二苯胺

The result indicated that deoxidizing emeraldine destroyed of quinone diamide conjugate structure, both of the conductivity and solubility were reduced. The charge was delocalized along the molecular chains after protonic acid doped, which was beneficial to the electric conductivity.

结果表明，还原本征态聚苯胺破坏了聚苯胺链中的醌二亚胺的共轭结构，电导率和溶解性能均下降；质子酸掺杂本征态聚苯胺后分子链上的电荷离域程度增加，有利于电子流动，从而提高其电导率。

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为：芳胺与七氟异丙基碘的物质的量比1：1.1~1.5，连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3，相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1，溶剂总用量使苯胺浓度在0.5~1.0 mol/L；反应温度10~20℃；溶剂采用乙醚。取代基供电子性越强，反应时间越短，产率越高；氨基的对位优先反应，氨基的邻位较难发生反应；且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

Dioxide quinoxaline formaldehyde semicarbazones and imines were synthesized by the reactions of 1,4-dioxide quinoxaline formaldehyde with aminourea or substituted anilines.

用1，4-二氧喹喔啉甲醛与氨基脲、苯胺、取代苯胺等反应，合成了11种1，4-二氧喹喔啉甲醛－缩氨脲和醛亚胺。

Rhodamine B, Malachite green, Auramine O, Bismark Brown,Methyl Violet 5BN, Basic Magenta, Acid Orange II, Chrysophenine GX, Direct Fast Black G, Indigo, Sulphur Black, Solvent Red 24, Solvent Red 49, Solvent Brown 41, Solvent Orange 3,Pigment Yellow 154,155, Pigment Red 188,208, Meta-Diethyiaminophenol, M-Amino acetanilide , P-Amino acetanilide, etc.

主要产品：碱性玫瑰精，碱性品绿，碱性嫩黄O，碱性品红，碱性紫5BN，碱性红6DDN，酸性橙II，靛蓝，硫化黑，直接冻黄，直接黑G，溶剂红24，溶剂红49，溶剂棕41，溶剂橙3，溶剂橙62，颜料黄154，155，颜料红188，208，间羟基－N，N－二乙基苯胺，间氨基乙酰苯胺，对氨基乙酰苯胺。

The recent advances in the main clean processes to synthesize diphenylmethane diisocyanates are reviewed, such as BTC method, condensation of aniline, reductive carbonylation of nitrobenzene, oxidative carbonylation of aniline, methoxycarbonylation of aniline, alcoholysis of N,N'-diphenyl urea and the coupling process.

回顾了清洁合成二苯甲烷二异氰酸酯的几种主要方法，如BTC法、苯胺缩和法、硝基苯还原羰基化法、苯胺氧化羰基化法、碳酸酯法、二苯基脲法和反应耦合法等合成路线。

In order to improve its solubility and conductivity, the chemical oxidation method was used to prepare emeraldine salt type conductive polyaniline co-doped with nitric acid (HNO3) and dodecylbenzene sulfonic acid.

本研究使用化学氧化聚合法，以硝酸与十二烷基苯磺酸共掺杂制备导电性聚苯胺，采用共掺杂的方法不但可改善聚苯胺难溶的特性，更可兼顾聚苯胺之导电性。

Racemic backbones 2-amino-2'-hydroxy-6,6'-dimethyl-l,l'-biphenyl la and 2-amino-2'-hydroxy-4,4',6,6'-tetramethyl-l,1'-biphenyl 1b were synthesized from o-methylaniline and 2,4-dimethylaniline via nitration, diazotation/iodination, Ullmann coupling, selective reduction, diazotation/hydrolysis and hydrogenation.

从邻甲苯胺及2，4-二甲基苯胺出发，经过硝化，重氮化-碘代，偶联，单还原，重氮化-水解及还原反应合成了消旋体骨架2-氨基-2'-羟基-6，6'-二甲基-1，1'-联苯1a和2-氨基-2'-羟基-4，4'，6，6'-四甲基-1，1'-联苯1b。

This thiosemicarbazide was treated under the catalysis of glacier acetic acid,mercuric acetate giving 2 benzyl 5 phenylamino 1,3,4 thiodiazole and 2 benzyl 5 phenylamino 1,3,4 oxadiazole respectively.

然后分别将其在冰醋酸、醋酸汞存在下关环，制得 2 苯甲基 5 苯胺基 1，3 ，4 噻二唑与 2 苯甲基 5 苯胺基 1，3 ，4 口恶二唑

Keywords hyperbranched polymer;triphenylamine;bis（4-ethynylphenyl）phenylamine;1-octyne;[2+2+2] cyclotrimerization;dicarbonyl-cyclopentadienyl-cobalt catalyst;fluorescence quantum yields

超支化聚合物；三苯胺；二-（4-乙炔苯基）-苯胺； 1-辛炔； [2+2+2]环三聚；二羰基茂钴催化剂；荧光量子效率

The synthetic route is concise and convenient. In chapter four, a serial of dithienylethene derivatives containing substituted triphenylamine groups was synthesized with a concise route.

第四章通过Suzuki反应，制备了在噻吩环的5-位上有单三苯胺取代的二噻吩乙烯，和5-，5'-位双三苯胺取代二噻吩乙烯光致变色化合物。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。