二酰亚胺

A photoresist composition including a polymer is disclosed, wherein the polymer includes at least one monomer having the formula: wherein, R1 is selected from H, linear, branched or circular alkyl with 1-20 carton atoms, linear, branched or circular alkyl with 1-20 C atom, which is perfluorinated or semi-perfluorinated; and CN; R2 is alicyclic group with 5 or more carbon atoms; X is selected from methylene, aether, ester, amide and the connecting part of the carbonate; R3 is linear or branched alkylene with one or more carbon atoms or perfluorinated or semi-perfluorinated linear or branched alkylene; R4 is selected from H, CH3, CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated aliphatic group; R5 is selected from the CF3, CHF2, CH2F and perfluorinated or semi-perfluorinated substituted and unsubstituted aliphatic group; n is 1 or higher integer; OR12 is OH or at least an acid unstable group selected from the tert-alkyl carbonate, tert-alkyl ester, tert-alkyl aether, acetal and ketal.

本发明公开了一种包含一种聚合物的光刻胶组合物，该聚合物包括至少一种具有下列结构的单体：其中，R 1 选自氢、具有1～20个碳原子的线形、支化或环状烷基、半氟化或全氟化的具有1～20个碳原子的线形、支化或环状烷基、以及CN；R 2 为具有5个或更多个碳原子的脂环基团；X为选自亚甲基、醚、酯、酰胺和碳酸酯的连接部分；R 3 为具有1个或多个碳原子的线形或支化亚烷基或者半氟化或全氟化的线形或支化亚烷基；R 4 选自氢、甲基(CH 3 )、三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的脂族基团；R 5 选自三氟甲基(CF 3 )、二氟甲基(CHF 2 )、氟代甲基(CH 2 F)、以及半氟化或全氟化的取代或未取代的脂族基团；n为1或更大的整数；OR 12 为OH或者选自叔烷基碳酸酯、叔烷基酯、叔烷基醚、缩醛和缩酮的至少一种酸不稳定基团。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用"一勺烩"方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

The result of the experiment showed that the qualitative medium - speed filter paper can be used as the material of the nitrite - detecting paper: color developing reagent A containing 4 - aminobenzene sulfonamide and N - 1 naphthyl ethylenediamine hydrochloride, and mixtures of 1 : 1 naphthylamine solution and sulfanilic acid solution as color developing reagent.

实验结果表明：定性中速滤纸可以作为亚硝酸根试纸的材料；含有4-氨基苯磺酰胺和N-1-萘基乙二胺盐酸盐的显色剂A及含有1：1的α-萘胺溶液和对氨基苯磺酸溶液的显色剂B，按1：1混合后可以作为显色剂；通过应用实验表明，亚硝酸根试纸具有体积小、便于携带、检测方便、成本低廉等特点。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料，在氢化钠存在下反应，合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应，用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2，4-咪唑啉-二酮、1，2，4-三嗪-3-酮、喹喔啉等含氮杂环化合物。

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

Temperature-sensitive hydrogels P(NIPA-co-DiAB) with aromatic group as hydrophobe was were prepared by free radical micellar crosslinking copolymerization with N-isopropyl acrylamide, N,N-dially benzylamine as comonomers, N,N-methylene-bis-acrylamide as crosslinker, sodium dodecyl sulfate as surfactant and ammonium persulfatetetramethylethylenediamine as initiator system.

以N-异丙基丙烯酰胺、N，N-双烯丙基苄胺为共聚单体、N，N-亚甲基双丙烯酰胺为交联剂、十二烷基硫酸钠为表面活性剂、过硫酸铵-四甲基乙二胺为氧化还原引发体系，采用自由胶束交联共聚法合成了疏水基团为芳香基的疏水改性温敏性智能水凝胶P(NIPA-co-DiAB)。

Purified water, euphorbia cerifera wax, glyceryl stearate, ammonium acrylates copolymer, butylene glycol, copernica cerifera wax, stearic acid, sucrose acetate isobutyrate, acrylates copolymer, bentonite, tromethamine, hexylene glycol, silk amino acids, cholesterol, glycine, synthetic wax, ethylhexyl glycerin, alanine, PEG-9 dimethicone, nylon-6, lecithin, silica, simethicone, caprylyl glycol, xanthan gum, propylene glycol, isostearic acid, sodium laureth-12 slfate, ceteareth-20, polyvinyl alcohol, sodium chloride, sodium acetate, disodium EDTA, benzyl alcohol, chlorphenesin, phenoxyethanol, methylparaben, ethylparaben, propylparaben, butylparaben, isobutylparaben, may contain /- mica, iron oxides (CI 77491, CI 77492, CI 77499), titanium dioxide (CI 77891), ferric ferrocyanide (CI 77150), ultramarines (CI 77007), blue 1 lake (CI 42090), bronze powder (CI 77400), aluminum powder (CI 77000), bismuth oxychloride (CI 77163), carmine (CI 75740), chromium hydroxide green (CI 77289), chromium oxide greens (CI 77288), yellow 5 lake CI 19140

水，小烛树蜡，硬脂酸甘油酯，丙烯酸铵共聚物，1，3-丁二醇，巴西棕榈蜡，硬脂酸，异丁酸醋酸蔗糖酯，丙烯酸酯共聚物，蒙脱土，二吡喃乙酸乙酯胺，已烯醇，丝氨酸，胆固醇，甘油，合成蜡，异丁基甘油，丙胺酸，PEG-9二甲基硅油，尼龙-6，卵磷酯，硅粉，硅氧烷，癸酰基乙二醇，汉生胶，丙二醇，异硬脂酸，月桂基醚-12硫酸钠，十六十八醇醚-20，聚乙烯醇，氯化钠，醋酸钠，EDTA二钠，苯氧乙醇，氯代苯酚，卞醇，尼泊金甲酯，尼泊金乙酯，尼泊金丙酯，尼泊金丁酯，尼泊金异丁酯，[可能还含有云母，铁黑(CI 77491， CI 77492， CI 77499)，钛白粉(CI 77891)，氰化亚铁(CI 77150)，靛蓝(CI 77007)，蓝1号(CI 42090)，青铜粉(CI 77400)，铝粉(CI 77000)，氯氧化铋(CI 77163)，洋红色素(CI 75740)，氢氧化铬绿(CI 77289)，氧化铬绿(CI 77288)，黄5号(CI 19140)]文章来自网络，不代表本网站立场，版权归原作者所有，转载请注明出处！

Three aspects were included here:The derivatives of dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid were synthesized via three different routes:(1) four new compounds were synthesized via the reaction bet ween dihydrol,2,4,5-tetrazine-3,5-dicarboxylic acid, thionyl chloride and corresponding alcohol ;(2) first ,dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate wer e synthesized, then ,another four new compounds were obtained t hrough the alcoholysis under the catalyst ;(3) three acylamines were got through the ammonolysis betw een dimethyl dihydro-1,2,4,5-tetrazine-3,5-dicarboxylate and amines.

本论文分别通过三条不同的路线合成了1，4-二氢-3，6-二甲酸-s-四嗪的衍生物：(1)通过1，4-二氢-3，6-二甲酸-s-四嗪与氯化亚砜和相应的醇反应，制备了四个新化合物；(2)合成1，4-二氢-3，6-二甲酸甲酯-s-四嗪，在催化剂的作用下，与高沸点的醇进行酯交换反应，合成了四个新化合物；(3)合成1，4-二氢-3，6-二甲酸甲酯-s-四嗪后，与胺进行氨解反应，合成三个新的1，4-二氢-3，6-二甲酰胺-s-四嗪化合物。

Originally limited to dialkylamino methylenation, the application of Mannich reaction has been expanded much further in recent years to a wide variety of monosubstituted amines, amine equivalents and amides. In addition, a variety of Aza-Mannich and Mannich-Michael methodologies have emerged.

最初该反应的应用范围仅局限于二烷基胺亚甲基化反应，近年来才得到了长足的发展，其研究范围扩展到单取代的胺、胺的类似物以及酰胺等化合物，并发展形成Aza-Mannich和Mannich-Michael等复合Mannich反应。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用&一勺烩&方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。