二苯胺

Despite their insolubility in many organic solvents, they are found to be soluble in nitrogen-containing solvents, such as DMF and pyridine.

这些化合物具有较好的稳定性，在胺类或其它含氮的有机溶剂中有较好的溶解度，如苯胺、二甲基甲酰胺或吡啶等。

The low-current STM image showed that polyaniline molecular wires on Au(111) clearly exhibited a hexagonal-lattice ordered arrays, and the nearest neighbor distance in all molecular direction was 〓 The easy and feasible route (supramolecular self-assembly with CD-electropolymerization) promises to prepare an insulated polyaniline molecular wire.

低电流STM图像表明在Au(111)表面的聚苯胺分子线为六角的二维有序，分子与分子之间的最相邻距离为〓这种先进行CD超分子自组装后电聚合的方法可能会成为一类制备导电聚合物绝缘分子导线的新方法。

Goal compound synthesis namely: Take the vanillic acid as outset raw material, obtains 4- hydroxyl - 3- anisole methyl formate with the methyl alcohol reflux conditions, then after the etherification, the nitration, the return to original state, the ring closure response obtains 6- methoxy - 7- animal pen oxygen radical kui zuo lin - 4- alkone, then passes through the chlorination, the substitution aniline, to escape responses again and so on animal pen oxygen radical, etherification to obtain the goal compound; The goal compound and the diethylamine had the amine substitution reaction to obtain TM1, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(N, N- two ethyl aminos) third oxygen radical] kui zuo lin; Through zuo has the etherification with the Austria niter to respond obtains TM2, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(2- methyl - 5- nitryl imidazole) third oxygen radical] kui zuo lin.

目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

For intramolecular electron transfer reactions in solution,the fluctuations of the intramolecular vibrational modes are much faster than that of solvent mode.Thus,the reaction-diffusion equation is commonly used to describe the motion of solvent,with a sink function to treat the vibrational high-frequency mode.Based on this theory-so -called the Sumi-Marcus theory,we proposed an imaginary-time split operator approach to solve the reaction-diffusion equation.The approach is applied to evaluate the intermolecular ET rate between oxazine 1 and N,N-dimethlaniline.By measuring the two average survival times of the donor state probability and the rate constant in long time limit,the full kinetics of the ET is revealed with a variety of sink functions.

对于扩散控制的溶液中的电子转移反应，分子内振动模的运动比溶剂运动快很多，Sumi-Marcus理论提出用反应扩散方程(reaction-diffusion equation)处理溶剂的扩散运动，而分子内的振动用sink函数来表示，我们基于此理论发展了用虚时间分裂算符的方法(imaginary-time Split operator approach)解反应扩散方程，并将其应用于嗪1(oxazine 1，OX1)和N，N-二甲基苯胺分子之间的电子转移反应，Sink函数采用几种不同的微扰表达式，通过计算得到给体几率衰减的两种平均速率和长时间极限下的速率常数，揭示了该体系电子转移过程中的一些动力学性质。

The method of using formaldehyde buffer solution a b sorption-hydrochloric pararosaniline spectrophotometry to determine sulfur diox ide in air has higher sensitivity and good selectivity,and prevents from adoptin g mercurial absorbent.But the conditions in lab are not well controlled,the v alue of reagent blank and standard curvilinear slope can't accord with the one s tipulated in"Methods for Air and Waste Gas Monitoring and Analysis".Some opra tional techniques for SO2 determination in lab are introduced for reference.

文摘：以甲醛缓冲溶液吸收-盐酸副玫瑰苯胺分光光度法测定空气中的二氧化硫，方法灵敏度高，选择性好，避免了使用含汞的吸收液，但如果实验条件控制不好，试剂空白值及标准曲线的斜率就会不符合《空气和废气监测分析方法》中规定的值，本文着重从操作技巧方面对二气化硫测定的实验室质量控制进行分析，仅供参考。

Red light-emitting polymer TPA-CNPPV was synthesized by alternatively introducing TPA and dicyano-substituted phenylene into the main chain.

通过将三苯胺与苯环上被对二氰基取代的PPV单元共聚，利用电子给体与电子受体交替的结构得到了发红光的聚合物TPA-CNPPV。

Methods Using 4-chloro-2-nitroaniline as a starting compound, followed by substitution, reductive cyclization, oxidation, and chlorination, to give the key intermediate 2,7-dichloroquinoxaline (7), which reacted with different phenolic compounds to afford quinoxaline derivatives.

方法以4氯2硝基苯胺为起始原料经取代、还原关环、氧化、和氯代合成了中间体2，7二氯喹喔啉(7)，再在喹喔啉的2位引入不同的取代酚结构单元，合成了一系列共9个新喹喔啉衍生物。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷，包括：γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3，4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3，4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

The synthetic organic chemicals, such as phenol, m cresol, phloroglucinol, phenylamine, 3,5 xylenol, p tertiary butyl phenol, nitrobenzene, tert butanol and chloral were oxidized in supercritical water system.

研究了超临界水氧化系统中合成有机化学品，如酚、间苯三酚、对叔丁基酚、间甲酚、3 ，5-二甲酚、苯胺、硝基苯、叔丁醇、三氯乙醛等的氧化作用。

A new triphenylamine-containing aromatic diamine monomer, 4-[4-(1-adamantyl)phenoxy]-4',4-diaminotriphenylamine, was synthesized from cesium fluoride-mediated N-arylation of 4-(1-adamantyl)-4'-aminodiphenyl ether with 1-fluoro-4-nitrobenzene and subsequent reduction of the dinitro intermediate.

摘要 本研究首先使用 4-(1-adamantyl)-4'-aminodiphenol ether 与 1-fluoro-4-nitrobenzene，於DMSO中，以氟化铯为媒介，进行氮-芳香化反应（N-arylation），随后再进行中间产物的还原反应，制得一个种新型具有三苯胺结构的芳香族二胺单体 4-[4-(1-adamantyl)- phenoxy]-4'，4-diaminotriphenylamine。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。