二苯胺

Is a high-tech private enterprise, located in Laohekou City, Hubei Province, the main products are: 3,4 - dichloro-nitrobenzene; 3,4 - dichloroaniline; 2,4 - dimethyl-nitramine p; 2,4 - dimethylaniline; 2,6 - dimethyl-nitrobenzene; 2,6 - dimethylaniline; 3,5 - dimethyl-nitrobenzene; 3,5 - dimethyl Aniline; acrolein; Glutaraldehyde and other fine chemical products.

老河口联谊化工有限公司为一家高科技民营企业，位于湖北省老河口市，主要产品有：3，4-二氯硝基苯；3，4-二氯苯胺；2，4-二甲基硝基苯；2，4-二甲基苯胺；2，6-二甲基硝基苯；2，6-二甲基苯胺；3，5-二甲基硝基苯；3，5-二甲基苯胺；丙烯醛；戊二醛等精细化工产品。

PVC resin, PTFE resin, fumaric acid, anthraquinone, nitroanthraquinone, paraaminophenol, melamine, cyanuric acid, sulfanilic acid, chemical inhibitor 168, azoic coupling component As, stearate, aniline, nitroaniline, pentaerythritol, chlorcosane, sodium calcium, triethylene diamine, sodium benzene sulphinate, m-phthalic acid, thiourea, aniline black dyestuffs, acid dyestuff, etc.

聚氯乙烯树脂、聚四氟乙烯树脂、反丁烯二酸、蒽醌、硝基蒽醌、对氨基苯酚、三聚氰胺、氰尿酸、对氨基苯磺酸、抗氧剂168、色酚As、硬脂酸盐、苯胺、硝基苯胺、双季戊四醇、氯？？？腊、甲酸钙、三乙烯二胺、苯亚磺酸钠、间苯二甲酸、二甲酯五磺酸钠、硫脲、油溶性苯胺黑染料、酸性黑染料等有机化工原料和中间体。

In this dissertation, two derivatives of aniline containing polyoxyethylene substituent m-phenylene diamino formyl alkylenediamine poly acetate and poly-3-aminobenzoate were designed and synthesized. And then, comb-shaped polyaniline grafted by PEO were prepared by chemical oxidation copolymerization. The structure of copolymers were characterized by FTIR, ultraviolet-visible spectrum, elemental analysis and TEM etc..

本文在设计并合成两种含聚氧乙烯取代基的苯胺衍生物——间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯和3-聚氧化乙烯单甲醚基苯胺的基础上，采用化学氧化法将它们与苯胺进行共聚，制备出了聚氧乙烯接枝聚苯胺的梳型共聚物。

This study concludes the following four parts:(1) acute toxicity of several chloroanilines to zebra fish;(2) effects of chloroanilines on antioxidant defense of crucian carp;(3) effects of chloroanilines on serum sex steroids in crucian carp;(4) effects of chloroanilines on lymphocyte proliferation in crucian carp, and the detailed results and main conclusions are concluded as follows

本论文以2-氯-4-硝基苯胺、4-氯-3-硝基苯胺、2-氯-5-硝基苯胺、2，4-二氯苯胺、3，4-二氯苯胺、2，5-二氯苯胺、2，3-二氯苯胺为研究对象，研究分为四部分：(1)氯代苯胺对鱼类的急性毒性；(2)氯代苯胺对鲫鱼抗氧化系统的影响；(3)氯代苯胺对鲫鱼血清性类固醇激素水平的影响；(4)氯代苯胺对鲫鱼淋巴细胞增殖的影响。

The acute toxicities of 2-chloro-4-nitroaniline, 4-chloro-3-nitroaniline, 2-chloro-5-nitroaniline, 2, 4-dichloroaniline, 3, 4-dichloroaniline, 2, 5-dichloroaniline, 2, 3-dichloroaniline to zebra fish were conducted in lab. 48h LC〓 values were 11. 18, 4. 62, 9. 23, 9. 55, 7. 07, 6. 68, 0.62mg/L respectively, and 96h LC〓 values were 6. 99, 2. 58, 8. 63, 7. 79, 6. 08, 5. 23, 0.49mg/L respectively.

1研究了2-氯-4-硝基苯胺、4-氯-3-硝基苯胺、2-氯-5-硝基苯胺、2，4-二氯苯胺、3，4-二氯苯胺、2，5-二氯苯胺、2，3-二氯苯胺对斑马鱼的急性毒性，经计算48h LC〓分别为11.18、4.62、9.23、9.55、7.07、6.68、0.62mg/L，96h LC〓分别为6.99、2.58、8.63、7.79、6.08、5.23、0.49mg/L，这7种化合物均属于高毒物质。

C. I. Reactive blue KN-R, Alizarin brilliant green G and Hostlam blue R could not be degraded by Zoogloea HP3. Furthermore, ABAS degradation was regressed under the exisitence of the above dyes. 1-Aminoanthraquinone-2sulfonic sodium, 1, 4-dihydroxylanthraquinone-2-sulfonic sodium, 1, 4, 5, 8tetrahydroxylanthraquinone, anthraquinone, aniline, phenol, catechol and ophthalic acid could be degraded by Zoogloea HP3. Aniline was the most degradable substrate among ABAS, aniline, phenol, catechol and o-phthalic acid. However, benzenesulfonic sodium and p-amino benzenesulfonic sodium were not degraded by it.

动胶菌HP3不能降解活性艳蓝KN-R、弱酸性绿GS及毛用活性蓝HW-R等蒽醌型染料，且染料的存在对菌体降解溴胺酸有不同程度的抑制作用；动胶菌HP3可以降解1-氨基蒽醌-2-磺酸钠、1，4-二羟基蒽醌-2-磺酸钠、1，4，5，8-四羟基蒽醌、蒽醌及苯酚、邻苯二酚、苯胺、邻苯二甲酸等苯系化合物，而不降解苯磺酸钠、对氨基苯磺酸钠；在溴胺酸、苯酚、邻苯二酚、苯胺、邻苯二甲酸中，苯胺是动胶菌HP3的天然底物。

The process is that chromium yeast is first washed after centificating from the cultural medium and dried and then determined by Biphenyl Carbazide Method.

确定了比较合适的有机铬检测方法：酵母粉进行振荡浸泡（100rpm）10h后，洗涤离心干燥，然后采用二苯胺基脲法检测有机铬含量。

At first, Polyaniline was synthesized by the improved chemical oxidation technique, then, PANI/HCl, PANI/TSA and PANI/DBSA were obtained by doping emeraldine with HCl, 4-methyl benzene sulfonic acid and dodecylbenzene sulfonate acid, separately. Leucoemeraldine was obtained in the N-dimethylformamide by using phenylhydrazine deoxidizing emeraldine in N_2 atmosphere.

本文首先通过改进合成条件的化学氧化法合成了聚苯胺，经氨水脱掺杂获得本征态聚苯胺，再经盐酸、对甲苯磺酸、和十二烷基苯磺酸掺杂，分别获得到质子酸掺杂的聚苯胺样品，然后在N，N-二甲基甲酰胺中，利用苯肼，在N_2氛围下还原本征态聚苯胺得到还原态的聚苯胺。

In this article,a non-carcinogenic dye intermediate 4-aminodianiline-2-sulfonic acid is synthesized from 4-nitro-1-chlorobenzen through sulfonation,condensation and reduction.

针对联苯胺作为合成染料的重要中间体已被确认为致癌物的情况，以对硝基氯苯为原料，经磺化、缩合、还原，合成了一种无致癌性并取代联苯胺的双胺化合物染料中间体4-氨基二苯胺-2-磺酸，利用红外光谱、差热和氢谱核磁对其性质进行了表征。

Place 5 ml in a test-tube immersed in iced water, add 0.4 ml of a 100 g/l solution of potassium chloride R, 0.1 ml of diphenylamine solution R and, dropwise with shaking, 5 ml of nitrogen-free sulphuric acid R.

硝酸盐：取本品5ml置试管中，于冰浴中冷却，加100g/l氯化钾溶液0.4ml与0.1%二苯胺溶液0.1ml，边摇边滴加无氮的硫酸5ml，摇匀，将试管于50℃水浴中放置15分钟，溶液产生的蓝色与标准硝酸盐溶液(2 ppm NO3)0.5ml，加无硝酸盐的水4.5ml，在同一时间用同一方法处理后的颜色比较，不得更深。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。