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Hydrogen bonding in hard segment domains of segmented polyester polyurethaneurea based on 4,4'-diphenylmethane diisocyanate, ethylene diamine and polybutylene adipate(M. W. 1975 and M. W. 1228) was studied by means of IR spectroscopy.
用红外光谱法对基於4,4'-二苯基甲烷二异氰酸酯、乙二胺和聚己二酸丁二醇酯(分子量分别为1975和1228)的两系列嵌段聚酯型聚脲氨酯硬段微区中的氢键化进行了研究。
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To improve the cyano reactivity, cyano-terminated PPENs were prepared by the end-capping reaction of PPEN-OL with CBN; benzonitrile terminated polys were also prepared by the polycondensation of excess 4,4'-oxydianiline with 1,2-dihydro-2-(4-carboxyphenyl)-4-[4-(4-carboxyphenoxyl)phenyl]-phthalazinone, followed by end-capping with CBA. The polymers synthesized exhibited good solubility in NMP, DMAc and DMF, and were crosslinked to afford phenyl-s-triazine-containing polymers under the similar conditions.
为提高氰基活性,以对氯苯腈为原料,对PPEN-OL进行封端,设计合成了含氰端基的聚芳醚腈;以含二氮杂萘酮联苯结构二酸单体与4,4'-二氨基二苯醚为原料,经Yamazaki膦酰化缩聚,并用对氰基苯甲酸进行封端,合成了含氰端基的聚芳醚酰胺。
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The preparation of esterified derivant : it is prepared by the esterifying reacting of above (3) product and 4g dodecylbenzene sulphonic acid heated in water bath at 40℃ within 30min.
聚环氧氯丙烷乙二醇哌啶接支酯化衍生物的制备:4g十二烷基苯磺酸于40℃水浴条件下聚环氧氯丙烷乙二醇哌啶接支衍生物进行酯化反应。
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With toluene two isocyanogen diethylene glycol dinitrate, the polyester or the polyether dihydroxy alcohol, two methylol propionic acid, the triethylamine, the ethylene diamine and so on are raw materials, uses the prepolymer dispersion method, has prepared a series of anion river character polyurethane emulsion.
用甲苯二异氰酸酯、聚酯或聚醚二元醇、二羟甲基丙酸、三乙胺、乙二胺等为原料,采用预聚物分散法,制备了一系列的阴离子水性聚氨酯乳液。
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In this article, we have been investigated that synthesizing and properties of shape memory polyurethane. The shape memory polyurethane was synthesized from PCL diol, MDI(4, 4'-diphenylmethane diisocyanate) and BDO (1,4-butanediol) in this experiment. We analyzed that the effect of differential mole ratio of monomers to synthesized SMPU. Besides, the various concentrations of Nano-silver were mixed with SMPU. Mechanical properties and shape memory behavior of SMPU nanocomposite films were investigated.
本研究目的为藉由改变4,4'-二苯甲基二异氰酸盐(4,4'-diphenylmethane diisocyanate, MDI)/聚己内酯二元醇(polycaprolactone diol, PCL diol)/1,4-丁二醇(1,4-butanediol, BDO)等不同莫耳比制备形状记忆型聚氨基甲酸酯(Shape Memory Polyurethane, SMPU);并探讨改变不同单体莫耳比及添加不同浓度奈米银溶液对其物性及形状记忆性的影响。
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Using pentaerythritol as initiator, boron trifluoride diethyl etherate as catalyst.dichloroethane as dispersion agent, the chloride polyether polyol is synthesized based on the mechanism of cationic ring-opening polymerization of epiclilnrohyclrin.The azide polyether polyol is synthesized, in DMF through A and sodium azide, and the non-reported azide energetic curing agent is synthesized through the adduction of B and IIDI.
以季戊四醇为起始剂,三氟化硼乙醚为催化剂,1,2—二氯乙烷为分散剂,环氧氯丙烷经阳离子开环聚合反应制成氯化聚醚多元醇,A在N,N—二甲基甲酰胺中与叠氮化钠反应制得叠氮聚醚多元醇,B与六亚甲基二异氰酸酯加成反应制得未见文献报道的叠氮固化剂。
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Silver nanoparticles with average particle size ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using 10 kinds of different functional group-containing organic modifiers, such as polyvinylpyrrolidone, tween-80, sodium dodecyl sulfate, sodium polyacrylate, polyethylene glycol, D-sorbitol, sodium dodecyl sulfonate, sodium dodecylbenzene sulfonate, polyvinyl alcohol, cetyltrimethylammonium bromide, at room temperature.
摘 要:选择10种含有不同官能团的有机物为表面修饰剂,如聚乙烯吡咯烷酮、吐温-80、十二烷基硫酸钠、聚丙烯酸钠、聚乙二醇、山梨醇、十二烷基磺酸钠、聚乙烯醇、十二烷基苯磺酸钠和十六烷基三甲基溴化铵等,在室温下进行了平均粒径在2~131nm范围内纳米银颗粒的控制合成研究。
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Dimethylnaphthalene (2,6-DMN) is a potentially useful raw material for production of polyethylene naphthalate, polybutylene naphalate and liquid crystalline polymers with superior properties. How to industrialize the process of producing 2,6-DMN is getting more and more studied in the world recently.
2,6-二甲基萘(2,6-DMN)是合成新型聚酯树脂聚萘二甲酸乙二醇酯和聚萘二甲酸丁二醇酯以及液晶高分子聚合物的重要原料,所以将2,6-DMN的生产工业化最近几年成为国内外研究的重点。
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Monolayer.2. A Novel Sensor Based on Layer-by-Layer Hybridized Phosphomolybdate and Poly on a Cysteamine Modified Gold ElectrodeA novel sensor have been constructed by layer-by-layer hybridizing phosphomolybdate and poly on a cysteamine modified gold electrode.
磷钼杂多酸和聚二茂铁硅烷多层组装膜修饰电极及其电化学行为采用层层组装法在金电极上组装多金属氧酸盐阴离子和聚阳离子聚二茂铁硅烷,交替沉积多层膜,构建了杂多酸-PFS多层膜修饰的金电极。
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Two series of polys and polys were synthesized by solution polycondensation of 4,4'-difluorodiphenyl sulfone and 4,4'-difluorobenzophenone, respectively, with various bisphenols in the presence of cesium fluoride.
二系列聚醚碸和聚醚酮分别由 4,4'-difluorodiphenyl sulfone 与 4,4'-difluorobenzophenone和五种不同之二酚在CsF的存在下经由溶液聚缩合法制得。
- 推荐网络例句
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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.
索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。
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The relationship between communicative competence and grammar teaching should be that of the ends and the means.
交际能力和语法的关系应该是目标与途径的关系。
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This is not paper type of business,it's people business,with such huge money involved.
这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。