二苯甲醇

Methods This title compound was prepared using the O-phenylene diamine and the anisaldehyde as the raw material,methanol as the solvent,and the phosphoric acid makes the oxidant.

方法本课题以邻苯二胺和对甲氧基苯甲醛为原料，在甲醇为溶剂，磷酸为催化剂的酸性条件下，一步反应制得2-(4-甲氧基苯基)苯并咪唑。

Some research and analysis on the reaction of 2,4-difluoronitrobenzene and nucleophilic reagent alcohol sodium (methyl alcohol ,ethyl alcohol, propyl alcohol, n-butyl alcohol, t-butyl alcohol, et hl) and the reaction choice of opposite -F in different solvent and conditions have done in this paper.

论文以2，4-二氟硝基苯为主要原料，研究了其与亲核试剂醇钠(甲醇、乙醇、丙醇、正丁醇、叔丁醇等)在不同溶剂中的反应情况，讨论了在几种代表性的溶剂——醇、四氢呋喃、苯、N，N-二甲基甲酰胺中亲核取代反应的情况，研究了温度、反应时间、亲核试剂、溶剂等条件对亲核取代反应的影响。

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核，分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链，设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

The charomatographic conditions of separation and direct dermination of benzophenone-4(MS40), salizyle acid sodium, salol, benzophenone-3(M40), octyl dimethyl PABA(6007), butyl methoxy dibenzoyl methane(1789), octyl methoxyl cinnamate and octyl salicylate(587) from u-Bondapak C18 Column were studied with methanol-water-THF as elution. A HPLC method for these compounds was founded.

研究了用甲醇-四氢呋喃-水作为流动相，从C18柱上分离和测定羟苯甲酮-5-磺酸(MS40)、水杨酸钠、水杨酸苯酯、羟苯甲酮(M40)、对-二甲酸氨基苯甲酸-2-乙基己酯(6007)、4-叔丁基-4-甲氧基二苯甲酸甲烷(1789)、对-甲氧基肉桂酸-2-乙基己酯、水氧酸-2-乙基己酯(587)等8种紫外线吸收剂的色谱条件，建立了用HPLC测定上述物质的方法。

For the synthesis reaction of chalcone, cyclohexanone aldolization and biodiesel,γ-Al_2O_3-NaOH-Na solid superacid has a satisfactory catalytic activity. With hypnone and phenylaldehyde as raw material, amount of catalyst 7.5% wt% of material, mole ratio of hypnone and phenylaldehyde 1:1.1, reaction temperature 40℃, after 3 hours, the yield of chalcone can be up to 96.88%. With cyclohexanone as raw material, amount of catalyst 10% wt% of material, reaction temperature 190℃, after 3 hours, dimmer of cyclohexanone can be up to 85.66%.

将该固体超强碱催化剂应用于查尔酮、环己酮自缩合以及生物柴油的合成反应中，该改性固体超强碱催化剂表现出了良好的催化活性：以苯乙酮和苯甲醛为原料，反应温度为40℃，催化剂用量为反应物总质量的7.5％，苯甲醛与苯乙酮摩尔比为1：1.1，反应3h查尔酮产率可达96.88％；以环已酮为原料，催化剂用量为原料总质量的10％，反应温度为190℃，反应3h，二聚物的总收率可达85.66％；以动物油和甲醇为原料，醇油摩尔为9：1，催化剂用量为动物油质量的2％，反应温度为70℃，反应3h后，生物柴油的收率可达91.8％。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

To study the bioactive components from water soluble extract of the Chinese eaglewood, various column chromatography of Chinese eaglewood led to the isolation of ten compounds. Their structures were elucidated as 2,3-bis(3-hydroxyphenyl)- propan-1-ol (1), [(2R,3R)-3-(4-amino-3,5-dimethoxyphenyl)oxiran-2-yl]methanol (2), 8-chloro-4'- methoxy-5,6,7,3'-tetrahydroxy-2-(2-phenethyl)-5,6,7,8-tetrahydrochromone (3), 4'-methoxy-5,6,7,3'-tetrahydroxy-2--5,6,7,8-tetrahydrochromone (4), the isomer of 4 (5), 4'-methoxy-5,6,7,8-tetrahydroxy-2-(3'-hydroxyphenethyl)-5,6,7,8- tetrahydrochromenone (6), 4'-methoxyisoagarotetrol (7), 6-hydroxy-2-(2-hydroxy-2- phenethyl)-chromone (8), 6-hydroxy-2-(2-phenethyl)-chromone (9), 6-hydroxy-2-(4'- hydroxy-2-phenethyl)-chromone (10), and Guaiacylacetone (11) by means of spectral analysis and comparison with references.

为了进一步发现沉香中具有生理活性的化学成分，本文对国产沉香的水溶性成分进行了研究，从中分离得到11个化合物，通过红外、紫外、质谱、核磁共振(1H-NMR， 13C-NMR， COSY， HSQC， HMBC， ROESY)波谱解析，分别鉴定为：2，3-二(3-羟基苯基)-丙-1-醇(1)，[(2R，3R)-3-(4-氨基-3，5-二甲氧苯基)-2-氧化烯基]甲醇(2)，8-氯-4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(3)，4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(4)，化合物3的差向异构体(5)，4'-甲氧基-5，6，7，8-四羟基-2-(3'-羟基-2-苯乙基)-5，6，7，8-四氢色原酮(6)，4'-甲氧基异沉香四醇(7)，6-羟基-2-(2-羟基-2-苯乙基)色原酮(8)，6-羟基-2-(2-苯乙基)色原酮(9)，6-羟基-2-(4'-羟基-2-苯乙基)色原酮(10)和Guaiacylacetone (11)。

Results61 peaks were separated and 16 constituents were identified, which were composed of about 96.46% of the total essential oil.ConclusionThe main constituents are allyl phenoxyacetate(80.17%), eudesma-4(14),11-diene(6.83%), 2,3-dihydro-3-methyl-3-benzofuran-methanol(2.94%), limonene(1.63%). The essential oil in Oenanthe javanica DC from Dali, Yunnan can be used in the food service industry and the cosmetic industry as spices.

水芹挥发油中的主要成分为苯氧乙酸烯丙酯（80.17%）、桉叶-4(14)，11-二烯（6.83%）、2，3-二氢-3-甲基-3-苯并呋喃甲醇（2.94%）、柠檬烯（1.63%），云南大理产水芹挥发油中萜类化合物及其衍生物含量在13%以上，苯氧乙酸烯丙酯含量高，可用作食品工业和化妆品工业的香料。

ConclusionThe main constituents are allyl phenoxyacetate(80.17%), eudesma-4(14),11-diene(6.83%), 2,3-dihydro-3-methyl-3-benzofuran-methanol(2.94%), limonene(1.63%). The essential oil in Oenanthe javanica DC from Dali, Yunnan can be used in the food service industry and the cosmetic industry as spices.

水芹挥发油中的主要成分为苯氧乙酸烯丙酯（80.17%）、桉叶-4(14)，11-二烯（6.83%）、2，3-二氢-3-甲基-3-苯并呋喃甲醇（2.94%）、柠檬烯（1.63%），云南大理产水芹挥发油中萜类化合物及其衍生物含量在13%以上，苯氧乙酸烯丙酯含量高，可用作食品工业和化妆品工业的香料。

The synthesis method of the invention is as follows: first, 5-amino-2-(p-aminophenyl)- benzoxazole and aliphatic diacid are respectively recrystallized; NMP is distilled; solubilizer is dried; second, in an atmosphere of nitrogen, after Py and NMP are mixed evenly and added to a sealed reactor, the solubilizer is added into the reactor, followed by the 5-amino-2-(p-aminophenyl)- benzoxazole, then the mixture in the reactor is stirred; second, in an atmosphere of nitrogen, the mixture in the second step is stirred and heated to 50-150 DEG C, then the aliphatic diacid is added, followed by TPP for condensation; fourth, after methanol is poured into the reactor, the sediment is separated out from the mixture, filtered, washed and dried, so the semi-aromatic polyamide containing oxazole ring is obtained.

本发明的合成方法如下：一、分别重结晶5-氨基-2-苯并唑与脂肪族二酸；蒸馏NMP；干燥增溶剂；二、在氮气气氛下，Py与NMP混匀后加入密封的反应器中，再加入增溶剂，然后加入5-氨基-2-苯并唑，搅拌；三、在氮气气氛下，将步骤二的混合液搅拌并升温至50℃～150℃后加入脂肪族二酸，再加入TPP后缩聚；四、再倾入甲醇析出沉淀，过滤，清洗沉淀，再干燥；即得到含唑环半芳香聚酰胺。

My first article for Screen Power Magazine, which is to this day is the official magazine of Jackie Chan, was a DVD review of the Hong Kong actioner Gen-X Cops, starring Nicholas Tse and Daniel Wu.

我的第一篇文章为屏幕力量杂志，在对这天是Jackie Chan 正式杂志，是香港actioner Gen X 警察的DVD 回顾，担任主角Nicholas Tse 和丹尼尔吴。

His lips grazed hirs, Now what are you going to do?

他的唇使吃草了 hirs，现在你将要做什麼？