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Cloud point curves from light scattering experiment verify the calculation results;The agreement between the cloud point curve s and the binodal is quite well.

用浊点测定、傅里叶变换红外光谱和微差扫描热分析等方法研究了苯乙烯-顺丁烯二酸酐共聚物与苯乙烯-丙烯腈共聚物共混物的相容性。

The major products were methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene, vinyl-substituted cyclopentene derivatives and C5/C6 isomers (pentadiene, methyl-substituted cyclopentene derivatives, cyclohexene, hexadiene and methyl-substituted cyclopentadiene derivatives), and the main primary products were determined to be C1~C4 compounds, cyclopentadiene, benzene, toluene and vinyl-substituted cyclopentene derivatives.

热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5, C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物),其中, C1~C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物。

The major products were methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene, vinyl-substituted cyclopentene derivatives and C5/C6 isomers pentadiene, met...

热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5,C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物),其中,C1~C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物。

A new organic compound, trans-2--5-dimesitylborylthiophene (abbreviated as DMASBT, 5) with dimesitylboryl, dimethylamino and styryl-thiophene as electron acceptor, electron donor and conjugate bridge respectively, was synthesized. Its crystal structure determined by X-ray diffraction method indicates that the B-C bond between B atom and it bridge is obviously shorter than those of between B atom and mesityl groups. This remarkably strengthened B-C bonding can be regarded as an evidence of additional p-7t conjugation between the B atom and n bridge.

合成了以含硼基团为电子受体,以二甲胺基为电子给体,以苯乙烯基噻吩为共轭桥的新化合物2-[(4'-N,N-二甲胺基)苯乙烯基]-5-二米基硼-噻吩 trans-2-[(4'-N, N-dimethylamino) styryl]-5-dimesitylboryl-thiophene(简写为DMASBT,5)。X射线衍射方法测定其单晶结构表明,硼原子与π共轭桥之间的硼碳键相对于其它的硼碳键明显缩短,硼与π共轭桥之间存在除了σ键之外的p-π共轭作用。

A CR/polystyrene IPN blend was prepared by stepwise synthesis based on CR and styrene monomer and using divinyl benzene as crosslinking agent of PS.

以CR和苯乙烯单体为原料,二乙烯基苯为苯乙烯的交联剂,采用分步合成法制备CR/聚苯乙烯互穿网络共混物。

Firstly, partial sulfonated polystyrene were prepared by solution polymerization with the raw materials of styrene, sodium styrene sulfonate and divinyl benzene; Secondly, the SPS/OMMT nanocomposites were prepared by intercalation polymerization with the monmers and organically modified montmorillonite.

首先,利用NMP为溶剂,BPO引发苯乙烯、苯乙烯磺酸钠、二乙烯基苯溶液共聚;同时,采用高分子的单体与有机蒙脱土插层聚合制备了磺化聚苯乙烯阳离子树脂/蒙脱土复合材料。

Since many phenylvinyl ketone derivatives showed a certain anti- inflammatory activity, the indolyl group is introduced to this skeleton, and thus a series of 1, 4-penten-3-one derivatives characteristic of the structures of both phenylvinyl ketone and indole have been synthesized and characterized by elemental analyses, MS, UV-vis, and 〓 NMR as well. All these compounds are found to be trans-isomers.

考虑到苯乙烯酮类化合物的抗炎活性,本文将吲哚基团引入到该类化合物上,设计合成了一系列新的兼具苯乙烯酮和吲哚二者结构特征的1,4-戊二烯-3-酮衍生物Al-A24,并对其进行了表征,发现所有这些化合物均为反式构型。

The organic montmorillonite VC18-MMT was prepared by the exchanging inorganic cations with vinylbenzyldimethyloctadecylammionun chloride which could be co-polymerized with styrene.The predispersion of VC18-MMT was realized via sonicating the suspension of the montmorillonite particles in emulsifier solution,and then the styrene was added into the system and the in situ emulsion polymerization was carried out to prepare PS/VC18-MMT nanocomposites.

以可与苯乙烯发生共聚的阳离子表面活性剂乙烯苄基二甲基十八烷基氯化铵为插层处理剂改性蒙脱土(VC18-MMT),有机蒙脱土在超声波强剪切作用以及乳化剂作用下预分散在乳化剂溶液中,然后引入苯乙烯单体进行原位乳液聚合制备聚苯乙烯/蒙脱土纳米复合材料。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-bPCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过RAFT活自由基聚合方法制备聚(苯乙烯-b-对氯亚甲基苯乙烯)二嵌段共聚物,其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应,最终获得了含有1,2,3-三氮唑官能团的聚苯乙烯二嵌段共聚物,核磁共振谱表征结果证明,PS-b-PCVB中的氯亚甲基完全转变成了1,2,3-三氮唑基团。

The diblock copolymer of styrene and chloromethyl-4-vinyl-benzene was obtained by means of reverse addition fragmentation chain transfer reaction living free radical polymerization. The chloromethyl groups in PS-b-PCVB were transformed into azidomethyl groups, and then into 1,2,3-triazol groups via click chemistry. The diblobk copolymer containing 1,2,3-triazol groups was thus obtained. The results from NMR spectra suggested a complete transformation from chloromethyl groups to triazol groups.

通过可逆加成-断裂链转移聚合活性自由基聚合方法制备了聚(苯乙烯-b-对氯亚甲基苯乙烯)二嵌段共聚物,其中的氯亚甲基侧基经叠氮化反应后与丙炔醇进行点击反应,最终得到了含有1,2,3-三氮唑官能团的聚苯乙烯二嵌段共聚物,核磁共振谱表征结果证明,PS-b-PCVB中的氯亚甲基完全转变成了1,2,3-三氮唑基团。

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