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Dimethylhexane-1,6-dimethyleurethane is the key material for preparation of 1,6-hexamethylene diisocyanate by non-phosgene route. Our work mainly focuses on the study of the catalytic performances of metal oxysalts and metal oxides for the ammonolysis of DMC to HDU-M. Experiment effect showed the ammonolysis was omposed by two steps, in which the first step was easier to occur than the second.

中文摘要六亚甲基-1,6-二氨基甲酸甲酯是非光气合成六亚甲基二异氰酸酯的关键原料,本文主要对金属含氧酸盐和金属氧化物这两类用于碳酸二甲酯胺解合成HDU-M 的催化剂进行了初步研究并优化了工艺条件。

HDI's molecular structure is a special saturated straight chain and it has highly unsaturated double bonds.It has such very lively and chemical properties that can be used to form polyurea with water. And it also reacts with polyurethane to form polyol, reacts with amine to biuret.

己二异氰酸酯分子具有特殊的直链饱和结构和含有高度不饱和双键的异氰酸酯基团,化学性质非常活泼,能够与水生成聚二脲,与多元醇反应生成聚胺酯,与胺反应生成缩二脲。

Preparation of water-borne polyurethane dispersion modified by epoxy resin;2. Preparation and Application of water-borne curing agent from cashew nut shell liquid;3. Synthesis and performance study of water-borne photosensitive PU acrylate PUA

以甲苯二异氰酸酯、聚丙二醇醚(PPG 2 2 0 )和二羟甲基丙酸为原料制备了阴离子型水性PU 乳液,研究了DMPA用量、n /n值、交联剂TMP用量对水性PU 乳液与涂膜性能的影响,得出了制备阴离子型水性PU 的最佳配

Secondary pollution might be produced in the weak zone while conventional acidify because of halfway flowback under poor producing energy. Thief zones can obtain superfluous acidizing fluid because of the permeability contrast between layers of prominent interlamination antinomy, which can induce collapse in the thief zone and invalid acidification in the less permeable layers.

低压油气层常规酸化时由于地层能量低,导致残酸溶液无法彻底返排而引起地层的二次污染;层间矛盾突出的地层,由于渗透率差异,酸液将优先进入高渗地层,导致高渗透层进酸量多,从而过度酸化引起坍塌,低渗透层则由于进酸量少而达不到酸化的目的。

From the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonylmethylate, the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonyl- methylate followed by cycloaddition reaction, was tentatively proposed.

通过研究反应过程中分离出的副产物反丁烯酸二乙酯III和4,5-二氢吡唑-3,4,5-三羧酸乙酯IV,初步提出了反应经过乙氧羰基甲基化苯并二氮杂卓翁中间体V再发生环加成反应的机制。

Objective To observe the antagonistical effect of DHA and EPA on the interference to metabolism of protein, DNA, RNA and the expression of bcl-2, bax gene by excessive iodine.

目的 观察二十二碳六烯酸二十碳五烯酸对高碘所致的脑蛋白质、核酸代谢和bcl-2、bax基因表达损伤的拮抗效应。

Sodium5sulfoisophthalic acid dimethyl ester was prepared by sulfonation of mC 6H 4 2 with chlorosulphonic acid , treatment of the 5sulfoisophthalic acid with methanol to esterify the -CO 2H groups and separation of the product in the form of sodium salt of sulfonic acid.

研究了由氯磺酸和间苯二甲酸经磺化及酯化反应合成间苯二甲酸二甲酯磺酸钠盐的工艺方法,探讨了投料比、反应温度、催化剂用量和反应时间对产物的影

In the high alumina cement , dicalcium aluminate silicate is transformed into Q phase.

将高铝水泥中的惰性成分硅铝酸二钙(C2AS)转化为水化活性良好的Q相,组成Q相铝酸一钙七铝酸十二钙(C12A7)高铝水泥系统,对此系统的烧成条件进行研究。

Based on reviewing of functionalization of saturated carbon by catalytic oxidation with metalloporphyrins and metal phthalocyanines as a mimic of the enzyme cytochrome P-450, two reaction systems of which one was the preparation of 4, 4'-dinitrostilbene-2, 2'-disulfonic acid from 4-nitrotoluene2-sulfonic acid and the other was the preparation of 4, 4'-bis (dimethylamino -diphenyl) phenylmethanol from 4, 4'-bis (dimethylamino-diphenyl) phenyl methane , were specifically studied as carfunctionalization and oxyfunctionalization of saturated carbon.

本文在全面综述金属卟啉和金属酞菁类模拟细胞色素P-450酶催化剂催化氧化饱和碳原子功能化的基础上,选择由4-硝基甲苯-2-磺酸制取4,4'-二硝基二苯乙烯-2,2'-二磺酸和由4,4'-二苯基甲烷制取4,4'-二苯基甲醇两个反应体系进行饱和碳原子碳功能化和氧功能化的具体研究。

Based on the study of the adsorption mechnism between the macroporous weak base anion-exchange resins and the aromatic sulfonic acid, a pretreatment method for the wastewater from 4, 4'-diaminostilibene-2, 2'-disulfonic acid manufacturing process, a refractory dye intermediate wastewater, was developed.

在对芳香磺酸化合物吸附机理研究的基础上,开发了大孔弱碱性阴离子交换树脂吸附法处理4,4'-二氨基二苯乙烯-2,2'-二磺酸氧化工序生产废水的新技术,并得到了工业化应用。

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By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候,里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色,卵在发育96h后卵基本全部孵化。

There was a conflict between plebs and patricians in ancient Rome in 494BC.

在公元前494年,罗马发生了一次平民反对贵族的斗争。