondria and cytosol respectively. A short chain ofγ-linked glutamates can be added by FPGS.Folate molecules exist in vivo mainly as polyglutamates and these are preferred by folate-dependent enzymes.

AtDFA为二氢叶酸合成酶(dihydrofolate synthase，DHFS)，定位于线粒体，在它的催化作用下，一个谷氨酸分子与二氢蝶酸(dihydropteroate ， DHP)相结合，形成二氢叶酸；AtDFB、AtDFC、AtDFD为多聚谷氨酸合成酶(folylpolyglutamate synthase，FPGS)，分别定位于质体、线粒体和细胞质，在多聚谷氨酸合成酶的作用下，谷氨酸分子可以逐一连接到四氢叶酸的谷氨酸γ位。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新