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When the sodium lauryl sulfate and p-octyl polyethylene glycol phenyl ether is used and its level in 3% and 6: 4 ratio, the polymerization process has the lowest coagulum and the highest monomer conversion. Higher reaction temperature and more level hydroxyl value lead to more coagulum, the latter also lead to larger particle size. The acid value has larger influence on viscosity and coagulum, there exist a best range. The emulsion particle size is larger for its hydrophilicity, most of its particles are connected together.

在含较高亲水单体的乳液聚合体系中,难以制得稳定的预乳化液,不能采用工业生产中常用的预乳化工艺,而只能采用混合单体直接滴加的方法;由于单体混合物的亲水亲油值较高,用阴离子型乳化剂十二烷基硫酸钠和非离子型乳化剂聚乙二醇辛基苯基醚混合,用量为单体总量的3%,且比例在6:4时,乳液聚合时具有最低的凝聚物含量和最高的单体转化率;乳液聚合反应温度升高,可以提高单体转化率,增加反应速度,但凝聚率相应提高;随着羟基单体含量的增加,聚合过程中凝聚率增加,聚合物乳胶粒平均直径增加;羧基单体有一个最佳的用量(2.6%),过高或过低凝聚率均提高;羧基含量对乳液的粘度有较大的影响,当羧基含量较低时,羧基含量增加,乳液粘度增加明显;含羟基乳液粒子由于含亲水基团较多,使得乳胶粒径增大,乳胶粒子大多数互相凝聚在一起,处于凝聚态。

Table 1 medical packaging materials, containers, scope of pharmaceutical packaging materials, containers, in the form of the name preparation notes plastic bottle kalidehydroandrogropholidi = 50ml material with PP, LDPE Infusion bags, kalidehydroandrogropholidi = 50ml material is PVC, polyalkene glass infusion bottle 50ml clorsulon = injection bottle kalidehydroandrogropholidi 50ml, kalidehydroandrogropholidi = 50ml-molded, control of glass bottle kalidehydroandrogropholidi kalidehydroandrogropholidi 50ml kalidehydroandrogropholidi 50ml ampule medical plastic bottle of tablets, capsules, tablets, colour.10pills glass ampoules, pills and capsules, syrup, oral solution, nanosuspensions, immunoembolization, tincture, linimentum, lotio hard PVC medicinal Tablet and capsule-plastic blister packaging PVC/PE/PVDC medicinal compound hard Tablet and capsule-plastic blister packaging Composite PVC/PVDC medicinal Tablet and capsule hard-plastic blister packaging cold metal forming hard medicinal compound tablets, capsules, suppository materials have nylon/aluminium/PVC double aluminum packaging Tablet and capsule PVC/hard LDPE medicinal compound tablets, capsules, suppository glass bottle ciinincal ciinincal ciinincal plastic bottle medicinal ciinincal medicinal eardrops plastic bottle eardrops medicinal nasal drops plastic bottle nose drops for external use liquid medicinal plastic bottle tincture, linimentum, lotio koufuye of medicinal plastic bottle syrup, oral solution, nanosuspensions, immunoembolization glass control oral bottle syrup, oral solution, nanosuspensions, immunoembolization packaging for medicine bag laminating film, puivis bletillae, feian and Tablet foil Tablet and capsule of unguentum Al fighting、smoke aluminium pipe, oculentum, puivis bletillae, Tin aerosolon, nabulization materials have aluminum, plastic valve pyritionate, nabulization stopple kalidehydroandrogropholidi 50ml, 50ml clorsulon = material bromide, CIIR synthesis of oprene 50ml clorsulon = gasket aluminium caps combination Cap koufuye falchion, kalidehydroandrogropholidi 50ml, 50ml prestrain kalidehydroandrogropholidi = potting needle kalidehydroandrogropholidi 50ml desiccant tablets, capsules, pills and aluminium bottles vinpocetione polyethylene film and bag vinpocetione b, package management and standards on the management of the drug packaging mainly has two modes: a mode of government management, such as Singapore, Indonesia adopted a market access system, United States, Canada, the European Union through the implementation of the medicine on the packaging of the strict management, that is, the drug registration, declare to use medical packaging of related materials; Government departments on the packaging manufacturer production system to carry out spot checks.

表1 药品包装材料、容器适用的范围药用包装材料、容器名称制剂形式备注塑料输液瓶注射剂≥50ml 材料有PP、LDPE 输液膜、袋注射剂≥50ml 材料有PVC、聚烯烃玻璃输液瓶注射剂≥50ml 冻干注射剂瓶注射剂0ml、注射剂≥50ml 模制、管制玻璃注射剂瓶注射剂0ml 安瓿注射剂0ml 口服固体药用塑料瓶片剂、胶囊、丸剂玻璃药瓶片剂、胶囊、丸剂、糖浆剂、口服溶液剂、混悬剂、乳剂、酊剂、搽剂、洗剂 PVC药用硬片片剂、胶囊铝塑泡罩包装 PVC/PE/PVDC药用复合硬片片剂、胶囊铝塑泡罩包装 PVC/PVDC药用复合硬片片剂、胶囊铝塑泡罩包装冷冲压成型药用复合硬片片剂、胶囊、栓剂材料有尼龙/铝/聚氯乙烯双铝包装片剂、胶囊 PVC/LDPE药用复合硬片片剂、胶囊、栓剂玻璃滴眼剂瓶滴眼剂药用滴眼剂塑料瓶滴眼剂药用滴耳剂塑料瓶滴耳剂药用滴鼻剂塑料瓶滴鼻剂外用液体药用塑料瓶酊剂、搽剂、洗剂口服液体药用塑料瓶糖浆剂、口服溶液剂、混悬剂、乳剂玻璃管制口服液瓶糖浆剂、口服溶液剂、混悬剂、乳剂药品包装用复合膜、袋散剂、颗粒剂、片剂药品包装用铝箔片剂、胶囊铝管、铝塑管软膏、眼膏剂、散剂、罐气雾剂、喷雾剂材料有铝、塑料阀门气雾剂、喷雾剂胶塞注射剂0ml、注射剂≥50ml 材料有溴化、氯化丁基橡胶合成聚异戊二烯垫片注射剂≥50ml 铝盖、铝塑组合盖口服液、注射剂0ml、注射剂≥50ml 预灌封注射针注射剂0ml 干燥剂片剂、胶囊、丸剂铝瓶原料药聚乙烯膜、袋原料药二、包装管理及标准各国对药品包装的管理主要有两种模式:一种模式是政府管理,如新加坡、印度尼西亚采取市场准入制的方式,美国、加拿大、欧盟通过对药品的管理实施对药品包装的严格管理即在药品注册时,申报所使用药品包装的相关材料;政府部门对药品包装生产企业的生产体系进行现场检查。

In this paper,the monomers including St and BA with strong waterproof property were employed to modify the traditional PVAc emulsion,and meanwhile draw into DAAM functional monomer in the copolymer system,will prepare out cross linking copolymer emulsion for ADH to improve the waterproof,oilproof and dry/wet mechanical property of fuel oil filter paper.

采用具有较强抗水性的苯乙烯、丙烯酸丁酯等单体对传统聚醋酸乙烯酯乳液进行共聚改性,并在共聚体系中引入双丙酮丙烯酰胺功能单体,制备出可通过外加己二酸二酰肼交联的外交联醋丙共聚乳液,以期提高燃油滤纸的耐水、耐油性和干湿态的力学性能。

In addition, the invention further relates to a catalyzer combination used for polymerizing a conjugated dialkene monomer and the anions of an optional mono-vinyl aromatic hydrocarbon into a polydiene polymer having high and medium vinyl content. The catalyzer combination comprises an organolithium compound used as an anionic polymerization initiator, at least an alkali metal alkoxide compound expressed by the formula as a structure regulator.

此外,本发明还涉及一种用于将共轭二烯烃单体和任选的单乙烯基芳烃阴离子聚合成具有中高乙烯基含量的聚二烯聚合物的催化剂组合物,其包含作为阴离子聚合引发剂的有机锂化合物,和作为结构调节剂的至少一种式所示的碱金属醇盐化合物。

Several main non-ionic surfactants (AEO、TX、SpanTweem、EL) was used to emulsify liquid paraffin and di octyl sebacate and the anti-coalescence stability of the corresponding emulsion was studied, the impact of the presence of benzene and double bond in lyophobic moiety of surfactant and its length and matching with dispersed phase upon the interfacial viscosity and Gibbs elasticity was analyzed.

本文采用了几种主要的非离子活性剂(AEO、TX、Span-Tween、EL)来乳化白油和癸二酸二辛酯,通过对各乳液体系抗聚并稳定性的考察,分析了活性剂亲油链段的长度、苯环和双键的存在、及亲油链段与被乳化对象分子结构的匹配关系对界面粘度和Gibbs弹性的影响。

In this dissertation, two series of rare earth initiators: rare earth tri (2, 6-di-tert-butyl4-methylphenolate) and rare earth calixarene complex have been developed to ring-opening polymerize 2, 2-dimethyltrimethylene carbonate, trimethylene carbonate and ε-caprolactone at mild conditions. Both the polymerization features and mechanisms are discussed in details.

本论文为环碳酸酯、内酯的开环聚合开发了两类新型低毒性稀土催化剂:三(2,6-二叔丁基-4-甲基苯氧基)稀土配合物和对叔丁基杯芳烃稀土配合物,都可以在温和的反应条件下单组分引发2,2-二甲基三亚甲基环碳酸酯、三亚甲基环碳酸酯和ε-己内酯聚合,合成各种分子量的均聚和共聚材料,考察了催化剂结构、聚合条件等对聚合的影响,深入研究了聚合机理。

To improve the effect of CDCA on dissolving cholesterol gallstone, the water-soluble copolymers as polycarboxylic acid of comb-like copolymers and C_(60)-PCC were synthesized, which being used for modification of CDCA and strengthening effects of CDCA on dissolving the cholesterol gallstones by their entropy-repelled properties of comb-shaped side chains in buffers of phosphate and in model bile.The design theory of polymer was mainly employed to synthesis the conjugate of PCC-CDCA and C_(60)-PCC-CDCA by C_(60), polyoxyalkylene allylalkyldiether and maleic anhydride, which were copolymerized with AIBN as initiator, and then PCC or C_(60)-PCC were reacted with CDCA. The structures of the copolymers and the conjugates of PCC-CDCA and C_(60)-PCC-CDCA were confirmed with IR, TLC and TEM. The dissolving effects and the dissolution kinetics mechanism of cholesterol gallstone was inverstigated in PBS and in model bile of different cholesterol saturated index at pH7.4, including PCC-CDCA or C_(60)-PCC-CDCA.

利用高分子设计理论,以烯丙基聚氧乙烯基醚、顺丁烯二酸酐、C_(60)和CDCA为原料,以偶氮二异丁腈为引发剂,合成具有梳状侧链结构的梳状共聚物-CDCA结合物和C_(60)-梳状共聚物-CDCA结合物,以IR、TLC和TEM法表征共聚物的结构,并在pH7.4的PBS液和不同胆固醇饱和指数的模拟胆汁中进行溶石效果的研究,探讨在PBS液和不同CSI的模拟胆汁中结合物溶解胆固醇结石的效果和溶解动力学机制。

This article describes the present situation of high-pressure and low-pressure flash tank ,gas-liguid separator and purified gas filter.

详细介绍了聚乙二醇二甲醚脱硫脱碳装置中脱硫富液、脱碳富液的高、低压闪蒸槽以及气液分离器和精制气气体过滤器的生产现状,分析了这些设备出现瓶颈的原因,同时提出了相应的扩能改造的基本思路和方法,最后总结了改造的效果。

DM is mainly used as high-boiling point solvent for printing ink, dyestuff, resin, cellulose and painting.

二乙二醇丁醚醋酸酯有着十分高的沸点,主要用于高温烤瓷以及印刷油墨的高沸点溶剂,也用作乳胶漆的助聚结剂;由于该溶剂挥发速度很慢,在水中溶解度低,所以可作为丝网印刷油墨的溶剂,以及聚苯乙烯涂料印花釉的溶剂;也可作为共沸剂用于醇与酮的分离。

objective: to prepare the molecularly imprinted composite membranes with propofol as template.methods: with the ultraviolet light and initiator, template molecular propofol, functional monomer methacrylate and crosslinking agent ethylenegly-coldimethacrylate formed molecularly imprinted composite membrane through polymerization on the surface of polyvinyli-dene fluoride microporous membrane.inspection of the combination of template molecule and functional monomer, characterization of the membrane surface morphology with scanning electron microscopy.results: the morphology of composite membranes was well.propofol bonded to methylacrylic acid with hydrogen bond.conclusion: the method of ultraviolet light-struck is feasible for preparation of molecularly imprinted composite membranes with propofol as template.

目的:制备异丙酚分子印迹复合膜。方法:在紫外光照和引发剂的作用下,模板分子异丙酚、功能单体甲基丙烯酸和交联剂乙二醇二甲基丙烯酸酯在聚偏氟乙烯微孔滤膜表面聚合形成分子印迹复合膜,考察模板分子和功能单体的结合特性,用扫描电镜表征膜的表面形态。结果:复合膜形态良好,异丙酚和甲基丙烯酸以氢键的方式缔合。结论:用紫外光照射法可以制得异丙酚分子印迹复合膜。

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