二苯乙二酮

Methoxycarbonyl-4-(4-methoxyphenyl )-6-methyl-3, 4-dihydropyrimidine-2(1H)-one was synthesized from anisaldehyde, methyl acetoactate and urea in presence of HF-1O1 strong acidic ion-exchange membrane.

在HF-101强酸性离子交换膜的存在下，由对羟基苯甲醛、乙酰乙酸甲酯与脲一步合成了5－甲氧羰基－4－（4－甲氧苯基）－6－甲基－3，4－二氢嘧啶－2(1H)－酮。

Goal compound synthesis namely: Take the vanillic acid as outset raw material, obtains 4- hydroxyl - 3- anisole methyl formate with the methyl alcohol reflux conditions, then after the etherification, the nitration, the return to original state, the ring closure response obtains 6- methoxy - 7- animal pen oxygen radical kui zuo lin - 4- alkone, then passes through the chlorination, the substitution aniline, to escape responses again and so on animal pen oxygen radical, etherification to obtain the goal compound; The goal compound and the diethylamine had the amine substitution reaction to obtain TM1, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(N, N- two ethyl aminos) third oxygen radical] kui zuo lin; Through zuo has the etherification with the Austria niter to respond obtains TM2, namely 4- benzene amino - 6- methoxy - 7- [2- hydroxyl - 3-(2- methyl - 5- nitryl imidazole) third oxygen radical] kui zuo lin.

目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

The other for: safrole, sassafras oil, safrole different 82 yuan / kg; 1 - phenyl -2 - propanone 2,500 yuan / kg; 3.4 dioxane methylene diphenyl -2 - propanone 7200 yuan / ton; Piperonal 1,000 yuan / kg; N-acetyl-o-amino benzoic acid 11500 yuan / ton; anthranilic acid 15,500 yuan / ton; Phenylacetate 15,000 yuan / ton; acetic anhydride 9900 yuan / ton; trichloromethane 4100 yuan / ton ; anhydrous ether 8500 yuan / ton; piperidine 58000 yuan / ton; methyl ethyl ketone 10,000 won / ton; sulfate 1,200 yuan / ton; hydrochloride 400 yuan / ton; ethanol 4200 yuan / ton.

另供：黄樟素、黄樟油、异黄樟素82元/公斤；1-苯基-2-丙酮2500元/公斤；3.4 亚甲基二氧苯基-2-丙酮7200元/吨；胡椒醛1000元/公斤；N-乙酰邻氨基苯酸11500元/吨；邻氨基苯甲酸15500元/吨；苯乙酸15000元/吨；醋酸酐9900元/吨；三氯甲烷4100元/吨；无水乙醚8500元/吨；哌啶58000元/吨；甲基乙基酮10000元/吨；硫酸1200元/吨；盐酸400元/吨；无水乙醇4200元/吨。

The other for: safrole, sassafras oil, safrole different 82 yuan / kg; 1 - phenyl -2 - propanone 2,500 yuan / kg; 3.4 dioxane methylene diphenyl -2 - propanone 7200 yuan / ton; Piperonal 1,000 yuan / kg; N-acetyl-o-amino benzoic acid 11500 yuan / ton; anthranilic acid 15,500 yuan / ton; Phenylacetate 15,000 yuan / ton; acetic anhydride 9900 yuan / ton; trichloromethane 4100 yuan / ton ; anhydrous ether 8500 yuan / ton; piperidine 58000 yuan / ton; toluene 5200 yuan / ton; methyl ethyl ketone 10,000 won / ton; sulfate 1,200 yuan / ton; hydrochloride 400 yuan / ton; anhydrous Ethanol 4200 yuan / ton.

另供：黄樟素、黄樟油、异黄樟素82元/公斤；1-苯基-2-丙酮2500元/公斤；3.4 亚甲基二氧苯基-2-丙酮7200元/吨；胡椒醛1000元/公斤；N-乙酰邻氨基苯酸11500元/吨；邻氨基苯甲酸15500元/吨；苯乙酸15000元/吨；醋酸酐9900元/吨；三氯甲烷4100元/吨；无水乙醚8500元/吨；哌啶58000元/吨；甲苯5200元/吨；甲基乙基酮10000元/吨；硫酸1200元/吨；盐酸400元/吨；无水乙醇4200元/吨。

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核，分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链，设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

Due to their applications in magnetic, optical, electronic and catalyst, polynuclear lanthanide clusters are of importance. In this part, a series of nanowheel-shaped nonanuclear lanthanide clusters,〓〓(Ln=Sm~Tm; BA=benzoylacetone), were prepared and characterized. Each complex can exist in three phases, i. e., cubic, tetragonal and triclinic.

本论文第二部分在醇溶液中以三乙胺调变溶液pH，利用β-二酮配位方式的灵活性成功地构筑了一系列结构稳定、纳米尺度轮状的九核稀土配合物〓〓（Ln=Sm~Tm；BA=苯甲酰丙酮），并在不同溶剂中重结晶分别得到了三斜、四方以及立方三种晶型的晶体。

The details and results are summarized below:(1)An ABC style three component cascade reaction of aromatic aldehydes, aromatic amines and diethyl malonic ester or cyclohexanone has been developed.

论文从苯炔和亚胺出发，设计并系统研究了4种新的多组分串联反应，主要内容和结果如下：(1)发展了一种芳醛、芳胺和丙二酸二乙酯或环己酮的ABC型三组分串联反应。

One of these compounds, 2-diethyl- aminoethyl-5--(4-methoxybenzylidene) cyclo- pentanone hydrochloride (T81) possessed sig- nificant antiinflammatory and analgesic ac- tivity when administered orally.

Ⅲ类化合物完全无抗癌活性，对其中一个化合物2-二乙胺乙基-5--（4-甲氧基苯亚甲基）环戊酮盐酸盐（T81）试验结果表明，它经口给药时具有显著的抗炎、镇痛活性。

These products include sodium percarbonate, percarbamide, 4Na 2SO 4·2H 2O 2·NaCl adduct, tertiary amine oxides, hydrazine hydrate, dihydroxy benzene, quaternary ammonium salt hydrogen peroxide and methylethyl ketone oxime.

介绍了近期国外过氧化氢在部分化学品合成中应用研究新进展，产品包括过碳酸钠、过碳酰胺、4Na2 SO4·2H2 O2 ·NaCl加合物、叔胺氧化物、水合肼、二羟基苯、季铵盐过氧化氢和甲乙酮肟。

Inorganic chemistry ; hydrogen peroxide ; review ; sodium percarbonate ; percarbamide ; 4Na 2SO 4·2H 2O 2·NaCl adduct ; tertiary amine oxides ; hydrazine hydrate ; dihydroxy benzene ; quaternary ammonium salts hydrogen peroxide ; methylethyl ketone oxim

无机化学；过氧化氢；综述；过碳酸钠；过碳酰胺； 4Na2SO4·2H2O2·NaCl加合物；叔胺氧化物；水合肼；二羟基苯；季铵盐过氧化氢；甲乙酮肟；合成；催化剂；质量；安定性；收率

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。