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二苯胺

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Versicolor suited to grow and produce laccases at pH value 3.5-5.7, and unbuffered media were able to get good laccase productivity though buffered media could get higher laccase activity. Metal ions Cu(superscript 2+) and Mn(superscript 2+) in the culture could remarkably increase the activity of laccases. The optimal concentration of Cu(superscript 2+) was 0.008-0.08mmol/L, and the optimal concentration of Mn(superscript 2+) was about 0.01mmol/L, when the culture contained 0.1mmol/L 2,5-dimethoxyaniline.

结果发现该菌种适宜在pH值3.5~5.7环境下生长并合成漆酶,培养基中添加缓冲液可以获得更高的酶活,但不加则有较高的酶产率;铜和锰可以显著提高漆酶活力,当以0.1mmol/L 2,5-二甲基苯胺为诱导剂时,培养基中宜含0.008~0.08mmol/L Cu(上标 2+),0.01mmol/L左右的Mn(上标 2+)。

Results Besides the action of conduction anesthesia,chlordimeform has the cardiovascular toxicity and the antiarrhythmic action induced by barium chloride,parallel to 2,6-dimethyl aniline.

结果 杀虫脒有局部麻醉作用,杀虫脒和利多卡因的代谢物2.6-二甲基苯胺都有心血管毒性和抗氯化钡诱发的心律失常作用。

The film made by PAn has some miraculous physical and chemical properties ( such as conductivity and electrochromism ,etc.), and could be potentially used in display devices ,secondary battery , gas separation, etc.

掺杂态聚苯胺特有的导电性、电致变色等物理化学性能,使其在显示器件、二次电极、气体分离等方面具有广阔的应用前景。

Acting as an antenna molecule in the supramolecular system, Mg(superscript 2+)-HA remarkably enhances the photoinduced electron transfer efficiency between C60 and an electron donor, N, N-dimethylaniline.

作为超分子体系中的光捕获分子,Mg(上标 2+)-HA能显著地提高C60与N,N-二甲基苯胺的光诱导电子转移反应效率,生成的C60负离子自由基的电子自旋共振光谱信号强度比未加入Mg(上标 2+)-HA时增强了9倍左右。

Objective To investigate the reproductive toxicity of 3,4-dichloroaniline (3,4-DCA), the effect of 3,4-dichloroanilines on sperms of Wistar rats was studied.

目的 研究3,4-二氯苯胺(3,4-DCA)对雄性大鼠精子的影响,以探讨3,4-DCA对雄性大鼠的生殖毒性作用。

The aniline HDN was strongly stressed by the presence of quinoline and DHQ and the HDN of quinoline proceeds exclusively via a pathway which involves fully saturated intermediates on the MCM-41-supported nickel phosphides. The HDN activity of nickel phosphide catalyst was dramatically reduced by the presence of H2S and DBT, probably due to the strong adsorption of H_2S and DBT on active sites which inhibited the adsorption of quinoline.

喹啉和DHQ对苯胺的HDN反应有强烈的抑制作用,喹啉在磷化镍催化剂上几乎全部通过完全加氢饱和路径进行反应。H_2S和二苯并噻吩强烈地吸附在磷化镍催化剂活性中心上,阻碍了反应物分子的吸附,从而对喹啉的HDN反应有强烈的抑制作用。

Optimum conditions are as follows: DMF is used as solvent, compound quaternary ammonium salt as catalyst, n(p-nitrochloro benzene):n=1: 1.2, m:m(p-nitrochloro benzene)=4%, m:m(p-nitrochloro benzene)1:1, and reacted under 155~160℃ for 18 h; reduction reaction is carried out in methanol with Raney nickel, which is used as catalyst; the raw product is added an antioxidant, and distilled simply under reduced pressure to obtain 4-fluoroaniline with excellence quality, purity is over 99.5%, total yield is 89.3%.

实验结果表明,氟化反应的最佳条件为:二甲基甲酰胺为溶剂、复合季铵盐为催化剂,n:n=1:1.2,m(催化剂:m=4%,m:m=1:1,于155~160℃下反应18h;还原反应在甲醇中进行,以阮内镍为催化剂;粗产品加入抗氧剂,减压条件下简单蒸馏得高品位的对氟苯胺。

Using N,N′-dimethy-p-toluidineas the catalyst,bisphenol A-glycidyl methacrylate,the resin matrix in most dental composite restorative materials,was synthesized by the reaction of bisphenol A and glycidyl methacrylate,and characterized by FTIR,~1HNMR and M S.

以N,N-二甲基对甲苯胺为催化剂,双酚A和甲基丙烯酸缩水甘油酯为原料合成了一种常用的口腔修复材料树脂基质———双酚A双甲基丙烯酸缩水甘油酯,并用FTIR1、HNMR和质谱对其结构进行表征。

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