二苄基

The second reaction we tested was diastereoselective Michael-Aldol annulation of -keto ester 121 with methacrolein to give a key intermediate for synthesizing (--Huperzine A.

通过对反应条件的筛选，我们得到的最好的结果是以-乳酸苄酯为手性辅基的β-酮酯121i为底物，以(1R， 2R)-环己二胺衍生的手性胍85i为催化剂，以无水四氢呋喃为溶剂，在-20℃反应，得到的产物的de值为73.2%。

Mainly engaged in: Hydrogen-imide hydrochloride, o-chlorophenyl cyclopentanone, 3.4 dimethoxy ethyl benzene, butyn single potassium acid, potassium ethyl malonyl, Ding amide, amide isobutyraldehyde , allyl chloroacetate, isopropyl chloroacetate Benzyl aluminum, cyclopentene, cyanide-o-chlorophenyl, o-methyl chloride, sulfuric acid chloride, p-chlorophenol, imidazole, Pinacolone, one chlorine Pinacolone.

主要经营：盐酸氢亚胺、邻氯苯基环戊酮、3.4二甲氧基苯乙酯、丁炔二酸单钾盐、丙二酸单乙酯钾盐、丁酰胺、异丁酰胺、氯乙酸烯丙酯、氯乙酸苄酯异丙醇铝、环戊烯、邻氯苯氰、邻氯苯甲酯氯、硫酸氯、对氯苯酚、咪唑、频呐酮、一氯频呐酮。

The general formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

The genera formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

Aqua, Sorbitol, PPG-1 PEG-9 Lauryl glycol ether, Hydrolyzed elastin, Hydrolyzed wheat gluten, Hydrolyzed collagen, Hydrolyzed glycosamino-glycans, Humulus lupulus, Propylene glycol, Triethanolamine, Sodium hydroxide, Carbomer, Maris limus extract, Ostrea extract, Imidazolidinyl urea, Parfum, Benzyl salicylate, Coumarin, Alpha isomethyl ionone, Hexyl cinnamal, Buthylphenylmethylpropionate, Linalol, Methylisothiazolinone, Methylchloroisothiazolinone.

水，山梨醇， PPG 公司- 1聚乙二醇- 9十二烷基醇醚，水解弹性蛋白，水解小麦面筋蛋白，水解胶原蛋白水解粘多糖，多聚糖，啤酒花提取物花，丙二醇，三乙醇胺，氢氧化钠，卡波姆，马里斯提取物，牡蛎提取物，咪唑烷基脲，香水，水杨酸苄酯，香豆素，阿尔法 l 紫罗兰酮，己基肉桂醛，丁苯基甲基丙醛，芳樟醇，甲基异噻唑啉酮，甲基氯异塞唑晽酮。

Take a Blue Sensitive Cyanine Dye and Ampicillinum Natricum an example. These two material both have good result and it it proved to be an effective tool for direct oscillographic analysis of organic.

以氨苄青霉素和感蓝染料3，3′-二(3-磺丙基)-4，5-苯并噻菁氢氧化物的三乙氨盐为例，二者在银盘电极上均有较好的示波响应，为示波分析直接进行有机分析提供了有效工具。

According to the experience of the research of the indoles alkaloid, we designed a series of novel compounds which contained indoles heterocyclic as the flat aromatic group, benzyloxy substituent at indoles 6 site as the nonhydrophilic group tail, carboxylic derivatives and TZDs bioisosterism substituent at indoles 2 site or 3 site as the hydrophilic group head.

于是根据我们课题组多年来对吲哚生物碱研究的经验，我们设计了以吲哚作为中间平面芳环体系，6位连接苄氧基作为疏水尾部，2位或3位连接羧酸及其衍生物、噻唑烷二酮及其电子等排体的一系列化合物。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。