二聚体

It indicates that the N—O bonds in the singlet dimer adsorption configurations are weaker than any other structures, and this is propitious to the NO direct decomposition. 7. Unlike NO molecules interaction with copper atoms, when two NO molecules interact with the adjacent silver atoms, the non-planar structures are more stable than the planar.

同时，单重态的二聚体与相邻的金属铜和银原子作用时，由于电子从金属原子转移到二聚体上的数量最多，因此在这种吸附构型中，金属原子被离子化的倾向最大，同时使得二聚体中N—O键被削弱的程度也最大，有利于NO的直接分解； 7。

The results showed that POD activity increased at first and then decreased in the skin and flesh of root. The peak occurred at 40 d and 60 d in the skin and flesh, respectively. POD activity in the skin was higher than that in the flesh at 30 d and then contrary results were observed. The higher POD activity was, the more POD isoenzyme was. The pattern of POD isoenzymes was different between skin and flesh at different vegetative growth stages. POD isoenzymes in the skin were composed of five monomers and four dimers while five dimers or two monomers, two dimers and one tetramer in the flesh. POD isoenzymes in the root were mainly acidic. POD localized mainly in the cell walls of periderm, cambium, xylem ray, xylem vessels and primary xylem.

结果显示，心里美萝卜营养生长期肉质根的皮和肉中POD活性均先升高后降低，分别在播种后第40 d和60 d出现峰值，30 d时皮中POD活性高于肉，之后则相反，酶活性最高时同工酶数目也最多，不同时期，皮和肉中同工酶种类不同；皮中POD同工酶由5个单体和4个二聚体组成，而肉中由5个二聚体或2个单体、2个二聚体和1个四聚体组成，均以酸性同工酶为主；组化定位显示POD主要分布在肉质根的周皮、形成层、木射线、木质部导管和肉的初生木质部等的细胞壁附近。

The excited-state intramolecular proton transfer tautomerism reaction of 6-methyl-4-hydroxy pyri-midine monomers and dimmers was investigated by the ab initio method with the self-consistent reaction field with Tomas's polarized continuum mode and CIS theories at HF level on the basis of 6-311+G* and 6-31G basis set. By studying the potential energy surface, it was found that the monomer's ground-state proton transfer process together with the excited-state proton transfer process is a molecular system of four energy level, but dimmers were not, which can be used to explain the fact that UV-visible absorption and fluorescence spectra of monomer and dimers all corresponded to quinoid.

采用 ab initio HF理论的组态相关CIS方法和连续溶剂模型PCM，分别在6-311+G*和6-31G水平上研究了6-甲基-4-羟基嘧啶单体及二聚体激发态质子转移的异构化反应；对其反应势能面的研究发现，单体基态和激发态的异构化反应一起可以形成四能级的分子电子体系，而二聚体的却不能，由此解释了单体和二聚体的紫外吸收光谱和荧光发射光谱均对应于酮式构型的原因。

The tryptophan residues play important roles in DNA photoreactivation catalyzed by CPD photolyases. We have investigated the action mechanism concerning Trp in DNA photoreactivation, and obtained the results as follows: 1 We proposed a mechanism of photosensitized splitting of CPDs by Trp and Trp-containing peptides. 2 Quantum yields of splitting of the model compounds that a Trp linked covalently a CPD were obtained under 290 nm light in various solvents, these values changing with solvent, range from 0.01 to 0.5. 3 Utilizing pulse radiolysis technique, splitting processes were observed in aqueous solution of the CPDs with hydrated electron and some oxidative species (such as hydroxyl radical, bromic radical and azide radical), and obtained their rate constants. In the case of interaction between CPD and hydrated electron, splitting of the CPD anion, and pyrimidine anion transfer an electron to FAD or Rf, were observed. The process rate was slower one order more than that in photolyase. Minor, but highly mutagenic UV-light-induced lesions are (6-4) photoproducts, which are repaired by (6-4) photolyases. These enzymes, discovered in 1993, are not well characterized and their mechanism is still under investigation.

我们研究它的作用机理，获得以下结果：1）建立了色氨酸及其肽对嘧啶二聚体光敏化裂解的直接修复作用机理模型；2）获得了色氨酸共价键连接于嘧啶二聚体的化合物在多种溶剂中290nm光辐照裂解的量子效率，其值随溶剂而变化，范围在0.01-0.5；3）运用脉冲辐解观察到嘧啶二聚体与水合电子和一些氧化性的自由基作用裂解过程，得到相应速率常数；对二聚体与水合电子作用发生裂解以及向FAD返还电子的过程进行了体外模拟；4）（6-4）光解酶的作用机理中一个关键假定是氧杂环丁烷中间体在接受电子后能自发裂解，恢复二嘧啶的结构。

Some isoforms were detected in the serotonin dimeric sprcies The structure of these isoforms need to be elucidated in the future. In conclusion, the dimeric species of serotonin is strongly related to pigment on rice.

目前的研究结果无法确定二聚体的结构，但由结果显示二聚体的含量似乎与水稻外壳的色素变化相关，因此推测 serotonin 二聚体极有可能改变水稻外壳色素。

It has also been found that acidic medium is necessary for the formation of protonated monomer and dimer. The stability of the dimer of the tungstophosphate is lower; a pure monomer can be obtained by treating the mixture with a base (Bu4NOR). However, the dimer of tungstosilicate is stable under the same condition.

实验结果还表明，酸性介质是生成质子化单体和二聚体的必要条件，且钨磷酸盐二聚体的稳定性较低，用碱(Bu4NOH)处理合成产物可得纯的钨磷酸盐单体，而相同条件下钨硅酸盐的二聚体却比较稳定。

The results from GC-MS and GC analysis confirmed that the oligomer was a mixture consisting of di-(14%),tri-(45%),tetra-(31%) and pentamer(10%).

GC-MS和GC的分析结果表明所得齐聚物是混合物，主要由二聚体、三聚体、四聚体和五聚体组成。

The reactions involved in the co-curing are: cyclodimerization and cyclotrimerization of cyanates, polyetherfication of epoxy groups and cyclotrimerization of cyclic dimers, as well as the formation of oxazolidinone rings.

反应历程首先是氰酸酯发生自聚反应形成二聚体或三聚体，然后二聚体可进一步共聚形成三嗪环，此过程伴随着环氧基的聚醚反应，最后是三嗪环与剩余的环氧基反应形成NFDA1唑烷酮。

The yeast Pxa1p and Pxa2p dimerize to form a functional transporter involved in very long chain fatty acid oxidation in the peroxisome. The formation of PMP70 assembles as dimeric or oligomeric forms on peroxisomal membranes implies that Pxa2p may form a homodimers.

同源於Pxa2p的PMP70被证实会形成同源二聚体或多聚体，这对於Pxa2p是否也会形成同源二聚体或多聚体的研究，是非常有意义的。

The optimum conditions for this reaction were confirmed: the mole ratios of the Lewis base and AlCl〓 with the electron-rich aromatic monomer are 1. 2 and 3. 4, respectively; 1, 2-dichloride ethane is the most suitable solvent in this reaction; The solution of the two reactants must be added slowly to a large amount of solvent containing catalyst under pseudo-high dilution conditions; The Lewis base, such as NMP, DMF are applicable in this reaction system.

在此理论的指导下，通过对单体结构的模拟，高选择性地合成了一种新型结构的芳香环状聚硫酯二聚体，对其结构进行了精确的表征，在不同溶剂中得到了该环状二聚体的单晶，单晶X-ray衍射表明该二聚体为环张力极小的大环化合物。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新