二聚的

Plasma from normal individuals is not expected to agglutinate Dimertest Latex.

正常人的血浆一般不和二聚体乳胶试剂凝集。

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

At first the energy of the microwave will energized the argon to be ionization, and the generated heat make the sulfur volatilizing into bivalency sulfur or dipolymer sulfur high pressure steam. The molecule transition will happen under the microwave energization, and the visible light will be emitted when the sulfur states change into the low energy level. The spectra of the plasma lamp is nearly centering at the visible lights, and there are very little ultraviolet and infrared spectrum, the Fig 3 shows the spectra of the sun and the plasma lamp from which we can see the spectrum character clearly.

微波能量首先激励氩气使其电离，产生的热量使硫挥发成为二价硫分子或二聚物高压蒸汽，在微能量的激励下使它形成分子跃迁，当返回到较低能级的状态时以连续光谱的形式放射出光线，它的光谱基本上集中在可见光，红外线和紫外线的辐射量很少，（图3）硫的放射光谱和太阳光谱的比较图片，可以很清晰地表达这一特性。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构，化合物8是白花丹素的Na盐，以离子化合物形式存在；化合物9～16为白花丹素的La，Y，Dy，Sm，Gd，Nd，Er，Eu的稀土金属配合物；化合物17是白花丹素的双核钇结构；化合物18为白花丹素的单核钇结构，该配合物除了含白花丹素外，还有来自白花丹植物中的另一个单体化合物也参与配位；化合物19～21是以2，2\'-联吡啶和邻菲咯啉等含N配体为辅助配体，具有白花丹素—含N配体—金属离子的三元配合物，化合物19是白花丹素和2，2\'-联吡啶与Cu的配合物，具有五配位的四方锥构型，通过Cu…O弱的成键作用形成二聚体，再通过分子间的氢键作用进一步形成一维链状结构，化合物20和化合物21是白花丹素分别与2，2\'-联吡啶和邻菲咯啉的Zn配合物，都具有六配位八面体构型的双核锌配合物，呈一维链状结构，化合物20中链与链之间的大量氢键将一维链扩展成二维层，分子间的π-π堆积作用进一步形成三维结构。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

The measuring of conductivity of the copolymers also indicates that addition of phthalie acid did not destroy the conjugation system of homopolymer of propargyl alcohol.

产物电导率的测量亦说明邻苯二甲酸的加入，并没有破坏聚丙炔醇的共轭体系，但共聚物的电导牢随邻苯二甲酸的含量增加而略有降低。

The major achievement of this paper is: Based on characteristics of the traffic data distribution, execute pattern recognition operations on traffic condition on two dimensions by clustering, then use BP neural network to describe and forecast traffic flow aiming at each pattern. Making use of classic flow-occupancy inverse "V" model, implement polynomial fitting using least-squares algorithm and statistics method on flow curves to detect outliers which are proved to be not accord with practice through the actual implement, then use the moving average model to recorrect the outliers and absent. Make correlation analysis on muti-direction flow queues of the intersection and ones of upriver intersections, choose flow queue with high correlation as assistant one to improve the error tolerance of the prediction system, at the same time we can use the method to give an estimation of flow in intersection with out sensors. We design and implement an SOA(Service-Oriented Architecture)-based UTDD(urban traffic data mining development) with high expansibility and performance, which implement unified management and call of the data-mining application though defining a XML-based description of data-mining process and a common interface to call data-mining process, finally we build traffic flow prediction application model on UTDD.

根据交通流量数据分布的特征，提出基于k-means的二次聚类方法，对交通流量在流量大小和时间上进行模式划分，进而对各个交通流模式进行基于BP神经网络的描述和预测，从而提高模型对流量预测的精度； 2）根据流量/时间占有率倒&V&字形曲线分布模型，提出基于最小二乘法的三次多项式曲线拟合和统计方法的异常检测方法，实际应用表明该方法能够有效识别异常数据，然后根据移动平均算法对异常数据进行修正； 3）基于序列相关性分析，分别对预测方向的交通流量数据序列、上游路口相关序列以及预测路口其它各个方向上的交通流量序列进行分析，选择相似性流量序列，作为辅助序列提供其他没有检测器路口的流量估计； 4）设计和实现了基于SOA（Service-Oriented Achitecture）的高性能、可扩展的智能交通数据挖掘系统UTDD，该系统通过定义基于XML的数据挖掘过程描述和通用的过程模型接口，实现数据挖掘应用的统一管理和调用，最后在UTDD上建立了基于路口流量预测的应用模型。

The optimum condition of preparing process were obtained: the amount - of - substance ratio of sodium hydroxide and eerie sulfate tetrahydrate was 4.8:1 ,the quantity of PEG was 8 mL in reaction and 7 mL in washing, absolute alcohol was 10 mL in washing, irradiation time was 6 min, constant microwave irradiation pressure was 0.14 MPa, microwave power was 232 W, the ultrasonic wave dispersing time was 10 min and the microwave drying time was 10 min.

通过考察制备过程中的各个影响因素，得到了制备纳米二氧化铈的最佳工艺条件：氢氧化钠与四水硫酸高铈物质的量比为4.8：1；聚乙二醇的反应用量为8mL，洗涤用量为7mL；无水乙醇的洗涤用量为10mL；微波恒压时间为6min；微波压力为0.14MPa；微波功率为232W；超声波分散时间为10min；微波干燥时间为10min。

The reactionsystem of polyesterification of DFA and EG was analyzed and simplified. Based on thehypothesis of equal and unequal activity of the end-group of monomer and polymer,the modelⅠand modelⅡfor estimating kinetic parameters were established usingimproved Genetic Algorithm, which was so improved by introducing the Elitist Model,Simulate annealing, Runge-Kutta method, proportional distribution randomizer etc.into the operators, and these models were more compatible with the estimation ofcomplex reaction kinetic model parameters.

对二聚脂肪酸与乙二醇缩聚反应体系进行了分析和简化，基于单体和聚合物端基等活性及不等活性的假设，采用已加入最优保存策略、变量数值扰动、龙格库塔积分(Runge-Kutta)算法、均匀分布的随机数发生器算子的遗传算法，建立了模型Ⅰ和模型Ⅱ，并利用C~计算机语言编程来估算动力学模型的参数。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。