二苯酰

In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应，由于溴代苯乙酮是含有羰基的卤代烃结构，它可以发生亲电取代和亲核加成反应，当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时，控制反应条件可以发生单取代和双取代两种产物；当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时，溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物，这在以前的研究中是没有发现的。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas containing 1, 3, 4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1, 3, 4-thiodiazoles with terephthaloyl diisothiocyanate.

摘 要：为寻找高活性的含杂环农药，由中间体5-烷基-2-氨基-1， 3， 4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1， 3， 4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲaf。

In order to find high active pesticide containing heterocycle, six novel terephthaloyl bisthioureas Ⅲ(subscript a-f containing 1,3,4-thiodiazole were synthesized by the reaction of 2-amino-5-alkyl-1,3,4-thiodiazoles with terephthaloyl diisothiocyanate.

为寻找高活性的含杂环农药，由中间体5-烷基－2-氨基－1，3，4-噻二唑与对苯二甲酰基二异硫氰酸酯反应，合成6种新的含1，3，4-噻二唑环的对苯二甲酰基双硫脲化合物Ⅲ。

The company researches and develops dimer acid synthesis technology by the Sichuan bentonite primarily catalyst, receives in the product quality and the product rate on greatly surpasses the domestic same profession (dimmer acid color ≤7#, viscosity between 5000~10000cp/250C adjustable, receives rate is higher than same profession 10%); serialized product plan: dimer acid, the monomer acid, the benzene dissolves the polyamide resins, alcohol dissolves the polyamide resins, the liquid polyamide resins mellowly and polyamine hotmelt adhesive, lets the enterprise in the intense market competition, adjusts the product mix nimbly, achieves should accomplish a task with ease to the market.

公司研发的以四川膨润土为主催化剂的二聚酸合成技术，在产品质量和产品收率上均大大优于国内同行业（二聚酸色泽≤7#，粘度在5000～10000cp/250C 之间可调，收率高于同行业10%）；系列化的产品方案：二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热熔胶，让企业在激烈的市场竞争中，灵活调整产品结构，做到应对市场游刃有余。

Cuspidate with 33％ identity and 50％ similarity to taxadien-5α-ol-O-acetyltransferase, 34％ identity and 52％ similarity to 10-deacetylbaceatin Ⅲ-10-O-acetyltransferase, and 33％ identity and 49％ similarity to taxane 2α-O-benzoyltransferase, respectively, moreover, it contained the conserved HXXXDG motif that is found in other transacylases, this sequence element has been suggested to function in acyl group transfer from acyl CoA to the substrate alcohol.

No.AF448807）在氨基酸水平与大部分植物来源的酰基转移酶具有较大的同源性，其中与东北红豆杉紫杉二烯-5α-醇-乙酰转移酶的一致性达33％、相似性达50％，与东北红豆杉紫杉10-去乙酰巴卡亭Ⅲ-10-0-乙酰转移酶的一致性达34％、相似性达52％，与东北红豆杉紫杉二烯2α-0-苯甲酰转移酶的一致性达33％、相似性达49％，并且在TS4的氨基酸序列中还发现酰基转移酶家族成员特有保守序列HXXXDG，这个序列单元被认为在将酰基CoA转移至醇类底物的过程中发挥作用。

The sodium dithiobenzoic acid was oxidized with potassium ferricyanide to obtain di disulfide.The influences of raw materials mole ratio,stirring method and reaction time on the yield were studied with orthogonal test.

用铁氰化钾溶液氧化二硫代苯甲酸钠，得双二硫代苯甲酰，采用正交实验探讨了4，4'-偶氮双(4-氰基戊酸)与双二硫代苯甲酰反应的投料比、搅拌方式、反应时间对反应收率的影响。

Amino-monomethoxypoly(ethy1ene glycol)(mPEG-NH2) was synthesized based on the principle of Gabriel synthesis.Monomethoxypoly(ethy1ene glycol) tosylate was prepared at first,and then reaction with potassium salt of phthalimide as nucleophile to produce the monomethoxypoly(ethy1ene glycol)phthalimide derivative.

摘 要：首先合成了单甲氧基聚乙二醇对甲苯磺酸酯，然后根据盖布瑞尔合成法原理，以邻苯二甲酰亚胺钾盐为亲核试剂与mPEG-OTs反应，生成单甲氧基聚乙二醇的邻苯二甲酰亚胺衍生物，mPEG-PI与水合肼反应肼解生成伯胺，合成了一端为氨基的单甲氧基聚乙二醇(mPEG-NH2)。

The UHF/AMl calculations were applied to study the thermolyses of o- dimethylaminobenzoyl, o-dimethylamino-p-methylbenzoyl and o- dimethylamino-p-nitrobenzoyl azides.

采用UHF／AM1方法对2－二胺基苯甲酰叠氮、2－二甲胺基－3－甲基苯甲酰叠氮和2－二甲胺基－3－硝基苯甲酰叠氮的热分解反应进行了研究。

The company developeddmmer acid synthesis technology in Sichuan bentonite mainly catalyst , the product quality and finished product rate both were much better than the internal industry(dimmer acid color:≤7#, viscosity : between 5000~10000 cp/250C adjustable , finished product rate :≥10% internal industry); a series products project : dimer acid 、 monomer acid 、 benzene dissolved polyamide resin 、 alcohol dissolved polyamine resin and polyamine hotmelt adhesive , let enterprises in the fierce market competition , flexible adjustment product structure , to cope with the market with facility .

公司研发的以四川膨润土为主催化剂的二聚酸合成技术，在产品质量和产品收率上均大大优于国内同行业（二聚酸色泽≤7#，粘度在5000～10000cp/250C之间可调，收率高于同行业10%）；系列化的产品方案：二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热溶胶，让企业在激烈的市场竞争中，灵活调整产品结构，做到应对市场游刃有余。

The company developed dmmer acid synthesis technology in Sichuan bentonite mainly catalyst,the product quality and finished product rate both were much better than the internal industry(dimmer acid color:≤7#,viscosity:between 5000~10000cp/250C adjustable,finished product rate:≥10% internal industry);a series products project:dimer acid、monomer acid、benzene dissolved polyamide resin、alcohol dissolved polyamine resin and polyamine hotmelt adhesive,let enterprises in the fierce market competition,flexible adjustment product structure,to cope with the market with facility.

公司研发的以四川膨润土为主催化剂的二聚酸合成技术，在产品质量和产品收率上均大大优于国内同行业（二聚酸色泽≤7#，粘度在5000～10000cp/250C之间可调，收率高于同行业10%）；系列化的产品方案：二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热溶胶，让企业在激烈的市场竞争中，灵活调整产品结构，做到应对市场游刃有余。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。