二苄基

CA-CTSs including N,O-carboxymethyl chitosan,N,O-1-carboxyethyl chitosan (N,O-1-CEC),N,O-2-carboxyethyl chltosan(N,O-2-CEC),N-carboxymethyl chitosan and N-1-carboxyethyl chitosan(N-1-CEC) are quaternized using active quaternary salts prepared in laboratory.5 series including 25 kinds amphoteric chitosans characterized with polymeric ampholyte,in which 24 kinds are synthesized firstly,are obtained, 2-Hydroxypropyl dimethylbenzyl ammonium N,O-(1-carboxyethyl) chitosan chloride (GDMBA-N,O-1-CEC) is hydrolyzed into serial low molecular weight GDMBA-N, O-1-CEC with acid as catalyst and microwave as assistant instrumentality innovately.

以合成的活性季铵盐改性了N，O-羧甲基壳聚糖、N，O-1-羧乙基壳聚糖(N，O-1-CEC)、N，O-2-羧乙基壳聚糖(N，O-2-CEC)、N-羧甲基壳聚糖和N-1-羧乙基壳聚糖(N-1-CEC)等羧烷基壳聚糖，得到5个系列25种具有两性高分子电解质特征的新季铵化羧烷基壳聚糖，其中24种为首次合成；创新提出以微波辅助酸催化的方法催化2-羟丙基二甲基苄基-N，O-(1-羧乙基)壳聚糖氯化铵(GDMBA-N，O-1-CEC)水解，得到了低分子量的GDMBA-N，O-1-CEC。

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

Benzyl bromide was synthesized from potassium bromide ,a by-product from synthesis of 2-hydroxy-4-n-octyloxybenzophenone(UV-531),and benzoic alcohol in the presence of concentrated sulfuric acid.

溴化钾作为工业生产2-羟基-4-正辛氧基二苯甲酮的副产品，在浓硫酸存在的条件下，与苯甲醇进行反应合成苄基溴。

Based on the tissue culture, the effect of N-phenyl-N＇-1,2,3-thiadiazol-5-ylurea, 6- benzyla minoprine（6-BA） and 1-Naphthylacetic acid on spore germination, protonema develop- ment and bud differentiation in Entodon challenged was investigated in this paper. The whole process was observed and taken pictures. The results show that TDZ, 6-BA and NAA have no significant effect on the spore germination. During the process of protonema development, 1.0 mg/L NAA can promote the primary development of protonema significantly, and 0.4 mg/L TDZ promotes branches formation in inter- mediate stage of the protonema development.

：研究了3种植物生长调节剂苯基噻二唑基脲、6-苄基腺嘌呤（6-BA）、萘乙酸对密叶绢藓孢子萌发、原丝体发育及芽体发生的影响，并对整个发育过程进行了显微观察和照相，结果表明：（1）3种植物生长调节剂对密叶绢藓孢子萌发影响不显著；（2）在原丝体发育阶段，1.0mg／LNAA对原丝体初期的发育促进效果显著，0.4mg／LTDZ对原丝体发育中期分枝的形成促进效果显著，6。

In the second part, the active tautomer of the HPPD inhibitor, 2-[2-nitro-4--benzoyl]-1,3-cyclohexanedione was studied bythe quantitative structure-activity relationship.

其后，我们利用三维构效关系对HPPD酶的高效抑制剂2-(2-硝基-4-三氟甲基苄基)-环己烷-1，3-二酮的活性结构进行了研究。

Di(3,4-dimethyl)benzylidene xylitol as synthesized in the lab from 3,4-dimethyl benzaldehyde and xylitol, and a series of polypropylene samples were prepared based on the amount of the nucleating agent, DMDBX used.

以3，4-二甲基苯甲醛和木糖醇为原料合成1，3-2，4-二（3，4-二甲基）亚苄基木糖醇，将DMDBX作为成核剂使用溶液沉淀法制备DMDBX质量分数分别为0、0.1%、0.3%、0.5%、0.7%、0.9%的聚丙烯样品，采用红外光谱仪、差示扫描量热仪、X射线衍射仪和偏光显微镜等方法，研究了DMDBX对PP结晶结构和结晶性能的影响。

The third part of this thesis is reactive simulating calculation In this section, some well-known auxiliaries are selected to compute in density functional theory B3LYP on Gaussian 03, from which the relationship between reaction active energies of transition states and enantiomeric excess of chiral products homoallylic alcohols isobtained based on relative reactive ratio theory. Using this relationship, calculations on the reaction of more than eight auxiliaries with four other aldehydes are carried out in AMI and MNDO, proving that N,N\'-dibenzyl tartamide has higher enantioselectivity than others in this reaction.

第三部分为计算化学部分，运用密度泛函理论B3LYP方法在Gaussian03软件上对已经报道的几种手性配体参与的醛不对称烯丙基化反应过程进行模拟计算，基于相对反应速率理论找出两种构型过渡态间活化能的差异与产物光学收率之间的关系；并以此为基础，用AM1和MNDO方法对上述合成的几种配体控制的反应过程进行量化计算，从而在理论上证实了N-苄基酒石酸二酰胺配体在醛的不对称烯丙基化反应中具有较高的立体选择性。

In a similar way, using N,N\'-dibenzyl tartamide as auxiliary,-(2-methyl)allyl-2-chloro-phenyl-methyl azide, a vital intermediate of Repaglinide, can be prepared via asymmetric allylation of o-chlorobenzaldehyde in

产物经氧化和碘加成内酯化反应得到阿伐他汀中间体(3R，5S)-3-羟基-5-碘甲基戊内酯(10)；将N-苄基酒石酸二酰胺用于邻氯苯甲醛的不对称烯丙基化反应以较高光学收率得-甲基烯丙基-2-氯苯基-甲基醇

Thiobarbituric acid was synthesized by sulfourea and diethyl malonate in sodium alcohol and 5-Arylidene thiobarbituric acid was prepared by the Knoevenagel condensation reaction from benzaldehyde and thiobarbituric acid.

采用丙二酸二乙酯和硫脲在乙醇钠存在下合成了硫代巴比妥酸，再分别采用固相反应和水相反应，由硫代巴比妥酸和苯甲醛经Knoevenagel缩合反应，制备了5-亚苄基硫代巴比妥酸。

An important intermidiate 2-butyl-4-chloro-5-(4-bromomethyl phenoxy) pyridazinone 3 was first obtained from 4,5-dichloropyridazinone using two different methods. Compounds 4a～4l were synthesized by the reaction of 3 with different oximes.

从2-叔丁基-4，5-二氯哒嗪酮出发，以两种方法合成了中间体2-叔丁基-4-氯-5-(4-溴甲基苯氧)哒嗪酮(3)。3与肟反应合成了含哒嗪酮的苄基肟醚类化合物4a～4l。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。