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First, the speed of the reaction between mud acid and rock is very fast, the effective distance of acid is short, active acid can not reach deep formation.

首先,高温下常规土酸与地层矿物反应速度极快,酸液有效作用距离短,活性酸不能到达地层深部;其次,HF与铝硅酸盐的化学反应不是简单的一次反应,其副产物氟硅酸和氟铝化物还可与铝硅酸盐发生二次反应和三次反应,形成一系列不溶性的沉淀物,对储层造成严重伤害;第三,高温情况下酸液对井下管柱及工具腐蚀性很强,对缓蚀剂性能要求高。

Amino-5-acety laminobenzenesulfonic acid has been synthesized from 2, 5-diaminobenzene sulfonic acid and Acid Red BG (CI Acid Red 37) has been synthesized by coupling the diazonium salt of 2-amino-5-acetylaminobenzenesulfonic acid with racid.

利用2,5-二氨基苯磺酸为原料合成2-氨基-5-乙酰氨基苯磺酸,并进一步经2-氨基-5-乙酰氨基苯磺酸重氮盐与γ酸的偶合反应合成了酸性红BG(CIAcidRed37),并对影响反应的因素进行了讨论

The main products are: calcium sulfate / calcium nitrate / calcium carbonate / copper sulfate / chloride, copper / zinc sulfate / nitric acid zinc / zinc chloride / potassium sulfate / potassium chloride / potassium bromide / potassium aluminum sulfate / potassium dihydrogen phosphate / 2 of potassium hydrogen phosphate / sodium bromide / sodium chloride / sodium nitrate / sodium fluoride / trisodium phosphate / sodium dihydrogen phosphate / disodium hydrogen phosphate / crystallization of sodium carbonate / anhydrous sodium carbonate / aluminum sulfate / nitrate aluminum / crystallization of aluminum chloride / aluminum hydroxide / nitrate Fe / hydrobromide / oxalic acid / boric acid / citric acid / barium chloride / Azone / magnesium sulfate / magnesium nitrate / magnesium chloride / ammonium chloride / ammonium sulfate / Bifluoride ammonium / ammonium aluminum sulfate / ferrous ammonium sulfate / ammonium dihydrogen phosphate / diammonium hydrogen phosphate / bromide / tetrabutylammonium bromide / chloride, nickel / nickel nitrate / sulfate nickel / cadmium chloride / cadmium sulfate / nitrate Cadmium / Cadmium Carbonate / Strontium / strontium nitrate / sulfuric acid manganese / manganese chloride / 50% manganese nitrate solution / stannous chloride / zinc chloride, such as crystallization of the four largest packing of chemical reagents AR and CP level.

主要产品有:硫酸钙/硝酸钙/碳酸钙/硫酸铜/氯化铜/硫酸锌/硝酸锌/氯化锌/硫酸钾/氯化钾/溴化钾/硫酸铝钾/磷酸二氢钾/磷酸氢二钾/溴化钠/氯化钠/硝酸钠/氟化钠/磷酸三钠/磷酸二氢钠/磷酸氢二钠/结晶碳酸钠/无水碳酸钠/硫酸铝/硝酸铝/结晶三氯化铝/氢氧化铝/硝酸铁/氢溴酸/草酸/硼酸/柠檬酸/氯化钡/氮酮/硫酸镁/硝酸镁/氯化镁/氯化铵/硫酸铵/氟化氢铵/硫酸铝铵/硫酸亚铁铵/磷酸二氢铵/磷酸氢二铵/溴化铵/四丁基溴化铵/氯化镍/硝酸镍/硫酸镍/氯化镉/硫酸镉/硝酸镉/碳酸镉/碳酸锶/硝酸锶/硫酸锰/氯化锰/50%硝酸锰溶液/氯化亚锡/结晶四氯化锌等大包装化学试剂的AR和CP级别。

Rare precious metals company mainly engaged in electroplating and metal surface treatment, environmental treatment, washed clean of raw materials: silver nitrate, nitric acid and rhodium, palladium nitrate; Asia selenium acid, selenium dioxide, tellurium dioxide, mineral selenium powder Japan, Mitsubishi Se powder, Mitsui, Sumitomo, emerging, Germany selenium powder; molybdenum trioxide, DMF; TX-10, NP-9 series, EDTA series; sodium hypophosphite, nickel nitrate, metal thallium, rhodium, palladium, platinum , Beryllium, Ritek, zirconium products; sponge palladium; electrolytic nickel, nickel corner, hydrazine hydrate, Ultra-fine silver, nano-silver; Thallium sulfate, iodized Thallium sulfate, nickel, copper sulfate, copper chloride, copper oxide, nickel oxide , Lanthanum oxide, oxidation Er, bismuth oxide, bismuth ingots, tin ingots, indium ingot, indium foil, Xinding, zinc powder; SnCl2, sulfate-tin; hydrofluoric acid, white Vaseline, propylene glycol, dichloro Methane, the propylene glycol, triethanolamine, triethanolamine oleic acid soap, chloroform, pyrophosphate copper, Gioia sodium, polyacrylamide, PAC, oleic acid, Glycerol, phosphate and other domestic and imported chemical series.

公司主要经营稀贵金属及电镀金属表面处理、环保污水处理、洗涤清洗原料:硝酸银、硝酸铑、硝酸钯;亚硒酸、二氧化硒、二氧化碲、日本矿业硒粉、三菱硒粉、三井、住友、新兴、德国硒粉;三氧化钼、二甲基甲酰胺;TX-10、NP-9系列、EDTA系列;次亚磷酸钠、硝酸镍、金属铊、铑、钯、铂、铍、铼、锆系列产品;海绵钯;电解镍、镍角、水合肼、特细银粉、纳米银粉;硫酸铊、碘化铊、硫酸镍、硫酸铜、氯化铜、氧化铜、氧化镍、氧化镧、氧化铒、氧化铋、铋锭、锡锭,铟锭、铟箔、锌锭,锌粉;氯化亚锡、硫酸亚锡;氢氟酸、白凡士林、丙二醇,二氯甲烷,二丙二醇,三乙醇胺、三乙醇胺油酸皂、三氯甲烷、焦磷酸铜、焦亚硫酸钠、聚丙烯酰胺、聚合氯化铝、油酸、甘油、磷酸等国产、进口化工系列。

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1,3-丙二醇酯的方法,采用以钛酸酯为主催化剂,锗化合物和钴化合物为协同催化剂,对苯二甲酸二甲酯和1,3-丙二醇按摩尔1∶1.05-2.2,在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应,或对苯二甲酸二甲酯和1,3-丙二醇按摩尔比1∶1.8-2.2,在160-220℃进行酯交换反应,将反应减压至高真空10-150Pa,反应终温在265-275℃,用氮气恢复到常压,得到本PTT产品;大大缩短了反应时间,直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片,使反应产物色相良好,PTT产品可用于纤维加工及工程塑料领域。

It was found that ARA was composed of esterification products of (2-HEA)-ester with pimaric acid, dehydroabietic acid, abietic acid and two isomers of acrylpimaric acid. ARA is a good crosslinking agent which can copolymerize with most vinyl monomers. The properties of solvent-resistance and heat resistance of the copolymer were improved considerably by the use of ARA.

实验结果表明:ARA主要由海松酸、脱氢枞酸、枞酸和丙烯海松酸的二种异构体的丙烯酸-2-羟基乙基酯的酯化产物组成,ARA是一种良好的交联剂,可与大多数乙烯基单体共聚合,其与MMA的共聚物的耐溶剂性和耐热性均得到了较大幅度的提高。

Laccase could degrade the conjugated resin acids and unsaturated fatty acids in model emulsions to some extend in the presence of ABTS2,2\'-azinobis(3-ethylbenzthiazoline-6-sulfonate or VIO.Palustric acid and abietic acid in DCS of Masson pine CTMP could be partially removed by lacaase treatment without addition of external mediator.

漆酶在ABTS2,2-连氮-二(3-乙基苯并噻唑-6-磺酸或紫尿酸存在的条件下可以降解带有共轭双键的树脂酸和不饱和脂肪酸;在不加介体的情况下漆酶处理可以除去马尾松CTMP的DCS样品中的部分长叶松酸和枞酸。

Similar to S-adenosylmethionine decarboxylase(B26),S-adenosylmethionine methyl-transferase(B70), allene oxide synthase(B38),ethylene receptor(B96),cytochrome P450(B58) and methionine synthase (B77) were found in ovaries of Pingyi Tiancha at 1d before the blossom day,which related to plant hormone and could participate in metabolic pathways of ethylene,polyamine,jasmonate acid and gibberellin,et al.,as well as had close relationship with maturity and senescence of plants.

在平邑甜茶开花前1d的子房中发现的S-腺苷甲硫氨酸脱羧酶(B26)、S-腺苷甲硫氨酸甲基转移酶(B70)、丙二烯氧化合酶(B38)、乙烯受体(B96)、细胞色素P450酶(B58)、甲硫氨酸合酶(B77)等相似基因片段与植物体内的生长素有关,将会参与乙烯、多胺、茉莉酸、赤霉素等的代谢途径,与植物的成熟和衰老具有密切的关系。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸;再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯;以氟化钾为氟化剂,环丁砜为溶剂置换氟化,再与甲醇酯化得到四氟对苯二甲酸甲酯;以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇;以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物;在乙醇溶液中经镁粉还原得到4-甲基-2,3,5,6-四氟苄醇;甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯,总收率达43.6%。

But, at present, the production of a soil displacement agent from heavy alkylbenzene sulfonate and petroleum sulfonate as oil displacement agent, there were still some problems as the instable quality, produce scale. It is necessary to develop a feasible production process of arylalkyl sulfonate, alkylated diphenyl ether sulfonate and fatty alcohol ether sulfonate as they can be used as oil displacement assistant in some special oil reservoir. In which Because their abundant raw material, big changeability of structure, high electrolyte tolerance, especial strong calcium tolerance, fatty alcohol ether sulfonate has huge industrialized value.

指出重烷基苯磺酸盐和石油磺酸盐作为三次采油的主表面活性剂,目前在工业化生产中仍存在一些问题,产品质量不太稳定,需进一步改进生产工艺技术,提高产品质量,扩大生产规模;芳基烷基磺酸盐和烷基二苯醚磺酸盐可作为助表面活性剂用于特殊的油藏条件,有必要尽快开发可行的工业化生产工艺;脂肪醇醚磺酸盐类表面活性剂的原料来源丰富,分子结构可变性强,耐电解质能力强,尤其是耐钙能力强,应用领域广,极具工业化价值。

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