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In this paper, a series of low cross-linking polyurethanes are synthesized using polycaprolacton or polybutamethylene adipate or polyethylene-propylene adipate, MDI and glycerin. Their mechanical, thermal and dynamical properties and shape memory function are studied.
采用聚己二酸乙丙二醇酯、聚己二酸丁二醇酯、聚己内酯和 4,4'-二苯基甲烷二异氰酸酯为原料,以丙三醇为交联剂合成了一系列低度交联的聚氨酯,讨论了组成、配比等对性能的影响,比较了它们和线型聚氨酯在性能上的差别。
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The recognition mechanisms of GGR and TCR to UVB-induced photodamages were summarized: Xeroderma Pigmentosum group C, the recognition factor in GGR, executed its function avoiding direct contacting with lesions; the conversion between monomer and dimer of Cockayne syndrome B protein was underlined in the recognition of TCR; ubiquitylation mediated by DNA damage binding protein played an important role in NER recognization at chromatin level; moreover, the fate of the recognition factors was also discussed.
识别因子XPC通过一种不直接识别损伤本身的机制在GGR识别过程中发挥作用;在TCR识别过程中强调了关键因子CSB单体及二聚体两种形式的转换。在染色质水平上,DDB介导的泛素化作用是NER识别过程中重要的调控要素。另外,完成使命的识别因子的最终走向也是NER途径中的一个重要环节。通过分析上述生化过程,较清楚地总结了GGR及TCR对UVB导致的光损伤的识别机制。
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The crystallization behavior of polyethylene terephthalate ; random poly (ethylene/tetramethylene terephthalate) P (ET/BT ; poly (ethylene terephthalate/ isophthalate) P (ET/EI and poly (ethylene terephthalate/adipate) P (ET/EA copolyesters; and block polyethylene terephthalate/polyethylene glycol and polyethylene terephthalate/polytetramethylene glycol were studied by DLI ; DSC; WAXD; PLM and IR technique.
本文通过缩聚反应合成了不同分子量的聚对苯二甲酸乙二酯;聚对苯二甲酸酯P(ET/BT、聚(对苯二甲酸/间苯二甲酸)乙二醇酯P(ET/EI和聚乙二醇酯P(ET/EA等系列的无规共聚酯以及PET/PBG和PET/PEG等系列的嵌段共聚酯,并采用DLI、DSC、WAXD、IR和NMR等实验技术着重研究了它们的结晶行为与共聚酯的序列结构。
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The crystallization behavior of polyethylene terephthalate ; random poly (ethylene/tetramethylene terephthalate) P (ET/BT ; poly (ethylene terephthalate/ isophthalate) P (ET/EI and poly (ethylene terephthalate/adipate) P (ET/EA copolyesters; and block polyethylene terephthalate/polyethylene glycol and polyethylene terephthalate/polytetramethylene glycol were studied by DLI ; DSC; WAXD; PLM and IR technique.
中文题名PET及其共聚酯的结晶行为副题名外文题名 The crystallization behavior of PET and its copolyesters 论文作者边界导师封麟先叶胜荣教授学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位浙江大学学位授予日期2001 论文页码总数10,159页关键词聚对苯甲酸乙二酯聚酯结晶馆藏号BSLW /2003 /O633 /1 本文通过缩聚反应合成了不同分子量的聚对苯二甲酸乙二酯;聚对苯二甲酸酯P(ET/BT、聚(对苯二甲酸/间苯二甲酸)乙二醇酯P(ET/EI和聚乙二醇酯P(ET/EA等系列的无规共聚酯以及PET/PBG和PET/PEG等系列的嵌段共聚酯,并采用DLI、DSC、WAXD、IR和NMR等实验技术着重研究了它们的结晶行为与共聚酯的序列结构。
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A series of modified polyurethane elastomer materials with different amino siloxane content were synthesized,which were based on polyoxypropylene glycol,aminoethyl aminopropyl poly,toluene diisocyanate and the curing agent dimethylsulfide toluylenediamine.
以聚氧化丙烯二醇或聚氧化丙烯三醇、氨乙基氨丙基聚二甲基硅氧烷、甲苯二异氰酸酯为原料在无溶剂条件下制备预聚体,利用二甲基硫甲苯二胺为固化剂合成一系列氨基硅油改性聚氨酯弹性体材料,并对材料的力学性能、耐热性、表面水接触角等性能进行了测试。
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The invention relates to a pipeline polyurea outer anticorrosive coating and the making method thereof, making heated prepolymerization reaction on dibenzo-methane diisocyanate, carbodiimide diisocyanate, polyether binary alcohol and polyether trihydric alcohol to prepare prepolymer solution A, and making end amino polyethylene oxide ether, dimethyl sulfur-based toluene diamine, diethyl diamine, iso-propyl titanate solution, polyacrylate, carbon black, titanium dioxide and lightweight calcium carbonate into solution B, and as using, respectively heating the solutions A and B to 65 deg.C and then mixing them, then quickly spraying and curing to form a coat.
本发明涉及一种管道用聚脲外防腐涂料及制造方法,由二苯基甲烷二异氰酸酯、碳化二亚胺化二异氰酸酯、聚醚二元醇和聚醚三元醇通过加热预聚反应制成预聚物的A液、由端氨基聚氧化乙烯醚、二甲硫基甲苯二胺、二乙基甲苯二胺、钛酸异丙酯溶液、聚丙烯酸酯溶液、碳黑、钛白粉和轻质碳酸钙配制而成的B液组成,使用时将A液和B液分别加热至65℃后混合,然后快速喷涂固化形成涂层。
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G. it is up to 80 eV when the cluster plane is parallel to the surface. In addition, the impact induced adsorption of C〓 cages was studied in detail. After impacting, the normal incident C〓 was found to move laterally on the surface due to the anisotropic interaction between the dimerized surface and the cage. Finally, it resided on the top of a dimmer or in the trough, which are the energy favored adsorption sites.
在能量为10-20eV的C〓富勒烯表面吸附动力学过程的研究中,我们还发现表面结构的不对称性会引起团簇-表面相互作用的各向异性,从而导致入射团簇在表面上有与入射方向垂直的的横向运动,最后吸附在两个二聚体的中心点和谷点,这两个位置是能量最低的的吸附组态。
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In response to TCDD exposure, AhR nuclear translocator forms a heterodimer with the aryl hydrocarbon receptor after the ligand-dependent translocation of AhR to the nucleus, and eventually the complex binds to the xenobiotic response elements, which promote transcription of several specific genes, such as CYP1A1.However, the diverse effects of TCDD could not be simply explained by the AhR pathway.
对於戴奥辛的毒性机制,以往的研究认为与芳香基碳氢化合物受体(arylhydrocarbon receptor-AhR)的活化有关;TCDD 活化了AhR,被活化的AhR 从细胞质转移到细胞核内,在细胞核与另一个蛋白质AhR nuclear translocator形成二聚体,并与DNA 上的xenobiotic regulatory element结合,诱发某些基因(如:CYP1A1)的转译与表现;不过,单从AhR的代谢途径并不能解释所有生物上的毒性现象。
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Sythesis and application of chlorostyrene-DVB strongly acidic cation exchange resin ;2. For this study,a series of poly( p -amino styrenes) with various amounts of supported hydrogen chloride,and a series of strongly acidic cation exchange resin s with various exchange capacity were synthesized,and their catalytic property for ketalization of cyclohexanone and glycol were investigated.
通过测定固载了不同量的氯化氢的聚和不同交换量的强酸性阳离子交换树脂催化的环己酮与乙二醇的缩酮化反应缩酮的收率,研究了聚合物固体酸催化剂的疏水性对其催化缩酮化反应性能的影响;发现在一定范围内增加催化剂的疏水性,可提高缩酮化反应的收率。
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Therefore, the EL spectra of (Znq_2)_4 is wider than that of Znq_2. 4._2 was synthesized. The analysis of molecular spatial structure and the characterization of material performance of_2 and Liq showed that two Liq molecules and two Naq molecules were connected by Na-O-Na bond bridges to form_2. Compared with Liq,_2 exhibits stronger rigidity in planar molecular structure, larger steric hindrance and intermolecular distance, and much smaller molecular polarity, thus resulting in much longer fluorescence lifetime, much higher fluorescence quantum efficiency, wider energy bandgap and better film formability. When used as light-emitting layer in OLED,_2 shows lower formation probability of excited dimmer and exciplex formation than Liq, thus emits bluer light with higher current efficiency than Liq. When_2 ultrathin film is used as electron injection layer in OLED, it exhibits higher current density, higher luminance, lower turn-on voltage and higher current efficiency than Liq ultrathin film for the existence of sodium ions in_2 ultrathin film. 5. The summarization the relationship between molecular spatial structure and material performance of Alq_3,(Znq_2) and Liq, lead the conclusion that the molecular spatial structure of Mq_n affects its material performance in such aspects as the rigidity of planar molecular structure, intermolecular interaction, molecule stacking mode and intermolecular distance.
制备了_2,通过对_2和Liq的分子空间结构与性能进行分析与讨论,发现_2是通过两个Na-O-Na键桥将两个Liq和两个Naq连接构成的,其分子平面结构的刚性程度强于Liq,空间位阻大于Liq,分子之间的距离大于Liq,分子极性远远小于Liq;_2的荧光寿命长于Liq,荧光量子效率高于Liq,成膜性优于Liq;_2的禁带宽度比Liq大,光致发光光谱中_2的最大发射峰较Liq发生蓝移;当_2在OLED中作为发光层时,激发二聚体与激基复合物的生成几率远远小于Liq,发的光比Liq更蓝,电流效率大于Liq;_2超薄膜中有Na离子的存在,与Liq超薄膜相比,当其在OLED中作为电子注入层时,具有更大的电流密度,更高的发光强度,更低的阈值电压和更高的电流效率 5、对上述Alq_3、Znq_2和Liq的分子空间结构与材料性能之间的关系进行了归纳总结,认为Mq_n的分子空间结构主要在分子平面结构的刚性程度,相邻分子之间的相互作用,分子堆叠的方式和分子之间的距离这四个方面影响其性能。
- 推荐网络例句
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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.
索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。
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The relationship between communicative competence and grammar teaching should be that of the ends and the means.
交际能力和语法的关系应该是目标与途径的关系。
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This is not paper type of business,it's people business,with such huge money involved.
这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。