二酸

By reactions of p-hydroxybenzoic acid with the chlorides of adipic acid, suberic acid, sebacic acid and 1,10-decanedicarboxylic acid respectively four new diacids, and then their dich-lorides, were obtained. The four diacids were found to be thermotropic.

将己二酸、辛二酸、癸二酸、1，10-十二烷基羧酸经酰氯化后，分别与对羟基苯甲酸合成，得到了四种二元羧酸以及与其相应的四种二元酰氯，并发现前者具有热致液晶性。

Calcium pimelate, calcium azelate and zinc azelate are prepared by alkali neutralization process, and calcium dimer are prepared using double decomposition reaction, the effect of binary carboxylate heat stabilizer on PVC thermal stability is studied adopting Congo red method and toast with heat method.

通过碱中和法制备了庚二酸钙、壬二酸钙、壬二酸锌，采用复分解反应法制备了二聚酸钙，采用刚果红法与热烘法研究了二元羧酸盐热稳定剂对PVC的热稳定作用。

Polyester polyol which was used for polyurethane hot melt adhesives was synthesized by the condensation polymerization of adipic acid and ethanediol, butanediol, hexanediol.

以己二酸、乙二醇、丁二醇、己二醇为原料进行酯化、缩聚反应，以钛酸丁酯为催化剂，采用阶梯式升温方式，合成了聚氨酯热熔胶用已二酸系聚酯多元醇；考察了醇酸摩尔比、催化剂种类和用量以及反应条件对酯化、缩聚反应的影响。

In the absence of organic solvent and phase-transfer reagent, the catalytic oxidation of cyclo- hexene to adipic acid with aqueous 30% hydrogen peroxide can be achieved in the presence of tungstic acid/acidic organic additive.

以钨酸/有机酸性添加剂为催化体系，在无有机溶剂、相转移剂的情况下，催化 30%过氧化氢氧化环己烯合成己二酸。当钨酸∶有机酸性添加剂∶环己烯∶过氧化氢=1∶1∶40∶176(摩尔比，钨酸用量为 2.5 mmol)时，使用有机酸性添加剂考察钨酸的催化性能，结果表明以钨酸/间苯二酚催化氧化环己烯的催化效果最优，反应 8 h 时己二酸分离产率达 90.9%、纯度为～100%；而不使用有机酸性添加剂时，己二酸分离产率只有 72.1%，产品纯度为 96.2%。

Liu Yakang Lu Jianmin He Jianyun Jin Guantai College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029

引言 环氧基型丙烯酸粉末涂料，通常所采用的固化剂主要有：壬二酸、癸二酸、十二二酸及二十二酸等［1］。

A new process has been studied to synthesize malonic acid from diethyl malonate through hydrolysis reaction and catalyzing by 732 type cation exchange resin.

用732型阳离子交换树脂催化水解丙二酸二乙酯制取丙二酸，考察了反应温度、反应时间、水与丙二酸二乙酯的质量比、丙二酸二乙酯与树脂质量比等工艺条件对收率的影响。

Niobic acid; catalytic synthesis; di-2-ethylhexyl phthalate; di-n-octyl phthalate; di-2-ethylhexylmaleate; di-n-octyl maleate; cyclohexene; modification of catalyst; dynamics of esterification

工程科技I，化学，有机化学铌酸；催化合成：邻苯二甲酸二辛酷；邻苯二甲酸二异辛酯；顺丁烯二酸二辛酯：顺丁烯二酸二异辛酯：环己烯；改性；动力学

In recent years, the company excellent location advantages, multi-introduction of advanced production equipment and technology to improve old products and develop new products to 12 - hydroxy acid-based rigid and at the same time the production of refined castor oil, hydrogenated castor oil, refined Gan oil, Sebacate methacrylate (annual output 1500 tons), dibutyl sebacate (annual output 1500 tons), octyl sebacate, anhydrous sodium sulfate, castor meal and other products.

近年来，公司以优越的区位优势，多方引进先进的生产设备和技术，改进旧产品，拓展新产品，以 12 －羟基硬质酸为主，又同时生产精炼蓖麻油、氢化蓖麻油，精甘油，癸二酸二甲酯（年产量 1500 吨），癸二酸二丁酯（年产量 1500 吨），癸二酸二辛酯，无水硫酸钠，蓖麻粕等产品。

The optimum conditions were obtained as follows: the weight ratio of fatty acids and 85%acetic acid is 1:4, ozonolysis temperature is 20-25℃, manganese/copper acetate as catalyst, and the amount of catalyst is 0.15% of fatty acids, oxidation decomposition temperature and oxidation decomposition time are 90-95℃ and 4 hours respectively. the yields of azelaic acid and pelargonic acid are 57.4% and 51.6% respectively.

以菜油酸为原料、85%醋酸水溶液为溶剂，经臭氧化、氧化分解、重结晶等过程制备壬二酸和十三烷二酸的最佳反应条件为：m：m(85%醋酸)=1：4，臭氧化温度20-25℃；氧化分解温度80-85℃，催化剂醋酸锰/醋酸铜用量为原料菜油酸质量的0.12%，氧化分解时间3h，重结晶溶剂壬酸的用量为5倍质量的氧化分解产物时，十三烷二酸的收率为58.3%，壬二酸的收率为57.2%。

It was discovered that trimalonic acid C60、fullerol、dimalonic[60]fullerene hydrolysate、tetraethyl methano[60]fullerenediphosphonate、methano[60]fullerenediphosphonic acid and dimalonic acid C60 exhibited different inhibitory effects on Taq DNA polymerase.

实验发现，6种富勒烯衍生物三丙二酸富勒烯、富勒醇、富勒烯丙二酸水解物、亚甲基富勒烯二膦酸四乙酯、亚甲基富勒烯二膦酸四乙酯的完全水解物和二丙二酸富勒烯对Taq DNA聚合酶存在不同程度的抑制作用。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。