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二酰亚胺

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Its commercial technologic processes and products,such as Acetic Acid Production by Carbonylation of Methanol,Formyl Morpholine,Steam Reforming Catalyst,Low Pressure Methanol Synthesis,Dimethyl Formamide Production by Dehydrogenation of Methanol,Dimethyl Ether Synthesis by Methanol Dehydration,Hydrogen Production by Methanol Cracking,Methanol Synthesis Catalyst,PSA Gas Separation Devices, and etc.,have been applied in more than 800 plants over fields including chemical industry,petrochemical,food, metallurgy,machinery,military industry.Many technological products were exported to American,European,Asian countries as well as Hong Kong,Macao and Taiwan.Remarkable economic and social benefits are achieved.

甲醇羰基化合成醋酸,甲酰吗啉,转化催化剂,低压合成甲醇,甲醇脱氢制二甲基甲酰胺,甲醇脱水制二甲醚,甲醇裂解制氢,合成甲醇催化剂,变压吸附制氢等成套工业装置和产品应用于全国800多家化工,石化,食品,冶金,机械,军工等企业,并出口美国,欧州,亚州等国及港,澳,台地区。

According to the properties of acrylic acid series polymer of scale inhibition. A kind of amphiprotic tercopolymer of acrylic acid, acrylamide and dimethyldiallylammonium chloride is synthesised, with water as solvent, persulfate and hypophosphate as initiator. Through the tests, the copolymer can show the good scale inhibiting effect and bactericidal action, and become a multifunctional scale inhibition.

本研究根据丙烯酸聚合物阻垢剂的特点,使用过硫酸铵(NH_4_2S_2O_8、次亚磷酸钠(Na_2PO_3)构成的氧化——还原型引发剂,水为溶剂,合成了新型可用于处理工业循环冷却水的丙烯酸—丙烯酰胺—二甲基二烯丙基氯化铵两性型三元共聚物。

The condensation of aromatic aldehydes with active methylene compounds like malononitrile, cyanoacetamide and ethyl cyanoacetate has been found to proceed very efficiently at room temperature giving excellent yields, but the condensation of heteroaromatic,α,β-unsaturated and aliphatic aldehydes with active methylene compounds proceeded smoothly in 50~65℃ with good yields and the reactions of aromatic, aliphatic ketones as well as p-phthalaldehyde with malononitrile also proceeded in 75~85℃ with moderate yields.

芳香醛与活泼亚甲基化合物如丙二腈、氰基乙酸乙酯、氰基乙酰胺的缩合在室温下即能顺利进行,获得了很高的收率;而对于杂环芳醛、α,β-不饱和的醛以及脂肪醛与活泼亚甲基化合物的缩合,需在50~65℃下进行,也取得了很高的收率;对于脂肪酮、芳香酮以及二元醛与丙二腈的缩合在75~85℃下也能顺利地进行,获得中等以上的收率。

Studing on samarium diiodide promoted asymmetric intramolecular reducing coupling reactions, we have made the resolution of the racemic biaryl dials by using enantiomeric N-tert-butanesulfinamine as the resolving reagent successfully and thus obtained a series of axially chiral biaryl dials with high enantiomeric excess.

中文摘要在二碘化钐促进的分子内不对称还原偶联反应中,我们不仅对联芳基二醛底物的合成路线进行了优化,还发现N-叔丁基亚磺酰胺辅基可以作为手性试剂,成功地对联芳基骨架二醛化合物进行拆分,得到高对映体过量的轴手性二醛类化合物。

Using pentaerythritol as initiator, boron trifluoride diethyl etherate as catalyst.dichloroethane as dispersion agent, the chloride polyether polyol is synthesized based on the mechanism of cationic ring-opening polymerization of epiclilnrohyclrin.The azide polyether polyol is synthesized, in DMF through A and sodium azide, and the non-reported azide energetic curing agent is synthesized through the adduction of B and IIDI.

以季戊四醇为起始剂,三氟化硼乙醚为催化剂,1,2—二氯乙烷为分散剂,环氧氯丙烷经阳离子开环聚合反应制成氯化聚醚多元醇,A在N,N—二甲基甲酰胺中与叠氮化钠反应制得叠氮聚醚多元醇,B与六亚甲基二异氰酸酯加成反应制得未见文献报道的叠氮固化剂。

Our company specializes in operating plating materials: sulfamic acid nickel, nickel sulphate, nickel chloride, nickel carbonate, etc.; environmentally friendly sewage treatment materials: polyacrylamide, polypropylene acid sodium, ferrous sulfate, etc.; washing cleaning materials: OP - 10, TX-10, NP-9, K-12, JFC, sodium carboxymethyl cellulose, etc.; cosmetic raw materials: Triclosan, Resorcinol, stearic acid and so on, basic chemical raw materials: Industrial salt, soda ash industrial ammonium chloride, ammonium chloride agriculture, Sodium Sulfate, Sodium Molybdate, Ammonium Molybdate, as well as chemical products such as UV-absorbers.

本公司专业经营电镀原料:氨基磺酸镍,硫酸镍,氯化镍,碳酸镍等;环保污水处理原料:聚丙烯酰胺,聚丙烯酰钠,硫酸亚铁等;洗涤清洗原料:OP-10,TX-10,NP-9,K-12,JFC,羧甲基纤维素钠等;化妆品原料:三氯生,间苯二酚,硬脂酸等,基础化工原料:工业盐,纯碱,工业氯化铵,农业氯化铵,元明粉,钼酸钠,钼酸铵等以及紫外线吸收剂等化工产品。

A base-catalyzed novel olefination methodology based on elimination of p-toluenesulfonamide:Treatment of diethyl cyanomethylphosphonate with catalytic amount of basegave the corresponding phosphoryl-stabilized carbanion, which added to the carbon-nitrogen double bond of N-tosyl imines.

新形成的氮负离子进一步攫取另一分子膦酸酯的活泼亚甲基氢形成加成产物同时再生出膦酰基稳定的碳负离子。加成产物消除对甲苯磺酰胺,高度立体选择性地得到-α-氰基-β-芳基-乙烯基膦酸二乙酯。

The prestent invention discloses the cDNA sequnce of a new human reduced NADH: ubiquinone oxidoreductase 14 KDa subunit (NADH-CoQ14KDa subunit). The protein coded with the sequence is the homolog of ox's NADH-CoQB14.5b subunit.

本发明提供了一种新的人还原型烟酰胺腺嘌呤二核苷酸-辅酶Q氧化还原酶14千道尔顿亚基(NADH:ubiquinone oxidoreductase 14 kDa subunit,简称为&NADH-CoQ 14 kDa亚基&的cDNA序列,该序列编码的蛋白是牛NADH-CoQB14.5b亚基的同系物。

Treatment of pterin (2-amino-4-hydroxy-pteridine) derivatives with N,N-dimethylformamide dimethylacetal [1,(CH 3) 2NCH(OCH 3) 2] usually gave corresponding N 2-(N,N-dimethylaminomethylene)- pterin derivatives in polar solvents.

用N ,N 二甲基甲酰胺缩二甲醇 [(CH3 ) 2 NCH(OCH3 ) 2 ,1]和蝶呤(2 氨基 4 羟基蝶啶)衍生物在极性有机溶剂中反应一般得到脒化产物:N2 (N ,N 二甲基氨基亚甲基)-蝶呤衍生物。

The Sm or Yb complexes were tested to be used as a catalyst for the Diels-Alder reaction of cyclopentadiene with methyl acrylate.

用α-亚磺酰基-N,N-二取代乙酰胺同三氯化钐和三氯化镱反应得到了相应的稀土配合物,用元素分析、红外光谱进行了结构表征。

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