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Hydrogen peroxide(H_2O_2)was used as oxidant,oxalic acid as complexing agent and tungstic acid (H_2WO_4)as catalyst.

研究了以环戊烯为原料、草酸为有机络合剂、H2O2为氧化剂,在催化剂钨酸(H2WO4)的作用下一步合成戊二酸的绿色新过程,考察了氧化剂的含量、反应物配比、催化剂用量、反应温度、反应时间等对反应的影响。

Typically,0.2 mmol of cd solution, and 0.4 mmol of mpa solution were mixed in a 40 ml solution and the ph of the solution was 二氰基丙酸乙酯 to 10.0 by solution was palced in a three-necked flask and was deaerated.

通常情况下, 0.2浓度的镉环硫乙烷,和0.4浓度的mpa的混合溶液中40巯基丙酸甲酯溶液和ph值的溶液是调整,以10.0的溶液放置在是在三制作乙酸钙中,并除去溶液中的气体。

The results show sheafing strength of wood glued-product produced by adhesive prepared with the optimal formulation of six starch-based API wood adhesive can completely meet requirement of JIS K6806 and each property indices of adhesive satisfy demand for the practical process technology.

其次,以复合变性玉米淀粉、乙二酸、聚乙烯醇、P-MDI为影响因素,按照日本JIS K6806标准中关于水性高分子-异氰酸酯木材胶粘剂胶接木材时的不同耐水性要求,通过正交试验,分别优化出Ⅰ型、Ⅱ型中Ⅰ、Ⅱ类的常态胶接、热水浸渍、反复煮沸胶接强度的六种淀粉基API的配方,并在对实验结果进行了验证性试验的基础上,进行了工业化生产试验。

Oxidation of the terminal ch2oh group of hexoses without oxidation of the reducing function produces hexuronic acids, hooc--cho.

醛糖分子两端氧化形成糖二酸,hooc-n-cooh,例如酒产生的糖醛酸,hooc-4-cho。

Sodium tungstate ; cyclohexene ; catalytic oxidation ; adipic acid ; acidic ligand ; reaction kinetics

钨酸钠;环己烯;催化氧化;己二酸;酸性配体;反应动力学

By alkaline fusion of hydroxycaproic acid and its derivatives with sodium hydrate.

用氢氧化钠碱熔处理废碱液中的羟基己酸及其聚合物,可使废碱液中己二酸的质量分数由 3。

By alkaline fusion of hydroxycaproic acid and its derivatives with sodium hydrate.

用氢氧化钠碱熔处理废碱液中的羟基己酸及其聚合物,可使废碱液中己二酸的质量分数由 3.18%提高到8.74 %,且环境效益和经济效益显

The catalyzed oxidation of cyclohexanol with 30% aqueous hydrogen peroxide by mass fraction to produce adipic acid can be achieved using tungstic acid -acidic additive catalyst system in the absence of organic solvents and phase-transfer reagent.

以钨酸-酸性添加剂为催化体系,在无有机溶剂和相转移剂的情况下,催化30%过氧化氢氧化环己醇合成己二酸

Cyclohexene ; catalytic oxidation ; tungstic acid ; hydrogen peroxide ; adipic acid

环己烯;催化氧化;钨酸;过氧化氢;己二酸

When the molar ratio of tungstic acid∶acidic organic additive∶cyclohexene∶hydrogen peroxide was 1∶1∶40∶176 (tungstic acid, 2.5 mmol) and the tungstic acid/resorcinol used as catalyst, the isolated yield of adipic acid was up to 90.9% for 8 h.

以钨酸/有机酸性添加剂为催化体系,在无有机溶剂、相转移剂的情况下,催化30%过氧化氢氧化环己烯合成己二酸

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