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二苯乙烯

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BACKGROUND: Chinese herb tuber fleeceflower root can enhance learning and memory ability and anti-cerebral ischemia ability in rats,while 2,3,5,4'-tetrahydroxystilbene-2-O-β-D-glucoside,the main effective component of tuber fleeceflower root,has very strong brain-protecting ef fects such as anti-oxidation and anti-aging.

背景:中药何首乌能够提高小鼠学习记忆和抗脑缺血能力,而二苯乙烯苷是何首乌的主要有效成份,具有较强的抗氧化与延缓衰老等脑保护作用。

The synthesis of a novel rotaxane containing α-CD(α-cyclodextrin) as the macrocycle,stilbene as the 'string' and the isophthalic acid as stopper via a palladium-catalyzed Suzuki coupling reaction in water at room temperature and supramolecular self-assembly was reported.

通过醋酸钯催化的Suzuki偶联反应,在室温下于水溶液中通过超分子自组装制备了以α-CD为大环,异酞酸为端塞,二苯乙烯衍生物为链的新型超分子轮烷。

They were Pinosylvin, pinosylvin monomethyl ether and pinosylvin dimethyl ether. PSD was only found in part of the samples where was low in concentration.

在抗腐朽的木材心材样品中,总二苯乙烯类物质的平均含量为7.43mg/g(试验林1)和5.10mg/g(试验林2);在易腐朽的心材样品中的含量为6.30mg/g(试验林1)和4.77mg/g(试验林2)。

Finally, a comprehensive model was proposed to elucidate the main characteristics and essential time constants of the cis/trans photoisomerization processes among the three 1,4-distyrylbenzene isomers.

最后,我们提出一套完整的动力学模型来描述对-二苯乙烯基苯的顺-反异构化的特徵及其异构化的速率。

Twenty-seven compounds were isolated from the methanol extract of the stems of Pinus massoniana by means of chromatographic methods, and their structures were elucidated as 8(14),15-Pimaradien-19-oic acid (1), Pimaric (2), Podocarpic acid (3), 12-Hydroxydehydroabietic acid (4), Dehydroabietic acid (5), 15-Hydroxydehydroabietic (6), 3β-Methoxyserrat-14-en-21-one (7), 3β-Hydroxy- serrat- 14-en-21-one (8), 3β-Methoxyserrat-14-en-21-one-30-al (9),(24R)-Stigmst- 4-ene-3-one (10),β-sitosterol (11),-3-Hydroxy-5-methoxy-stilbene(12), 4-Hydroxy-3- methoxycinnamaldehyde (13),-Ferulic acidtetracosyl ester (14), Alkylferulates (15), Pinocembin (16), Coniferaldehyde (17), Matairesinol (18),-Nortrachelogenin (19), Balanophonin (20), Cedrusin (21),-Pinoresinol (22), Tanegoside (23), 1,2-Bis-(4-hydroxy-3- methoxyphenyl)-propane-1,3-diol (24),(1S*, 2S*)-1-(4- Hydroxyphenyl) glyceri...

同时对马尾松枝条的甲醇提取物利用各种色谱技术进行了分离纯化,并利用现波谱技术鉴定了27个化合物的结构,分别为:8(14),15-Pimaradien-19-oic acid (1)、海松酸(2)、罗汉松酸(3)、12-羟基脱氢松香酸(4)、脱氢松香酸(5)、15-羟基-脱氢松香酯(6)、3β-甲氧基-锯齿石松-14-烯-21-酮(7)、3β-Hydroxyserrat-14-en-21-one (8)、3β-Methoxyserrat-14-en-21– one-30-al (9)、(24R)-豆甾-4-烯-3-酮(10)、-3-羟基-5-甲氧基-二苯乙烯(12)、4-Hydroxy-3-methoxycinnamaldehyde (13)、-Ferulic acidtetracosyl ester (14)、Alkylferulates (15)、Pinocembin (16)、Coniferaldehyde (17)、罗汉松树脂酚(18)、 Balanophonin (20)、tanegoside (23)、1,2-Bis-(4-hydroxy- 3-methoxyphenyl)-propane- 1,3-diol (24)、(1S*,2S*)- 1-(4-hydroxyphenyl)glycerins (25)、(1R*,2R*)-1-(4-hydroxy- phenyl)gly-cerins (26)和赤松素(27)。

Novel styryl derivatives with triphenylamine as donor and triazine as acceptor were synthesized. The two-photon absorption cross section for Ⅴ-1,Ⅴ-2 and Ⅴ-3 were determined to be 0.31×10〓cm〓/Gw, 0.365×10〓cm〓/Gw and 1. 64×10〓cm〓/Gw by femtosecond Z-san technology, respectively.

合成了以三苯胺为电子给体、三嗪为电子受体的新型二苯乙烯类化合物,用飞秒开口z-扫描测量化合物Ⅴ-1、Ⅴ-2和Ⅴ-3的双光子吸收截面分别为0.31×10〓cm〓/Gw、0.365×10〓cm〓/Gw和1.64×10〓cm〓/Gw。

The two-photon absorption cross-sections of these styryl derivatives were determined by Z-scan technique, and the benzothiazolium derivatives exhibited the largest TPA cross-sections (10〓s·cm〓/photon) and the best power limiting ability at high operable incident intensity. The results show that the benzothiazolium derivatives are promising organic compounds as two-photon absorption optical limiting materials. 2. Several organic dyes active to 800nm femtosecond laser with D-π-A structure were designed and synthesized.

研究了它们的上转换荧光、上转换激射和光限幅行为,通过改变染料分子共轭体系的大小,首次实现了在576nm-635nm范围内的双光子上转换激光波长的调节,其中噻唑啉碘盐类二苯乙烯化合物的双光子上转换激射峰(576nm)是迄今在1064nm皮秒激光作用下能够得到的最短波长的激光;阴离子显著改变上转换激射效率,但对上转换荧光峰和激射峰的位置影响很小;增加溶液的浓度,上转换荧光光谱和激射光谱红移,并在一定的浓度范围内,能够有效的提高上转换激射效率;利用Z-扫描技术测定了染料分子的双光子吸收截面,发现苯并噻唑类染料分子的双光子吸收截面高达10〓s·cm〓/photon,而且在较大的入射光强范围内,这类染料分子具有较大的光限幅能力,是一类作为双光子吸收光限幅材料很有潜力的染料分子。

Objective: To study lipid-regulating action of 2, 3, 5, 4′-tetrahydroxy stilbene-2- O-β-D -glucopyranoside from Polygonum multiflorum on experimental model hyperlipidemic rats.

中文摘要:目的:研究何首乌的2,3,5,4′-四羟基二苯乙烯-2- O-β-D -葡萄糖苷对实验性高脂血症大鼠的调脂作用。

Objective To explore the effects of 2, 3, 5, 4'-tetrahydroxy stilbene-2-β-D-glycoside on the over-expression and aggregation of α-synuclein in vitro.

目的 观察二苯乙烯苷在体外试验中对COS-7细胞株过度表达α-synuclein蛋白的影响。

Based on the objective lens and voice coil motor of the current DVD pickup head,according to photobleaching three-dimensional (3D) optical information storage's theory of two-photon absorption,the Ti∶sapphire femtosecond pulse laser was used as written optical beam and reading optical beam of two-photon three-dimensional optical storage voice coil motor was carried through multiplayer choice, and the storage and readout experimental study of binary format code with two-photon photobleaching in the new photobleaching material consisting of stilbene derivant was conducted.

基于现有的DVD光头物镜与音圈电机,根据光致漂白的双光子吸收三维光信息存储原理,以钛蓝宝石飞秒脉冲激光进行双光子光信息写入和读出,利用音圈电机进行选层,在新型光致漂白材料二苯乙烯衍生物中进行光致漂白二进制编码信息的存储和读出实验研究;实现了三层光信息存储,信息点间距和信息层间距分别为4 μm和15 μm;用Matlab软件读出信息的信号强度并对其进行了识别,识别结果与写入的二进制编码信息完全一致。

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