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Therefore, the metabolic pathway from soybean oil to erythromycin was presumed as follows: soybean oil is metabolized into TCA pathway to generate much α ketoglutaric acid and then generate succinyl CoA by strengthening TCA pathway, and the methylmalonyl CoA is formed from succinyl CoA by isomerization. Finally, methylmalonyl CoA can be used as the precursor for the biosynthesis of erythromycin.

推测豆油经过红色糖多孢菌代谢后进入红霉素合成的一条可能途径:豆油经过代谢后进入TCA循环,并强化了TCA循环的通量,产生了大量α酮戊二酸,再生成琥珀酰CoA,琥珀酰CoA在甲基丙二酰CoA异构酶的作用下生成甲基丙二酰CoA作为红霉素合成的前体。

CoA by strengthening TCA pathway, and the methylmalonyl??CoA is formed from succinyl??CoA by isomerization. Finally, methylmalonyl??CoA can be used as the precursor for the biosynthesis of erythromycin.

餐?戊二酸,再生成琥珀酰CoA,琥珀酰CoA在甲基丙二酰CoA异构酶的作用下生成甲基丙二酰CoA作为红霉素合成的前体。

The effects of DCPD and adipic acid content on product properties are investigated and the properties of DCPD-type-UPR and 191# UPR are cont rasted.

考察了双环戊二烯、己二酸加入量对双环戊二烯型不饱和聚酯树脂性能的影响,并与通用191#树脂的性能进行了比较。

There are many reports related to the synthesis of azelaic acid, such as oxidation of oleate with nitric acid or ozone (9); oxidation of castor oil with potassium permanganate (10), as well as some other synthetic methods using 1, 9-nonadialdehyde〔11〕or 1,5-cyclooctadiene 〔12〕as the materials.

有关壬二酸合成的研究报道很多,例如用硝酸或臭氧氧化油酸〔9〕;高锰酸钾氧化蓖麻油〔10〕以及以1,9-壬二醛〔11〕、1,5-环辛二烯为原料〔12〕等方法制得。

To improve water solubility of betulin, two acyl groups were introduced at C-3 and C-28 hydroxy groups of betulin. 3, 28-di-O-glutaryl-betulin was synthesized with pyridine as solvent and DMAP as catalyst from betulin and glutaryl anhydride.

为了增强桦木醇的亲水性,对桦木醇的C-3位、C-28位羟基进行修饰,在吡啶作溶剂、二甲基氨基吡啶作催化剂的条件下,与戊二酸酐反应合成桦木醇戊二酸酯。

The coupling process of dehydrogenation of 1,4-butanediol and hydrogenation of dimethyl maleate over CuO/SiO2 catalysts to produce one important fine chemical γ-butyrolactone was carried out in a continuous fixed bed reactor under atmospheric pressure.

和传统的反应过程相比,耦合反应提高了顺丁烯二酸二甲酯加氢和1,4-丁二醇脱氢活性。

Leaves was 0.11%. 11 compounds were separated and identified, which accounted for 100% of the essential oil of the skins. The main chemical components of the essential oil were 3, 7, 11-trimethyl-, 1, 6, 10-Dodecatrien-3-ol (46.03%),-Globulol (8.39%), adipic acid, dioctyl ester (7.03%), Ledol (7.00%), Copaene (5.86%), etc. ConclusionThe essential oil of leaf of Horsfieldia hainanensis Merr.

结果水蒸气蒸馏提取物得率为0.11%,通过计算机检索、图谱分析鉴定出11个化合物,占总油量的100%,其主要成分为3,7,11-三甲基l-1,6,10-十二碳三烯-3-醇(46.03%)、-蓝桉醇(8.39%)、己二酸二辛酯(7.03%)、喇叭茶醇(7.00%)、胡椒烯(5.86%)等。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先,以巴豆醛与乙硫醇为原料,在三乙胺的催化作用下高收率制得3-乙硫基丁醛;然后从乙酰乙酸甲酯出发,通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮,接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环,再通过皂化和脱羧反应生成中间体5-[2-丙基]-1,3-环己二酮;再与丙酸酐反应丙酰化,最后与0-3-氯-2-丙烯基羟胺肟化,得到目标化合物烯草酮。

Star polymer ; 1; 1-Trihydroxymethylpropane ; Sebacic acid diacetic anhydride ; PEG

星型聚合物; 1; 1-三羟甲基丙烷;癸二酸二乙酸酐;聚乙二醇

The different molar ratio of hexane diacid to terephthalic acid with the same molar diamine is designed to give the composites with different viscosity, thermal performance and the barrier properties. The 3-10 times of enhanced barrier properties of these polyerster based nanocomposites with this above MXD6T to pure polyester resins are first reported.

在相同摩尔二胺的情况下,不同摩尔比例的己二酸和对苯二甲酸使复合材料具有不同的粘度、热性能和阻隔性能,含有NMXD6T改性剂的聚酯其阻隔性能相对于纯聚酯提高了3-10倍。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。