二苯胺

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核，分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链，设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

Nonlinear optical organic materials have more advantages than inorganic materials. Based on the molecule design, a new D-π-A structure NLO chromophore molecule [4-nitro-4'-N,N-di aminoazobenzene] 3 with nitro, azobenzene and epoxy is synthesized.

以环氧氯丙烷、苯胺、对硝基偶氮苯胺为原料，设计并合成了一种具有推拉电子结构、含双环氧基的偶氮类有机非线性光学发色团分子4-硝基－4'-N，N-二缩水甘油氨基偶氮苯。

The cesium fluoride-mediated N,N-diarylation of 4-(biphenyl-4-oxy)aniline with 4-fluoronitrobenzene and subsequent reduction of the dinitro intermediate led to a new triphenylamine-based diamine monomer, 4,4'-diamino-4-(biphenylyl-4-oxy)triphenylamine.

以氟化铯为媒介将此苯胺与 4-fluoronitrobenzene 进行芳香族亲核取代反应，随后再进行dinitro中间体的还原反应，制得ㄧ种新型具有三苯胺结构的芳香族二胺单体4，4'-diamino-4-(biphenylyl-4-oxy)triphenylamine。

Application of conductive polyaniline on the electronic related industry has become more and more interesting and popular. In this research, the chemical oxidization method was used to form emeraldine salt type PANi doped with HNO3 and dodecyl benzene sulfonic acid.

导电性聚苯胺(Polyaniline；PANi)应用在电子相关产业是目前相当热门的研究领域，本研究采用化学氧化合成法制备硝酸与十二烷基苯磺酸共掺杂之Emeraldine Salt型聚苯胺。

2The chemical oxidization method was used to prepare emeraldine salt type conductive polyaniline co-doped with hydrochloric acid and dodecylbenzene sulfonic acid (PANI－HCl－DBSA) by interfacial polymerization which employ immiscible interface formed via the water and organic solvent.

2采用化学氧化合成法，以界面聚合方式，利用水与有机溶剂所形成的不相容界面，直接制备以盐酸和十二烷基苯磺酸共掺杂ES型导电性聚苯胺(PANI－HCl－DBSA)，藉由加入适量之DBSA，达到聚苯胺可完全溶解分散於有机溶剂中的目的。

The dye intermediate 2,6-dichloro-4-nitroaniline was prepared by direct chloridization of nitroaniline in the solution of hydrochloric acid.

在盐酸溶液中，以对硝基苯胺为原料，采用直接氯化法制取了染料中间体2，6-二氯-4 -硝基苯胺。

New hyperbranched polymers containing triphenylamine were synthesized by polycyclotrimerization of bis(4-ethynylphenyl)phenylamine and 1-octyne with dicarbonyl- cyclopentadienyl-cobalt CpCo(CO2 as catalyst under ultraviolet irradiation.

在以CpCo2为催化剂和紫外光照射的条件下，以二-(4-乙炔苯基)-苯胺和1-辛炔为单体合成了新型的含三苯胺超支化聚合物。

The polycondensation of the benzoguanamine and pyromellitic Dianhydride was carried out under microwave irradiation, and the resulted polyamic acid was grafted with TDI-para position substitution aniline derivatives. Thus graft polymers with different electronic effect of the end group in side chain were obtained.

将微波辐射合成的苯代三聚氰胺-均苯四酸二酐体系的PAA与TDI-对位取代苯胺衍生物反应，通过改变TDI－对位取代苯胺衍生物的对位取代基来合成具有不同电子效应的侧链端基的接枝聚合物。

It was found that for benzoyl peroxide initiation at room temperature, HMA is efficient than the more commonly used DMA, as indicated by decreased cure times or increased peak exotherm and barcol hardness.

比较了N，N-二甲基苯胺和N-甲基-N-2-羟乙基苯胺对不饱和聚酯树脂的固化，HMA的固化时间比DMA的短，放热峰温度和巴士硬度比DMA的高。

As for PAn-based composites, the influences of the kinds of oxidant, the amount of hydrochloric acid and barbon black on conductivity were investigated, Li/PAn button-type secondary batteries were assembled with PAn-based composites which were synthesized by chemical oxidative polymerization and used as cathode, the influences of the kinds of oxidant, synthesized technics, conducting carbon black added mode and PAn/metal oxide composites used as cathode on the properties of these batteries were studied.

对于聚苯胺基复合材料体系，研究了氧化剂种类、盐酸用量、炭黑用量对复合材料电导率的影响；以化学法制备的聚苯胺基复合材料作正极组装了Li/PAn二次扣式电池，探讨了氧化剂种类、聚合工艺、导电剂的加入方式以及PAn与金属氧化物复合后作电池正极的性能。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。