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Part 7 is the conclusion of this paper.The main research in this paper includes:1 The 22 mixed ligand complexes were synthesized in which bipyridine-, phenanthroline 5-nitrophenanthroline , phenanthroline- 5,6-dikentone and biquinoline are the first ligand and chlorine ion phenylalanine, tyosine asparagic radical 2.6-diaminocaproic radical tryptophan , histidine malonate(mal2-) benzyl malonate (bmal2-) phenethtyl malonate (pmal2-) are the second ligand.

本文具体研究内容包括四部分:一、合成了以联吡啶、邻菲啰啉、5—硝基邻菲啰啉、邻菲啰啉-5,6-二酮、联喹啉为第一配体,以Cl~-、苯丙氨酸根、酪氨酸根、天冬氨酸根asp~(2-、赖氨酸根、色氨酸根、组氨酸根、丙二酸根mal~(2-、苄基丙二酸根bmal~(2-和苯乙基丙二酸根pmal~(2-为第二配体的共22个混配配合物,制备了其中6个混配配合物和1个单配体配合物单晶,用X-射线单晶衍射法测定了晶体结构。

Chapter 4: Synthesis of 1,5-diary 1-1,4-pentadien-3-ones from acetone or benzalacetone with aromatic aldehydes results in 86-97% yield with potassium hydroxide as catalyst under ultrasound irradiation in 5-60min.

为合成氰基环己醇找到一条方便高效的合成方法。第四章:研究了超声辐射下,以氢氧化钾为催化剂,芳香醛与丙酮及亚苄基丙酮之间反应合成1,5-双苄基-1,4-戊二烯-3-酮。

In this paper,- and (5)-2,2'-diethynyl-1,1'-binaphthyl with highly stable chiral configurations were employed as structural templates, and a new type of helical cyclophane compounds-3 and-3 were synthesized in enantiopure form by the introduction of benzyl sulfone through Sonogashira coupling reaction, followed by the treatment of disulfone with lithium diisopropylamide.

基於2,2'-二取代的联萘衍生物在手性构型上高度稳定的特点,分别从光学活性的-和-2,2'-二乙炔基-1,1'-联萘结构模板出发,通过Sonogashira偶连反应导入苄基碸,然后用二异丙基氨基锂处理制得的联萘二碸成功地合成了一种新的螺旋环芳分子-对映异构体-3和-3。

Dibenzyl oxalate was synthesized from oxalic acid, potassium hydroxide and benzyl bromide under microwave irradiation using tetrabutylammonium bromide as phase-transfer catalyst and polyethylene glycol-200 as solvent.

在微波辐射条件下,以草酸、氢氧化钾和溴化苄为原料,四丁基溴化铵为相转移催化剂,聚乙二醇200为溶剂合成了草酸二苄酯,并通过熔点和红外光谱对产物的结构进行了表征。

The second synthetic strategy commenced from butane-1,4-diol 50, which underwent monobenzylation, Swern oxidation, enolization followed by acetylation and debenzylation to yield an intermediate 46 in an overall yield of 54% in a 4-step procedure.

第二条路线从1,4-丁二醇50开始,这个化合物经过单苄基化、Swern氧化、烯醇化随后乙酰化和脱苄基化共4步反应得到中间体46,总产率54%。

An unusual substitution of 5-fluorouracils by the reaction of lithium salts of 1,3-dialkyl-5-fluorouracil with benzyl bromide is described.

1,3-二烷基-5-氟尿嘧啶的锂盐与苄基溴进行苄基化反应时产生了异常的反应结果。

L-Phenylalanine was then obtained by alkylation of N- glycine ethyl ester with benzyl bromide in the presence of an asymmetric phase-transfer catalyst-N-benzyl-cinchonine chloride, followed by hydrolysis of the resulting product.

以甘氨酸乙酯盐酸盐和二苯甲酮为起始原料合成了N-二苯亚甲氨基乙酸乙酯,后者在手性相转移催化剂-N-苄基氯化辛可宁诱导下与烷基化试剂溴化苄发生不对称相转移催化烷基化反应,水解得到L-苯丙氨酸。

The experiment consist of two parts :the first one research nucleophilic addition of m-dinitrobenzene, nucleophilic reagent is benzyl cyanide; the second one synthesize 2,4-dihydorxybenzophenone from 2,4-dichlorobenzophenone and NaOH.

实验分为两部分:第一部分研究了间二硝基苯的亲核加成反应,亲核试剂为苄基腈;第二部分是用2,4-二氯二苯甲酮与氢氧化钠反应制备2,4-二羟基二苯甲酮。

The algicidal performances of monomer dimethyldiallylammonium chloride and a commercial algicide dodecyldimethylbenzylammonium chloride( 1227 ) were contrasted with that of PDM.

对两种营养化的模拟水体,通过灭藻实验,研究了聚二甲基二烯丙基氯化铵系列样品的静态灭藻性能,考察了加药量、作用时间、特征黏度等因素对灭藻性能的影响规律,并与聚合物单体二甲基二烯丙基氯化铵及市售灭藻剂十二烷基二甲基苄基氯化铵(1227)的灭藻性能进行了对比。

Several glycosyl phosphate and phosphonates, as inhibitors of AGPase, were synthesized.In the synthesis of β〓-6 linked oligosaccharide phosphonates, A new method was developedfor preparation of 〓,6-〓-di-acetyl-2,3,4-〓-tri-benzyl-D-hexoses by acetylation of benzylatedmethyl glycosides in high yield under the conditions of 〓 and cat.〓.

合成了一些磷酸酯及其类似物作为嗜热AGPase的抑制剂,在研究β 1-6连接的寡糖膦酸酯的合成中,发现了制备1,6-〓-二乙酰基-苄基保护糖的新方法:苄基保护的糖苷在醋酐和催化量的硫酸作用下,在0℃反应进行7-10 min,可以选择性、高收率地得到此化合物。

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推荐网络例句

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。