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Glyoxylic acid was prepared by reaction of sodium hydroxide surplus with methyl dichloroacetate in methanol solution via neutralization of filtrate with 50 percentage sulfuric acid to pH 2~3 and hydrolyzation after separation of salts.

二氯乙酸甲酯和过量的氢氧化钠在甲醇溶液中反应,滤出氯化钠后,直接加入适量的 5 0 %的硫酸调 pH值为 2~ 3,滤出硫酸钠,蒸馏回收甲醇,水解、浓缩,得到不含乙二醛的 4 0 %乙醛酸溶液。

Ee were achieved in the Pd (0)-catalyzed asymmetric reaction of racemic 1, 3-dipheylprop-2-en-1-yl acetate with dimethyl malonate under the optimized reaction conditions.

在钯催化的乙酸1,3-二苯基烯丙基酯与丙二酸二甲酯的不对称反应中,取得了接近定量的收率和较好的对映选择性(71.2%ee)。

In this study aldylencdithiomethylene Malonic acid acts as the main coordination agents and compound iron ion have been synthesized by the means of solution, As a result ,the 1D polymer is obtained.

本论文采用常规的溶液合成方法,首先设计合成了一个以含有二硫缩烯酮结构的丙二酸类配体和过渡金属铁离子的单核配合物,再以此单核配合物作为配体设计合成了三个异多核配合物和配位聚合物。

The first committed step in fatty acid biosynthesis is the carboxylation of acetyl CoA to form malonyl CoA using CO2 in the form of bicarbonate HCO3-.

在脂肪酸的从头合成过程中,参入脂肪酸链的二碳单位的直接提供者并不是乙酰CoA,而是乙酰CoA的羧化产物——丙二酸单酰CoA(malonyl-CoA)。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; and a mixture of two or more different selectivity control agents, said SCA mixture comprising from 1 to 99 percent of one or more esters of one or more aromatic monocarboxylic acids or substituted derivatives thereof, and from 99 to 1 percent of one or more alkoxysilane compounds.

一种用于丙烯聚合的催化剂组合物,包括:一种或多种齐格勒-纳塔主催化剂组合物,该齐格勒-纳塔主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体;一种或多种包含铝的辅催化剂;和两种或更多种不同的选择性控制剂的混合物,所述SCA混合物包括1到99%的一种或多种芳族单羧酸的一种或多种酯或其取代衍生物、和99到1%的一种或多种烷氧基硅烷化合物。

In this paper,the monomers including St and BA with strong waterproof property were employed to modify the traditional PVAc emulsion,and meanwhile draw into DAAM functional monomer in the copolymer system,will prepare out cross linking copolymer emulsion for ADH to improve the waterproof,oilproof and dry/wet mechanical property of fuel oil filter paper.

采用具有较强抗水性的苯乙烯、丙烯酸丁酯等单体对传统聚醋酸乙烯酯乳液进行共聚改性,并在共聚体系中引入双丙酮丙烯酰胺功能单体,制备出可通过外加己二酸二酰肼交联的外交联醋丙共聚乳液,以期提高燃油滤纸的耐水、耐油性和干湿态的力学性能。

The GLE of MA-dibutyl sebacate were calcualted by the data looked from literature on COOOC using UNIFAC method.

查取文献报道的涉及COOOC基团的汽液平衡数据,由UNIFAC方法和回归关联的方法计算出癸二酸二丁酯-顺酐体系的气液平衡关系。

Two kinds of fluids including liquid crystal and the mixture of liquid crystal and dibutyl sebacate were injected into the micro motors with four different structures of electrodes respectively.The renational corves between the rotate speed of the rotor and the voltage were got,and a series of conclusions o...

分别将单体液晶和单体液晶与癸二酸二丁酯的混合液体注入具有4种不同电极结构的微马达,得到了8条转子转速与电压的关系曲线,得出了转速与电压、液体种类、电极结构等关系的一系列结论。

The tribological characteristics of the esterified Castor oil is better than those of Castor oil, Di-iso-butyl sebacate, Pentaerythritol esters , mineral oil 150#, bean oil, Rapeseed oil. As part of 12-hydroxyl of Castor oil acid has transformed into ester so that the isomerization degree of esterified castor oil increases with the branching carbon chain extending.

四球机测定酯化蓖麻油的摩擦性能优良;优于蓖麻油、癸二酸二异辛酯、季戊四醇酯、矿物油VG150〓、豆油和菜籽油;酯化蓖麻油的流变性能改进的机理认为是部分12-OH酯化后,直链的植物油结构异构化。

CNTs were first pre-treated using acid solution (HNO3) to obtain CNTs functionalized with carboxylic groups. Subsequently, the stearyl alcohol was grafted onto CNT with the assistance of dehydrating agent, N,N'-dicyclohexyl-carbodiimide. Excellent dispersion in organic solvents such as acetone, THF, and chloroform was found for the modified CNTs (CNT-C18). In addition, the PBS/CNTs nanocomposites were then prepared through simple melt-blending. Mechanical properties, thermal behavior, conductivity of resultant polymer/CNT composites were investigated. The results show that excellent dispersion of nanotubes in the PBS matrices was achieved.

为了增加多壁奈米碳管在复合材料中的分散性,将碳管表面进行化学修饰,首先将多壁奈米碳管浸入HNO3溶液中,进行酸化,使碳管表面带有羧酸的官能基,然后再加入十八烷醇,在温和的条件下,藉由N,N'-二环己基碳二亚胺(N,N'-dicyclohexyl- carbodiimide,DCC)脱水剂脱水,使碳管和十八烷醇之间产生酯基的化学键结,改质后的碳管可以分散在acetone、THF、chloroform…等有机溶剂中,结果显示成功的利用DCC脱水剂完成碳管的改质。

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