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Study prepared method of dimethylbenzyl carbinol and seek the best technologic conditions and craft route of dimethylbenzyl carbinol.

研究二甲基苄基甲醇制备方法,寻找制备二甲基苄基甲醇的最佳工艺条件和工艺路线。

With trimethyl,4-dodecylbenezyl ammonium chloride and 18-crown-6 as pase-transfer catalysts, the azidation of polyepichlorohydrin in poly and H2O were studied. The reaction discipline and mechanism were discussed. The results show that the system with trimethyl, 4-dodecylbenezyl ammonium chloride as phase transfer catalyst and PEG as medium is a safe and effective approach to glycidyl azide polymer preparation, and azidational ratio of PECH can reach 97% above within 15 h.

研究了氯化十二烷基苄基三甲基铵和18-冠-6为相转移催化剂时端羟基聚环氧氯丙烷在聚环氧乙烷和水为介质中的叠氮化反应,探讨了反应规律和反应机理,结果表明:以PECH为介质,十二烷基苄基三甲基氯化铵(TMDA-1)为相转移催化剂的反应体系,可在15h内使PECH叠氮化转化率达到97%以上,无主链断裂等副反应,是一条较为安全快速的制备叠氮粘合剂的方法。

Acridone 1 reacted with benzyl chlorides 2 in NaH/DMF/KI to give 10-benzyl-9-acridones 3 in high yields. Subsequent reduction of 3 with NaBH4 gave 10-benzy1-9,10-dihydroacridine derivatives 4 with yields of 88%~96%.

吖啶酮1与氯化苄及其衍生物2在氢化钠/N,N-二甲基甲酰胺/碘化钾中反应高产率生成10-苄基吖啶酮类化合物3; 3经硼氢化钠氢化还原生成10-苄基-9,10-二氢吖啶类化合物4,产率88%~96%。

Results: A total of 18 kinds of SVOCs were qualitatively and quantitatively analyzed, the main compounds deteced were dimethylphthalate, diethylphthalate, dibuylphthalate, bis (2-ethylhexyl) phthalate, phenol, chrysene, benzo anthracene, benzo fluoranthene, benzo perylene, indeno (1, 2, 3-cd) pyrene, dibenzo anthraeene.

结果:定性定量检出邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丁酯、双(2-乙己基)邻苯二甲酸酯、邻苯二甲酸二辛酯、丁基苄基邻苯二甲酸酯、苯酚、4-甲基苯酚、萘、荧蒽、芘、屈、苯并蒽、苯并荧蒽、苯并荧蒽、苯并二萘嵌苯、茚并(1,2,3-cd)芘和二苯并蒽18种优先控制有机污染物。

Two monomers,bispmpargyl ether of bisphenol-Aand 4,4'-biphenyl dibenzyl azide were synthesized and characterized with FT-IR,1H-NMR and elementary analysis.

合成了两种单体双酚A二炔丙基醚与4,4′-联苯二苄叠氮,研究了一种新的低温聚合体系——双酚A二炔丙基醚与4,4′-联苯二苄叠氮在烘箱中的本体聚合行为。

The fish samples were cleaned up by Florisil, then analyzed by GC-EI-MS to determine eight phthalic acid esters, diethyl phthalate, dipropyl phthalate, dibutyl phthalate, butyl benzyl phthalate, dipentyl phthalate, dicyclohexyl phthalate, dihexyl phthalate and diethyl hexyl phthalate.

鱼肉样品以Florisil硅藻土层析柱净化后,经气相色谱-电子轰击离子源-质谱法分析其中8种邻苯二甲酸酯含量:邻苯二甲酸二乙酯、邻苯二甲酸二丙酯、邻苯二甲酸二丁酯、邻苯二甲酸丁基苄基酯、邻苯二甲酸二戊酯、邻苯二甲酸二环己基酯、邻苯二甲酸二己酯、邻苯二甲酸二(2-乙基己基)酯。

The flotation behavior and mechanism of benzyl malonic acid collector with combination use of hydroximic acid were studied by single mineral tests. The results showed that the recovery of minerals increased by combined use of benzyl malonic acid and hydroximic acid.

通过单矿物试验研究了苄基丙二酸与羟肟酸类捕收剂组合使用时对赤铁矿和菱锌矿的捕收性能,结果表明:苄基丙二酸与羟肟酸组合使用能明显提高矿物的回收率,提高浮选效率。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品:对氯苯酚,邻氯苯酚,2,4二氯苯酚,2,6二氯苯酚,2,4,5三氯苯酚,2,4,6三氯苯酚,4氯2苄基苯酚,对溴苯酚,2,4,6三溴苯酚,对氯苯基叔丁基醚,间溴苯甲醚,间溴氟苯,α溴甲基四氢呋喃,α溴代4氯苯乙酮,α溴4甲氧基苯乙酮,4氯二苯甲酮,4氯2甲基苯胺,N(2羟乙基)乙二胺, 2,3二溴丙酰氯,对溴苯磺酰氯,对苯二甲酰氯,间苯二甲酰氯,N氯代丁二酰亚胺,N溴代丁二酰亚胺,四氯苯醌,5氯靛红。

By synthesizing the hapten LBc starting from the metabolite of bifenthrin (2-methyl-3-phenylbenzyl alcohol), LBs (2-methyl[1,1-biphenyl]-3-ylmethyl 3-carboxyl-2,2-dimethylcyclopropane carboxylate and Lby (2-methyl[1,1-biphenyl]-3-ylcarboxylic acid , Three haptens were praparaed which were used in next step.

利用联苯菊酯的代谢物联苯醇合成了联苯菊酯的半抗原LBc(2-甲基-3-苯基苄基氧基羰基丙酸)、LBs(2-甲基-3-苯基苄基-3-羧基一2,2-二甲基环丙烷羧酸)和LBy(2-甲基-3-苯基苯甲酸)。

They are 2,7-dihydroxy-1,5,6-trimethoxy-9,10-phenanthrene,p-hydroxy phenyl aldehyde, 4-Hydroxybenzyl alcohol, Protocatechuic aldehyde, Gastrodin, 4,4'-Dihydroxydiphenylmethane,4-(4-(hydroxym-ethyl)phenoxymethylphenol,Isorhamnetin-3-O-glucoside,Isorhamnetin-3,7-di-O–glucoside, Imbricatin,2,3-dihydroxy-7-methoxy-9,10-dihydrophenanthropyrone, Cyclopholidone,Cyclopholidonol and β-daucosterol.

分别为:2,7-二羟基-1,5,6-三甲氧基-9,10-二氢菲,对羟基苯甲醛、天麻苷元、原儿茶醛、天麻素、4-(4-羟基-苄基)苯酚、4(4-苯氧基甲基苯酚、异鼠李素-3-O-葡萄糖苷、异鼠李素-3-O-7-O-二葡萄糖苷、Imbricatin、2,7-二羟基-3-甲氧基-9,10-二氢菲吡喃酮、Cyclopholidone、Cyclopholidonol和β-胡萝卜苷。

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Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在,所有的孩子都要在综合学校继续学习,所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地,使人们普遍认识到发展不能以牺牲农业为代价。

Detailed Intrinsic Reaction Coordination calculations were carried out to guarantee the optimized transition-state structures being connected to the related tautomers.

同时,做了详尽的内禀反应坐标计算,以保证所得到的过渡态连接相应的始末异构体。