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Cyclohexane with Mn as a catalyst in Trial 3 gave a total conversion of cyclohexane of 73% and 28.8% of which were oxygenates which contained 15.2% of dimethyl succinate, 19.6% of dimethyl glutarate and 65.2% of dimethyl adipate.

环己烷锰作为催化剂在审判3了总转化环己烷的73 %和28.8 %,其中含氧化合物其中载有15.2 %的二甲基丁二酸, 19.6 %的二甲基戊二和65.2 %的二己二酸。

Hydrogen bonding in hard segment domains of segmented polyester polyurethaneurea based on 4,4'-diphenylmethane diisocyanate, ethylene diamine and polybutylene adipate(M. W. 1975 and M. W. 1228) was studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯(分子量分别为1975和1228)的两系列嵌段聚酯型聚脲氨酯硬段微区中的氢键化进行了研究。

The subcutaneous administration of sodium dimercaptosuccinate at a dose of 1500 mg/kg immediately after the intraperitoneal injection of trivalent antimonyl ammonium gluconate increased the LD_(50) of the latter from 90—112 mg/kg to 1300—1460 mg/kg.

皮下注射二巯基丁二酸钠1500毫克/千克,司将小鼠一次腹腔注射锑铵的半数致死量从90—112毫克/千克提高至1300—1460毫克/千克。静脉注身锑~(124)铵予家兔后,如立刻经同一途径注射二巯基丁二酸钠,亦可降低锑铵的急性毒性。

In order to overcome the fault of 5'-GMPNa2 product quality, such as amorphic state, lower purity and inconstant water content, a systematical study on the crystallization process of 5'-GMPNa2 had been presented in this thesis. A new crystallization process has been developed, with which the high quality crystals of 5'-GMPNa2 can be obtained.

针对目前国内生产5'-鸟苷酸二钠基本为无定形体,且产品纯度低、水含量不稳定等问题,本文对5'-鸟苷酸二钠的结晶过程进行了系统的研究,提出了新型精制结晶工艺,解决了制备高质量的I型5'-鸟苷酸二钠晶体的问题。

Azelaic acid is a natural saturated binary carboxylic acid, which has good inhibitory and killing activities to various aerobic and anaerobic micro-organisms presents on the skin suffered acne.

壬二酸是一种天然的饱和二羧酸,壬二酸对存在于粉刺皮肤上的各种需氧和厌氧微生物均有良好的抑菌、杀菌活性。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法,合成了4种苯并咪唑-2-羧酸衍生物并进行了表征;培养了2个化合物d、e的晶体并测定和讨论了晶体结构;制备了3种未见报道的苯并咪唑金属配合物,对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

The flotation behavior and mechanism of benzyl malonic acid collector with combination use of hydroximic acid were studied by single mineral tests. The results showed that the recovery of minerals increased by combined use of benzyl malonic acid and hydroximic acid.

通过单矿物试验研究了苄基丙二酸与羟肟酸类捕收剂组合使用时对赤铁矿和菱锌矿的捕收性能,结果表明:苄基丙二酸与羟肟酸组合使用能明显提高矿物的回收率,提高浮选效率。

Isocyanurate based on TDI was synthesized and the heat-resistance property of casting polyurethane elastomer which synthesized using isocyanurate based on TDI and PEPA was obviously enhanced compared to polyurethane elastomer which did not introduce the isocyanurate by the TGA under the different temperature and the mechanics performance maintenance rate at high temperature.

在催化剂作用下,合成了TDI-100型异氰脲酸酯,并与己二酸乙二醇丙二醇酯合成了浇注型聚氨酯弹性体,通过不同温度下的热失重分析和弹性体的力学性能高温保持率对比分析表明,在TDI型聚氨酯弹性体中引入异氰脲酸酯基团,可明显提高弹性体的耐热性能。

The determination and degradation of clopyralid in soil and oilseed were studied. The soil samples were macerated with aqueous sodium hydrogen. The slurry was tumbled and centrifuged.

本文采用反相高效液相色谱分析测定二氯吡啶酸在油菜田土壤中和植株上的残留动态及收获期土壤和油菜籽粒中二氯吡啶酸的残留量,并对二氯毗啶酸在土壤-水中的吸附解吸特性进行了研究。

Segmented polyester polyurethaneurea based n 4, 4'-disphenylmethane diisocyanate, ethylene diamine and polybutylene adipate elastomers and their deuterated polymers were studied by means of IR spectroscopy.

用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯的嵌段聚酯型聚脲氨酯弹性体及其氘化產物进行了研究。

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