二聚

The polymethyl methacrylate material with super-hydrophobic surface of the invention is prepared in the following steps: 1 the polymethyl methacrylate material is first put into diamine solution, so that the ester group on the surface of the material has ammonolysis reaction with diamine molecules; 2 and then, the product of the step 1 is put into long chain fatty acid solution to be treated and the solvent is volatilized, so as to obtain the polymethyl methacrylate material with super-hydrophobic surface.

本发明具有超疏水表面的聚甲基丙烯酸甲酯材料，是按照如下步骤进行制备的：1将聚丙烯酸甲酯材料先置于二胺溶液中使聚丙烯酸甲酯材料表面的酯基与二胺分子发生氨解反应；2然后，将其置于长链脂肪酸溶液中进行处理，挥发掉溶剂，得到具有超疏水表面的聚甲基丙烯酸甲酯材料。

Under the catalyst, the polymerization retarder, the including water medicinal preparation existence condition, the methylacrylic acid and the polyethylene glycol single methyl ether (400) direct esterification synthesis methylacrylic acid polyethylene glycol single methyl ether (400) ester, and the influence factors of the catalyst, polymerization retarder, including water medicinal preparation has mellowly carried on the comparison.

摘要在催化剂、阻聚剂、带水剂存在的条件下，由甲基丙烯酸与聚乙二醇单甲醚(400)直接酯化合成甲基丙烯酸聚乙二醇单甲醚(400)酯，并对酸醇比、催化剂、阻聚剂、带水剂等影响因素进行了比较。

Three series of segmented polyurethanes were synthesized, which are based on 4,4'-methylene-di, N-methyl diethanolamine and hydroxy terminated poly-butadiene, poly or poly.

本文讨论了以聚环氧乙烷、聚环氧丙烷以及聚丁二烯为软段，以4，4'-二异氰酸二苯甲烷和N，N-二羟乙基甲胺为硬段的链段型聚氨酯的合成。

The polyetherurethane was synthesized by one-step method for cosmetic applications by coupling poly(PTMG,Mn=2000) and poly(PEO,Mn=2000) with 4,4'-diphenylmethane diisocyanate.

聚醚型聚氨酯用于化妆品中，由聚四亚甲基醚二醇和聚环氧乙烷与4，4-二苯甲烷二异氰酸酯采用一步法合成，结果表明PEU暴露在60℃酒精/水(80/20，体积比)溶液中放置4周后发生降解，PEU发生变质，其相对分子质量、粘度和机械性能都发生改变。

Attempts in part I of the dissertation were to develop microemulsion systems using medium chain triglyceride, Captex 300, deionized water (H2O), and TPGS as surfactant for the oral delivery of protein drugs or poorly water soluble drugs. Pseudo-ternary phase diagrams were constructed to elucidate the phase behavior of systems composed of medium-chain triglyceride and water with TPGS as main surfactant, polysorbates (Tween 20, Tween 40, Tween 60 and Tween 80) as adjuvant surfactants, and polyethylene glycols (PEG 400 and PEG 600) and polyols (ethanediol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol and glycerin) as cosurfactants.

藉由拟三相图（Pseudo-ternary Phase Diagrams）的建立来了解中链型三酸甘油酯、去离子水及TPGS为主要界面活性剂配合聚醇山梨酯（如Tween 20、Tween 40、Tween 60及Tween 80）为辅助界面活性剂或聚乙二醇（如PEG 400及PEG 600）及多醇类（如乙二醇、1，2-丙二醇、1，3-丙二醇、1，3-丁二醇、1，4-丁二醇及甘油作为共界面活性剂所形成的微乳基剂之相变化。

The pegylated polylactide-poly glycolide nanoparticle, whose surface was co-modified withmaleimide-polyethylene glycol and methoxy-polyethylene glycol, was made by double-emulsion and solvent evaporation method andcovalently conjugated with thiolated lactoferrin via its maleimide functionalgroup.

第一章首先由复乳／溶媒蒸发法制备马来酰亚胺—聚乙二醇(Maleimide-PEG，MAL-PEG)和甲氧基聚乙二醇表面共修饰的聚乳酸-聚羟基乙酸纳米粒，然后通过其表面MAL-PEG与巯基化Lf共价连接而制备Lf-NP_。

By use of titration analysis, the thesis investigated various factors such as isocyanate, PE molecular weight, reacting substance molecular ratio, reacting temperature and time etc. influencing upon prepolymerization step. It was found that 2, 4-tolulene diisocyanate and 4, 4'diphenylmethane diisocyanate is more rapidly reacted with PE600 than HDI. With PE molecular weight increasing, the reacting temperature or time should be raised or extended relevantly. Thus PE2000+2HDI pre-polymerization should be better carried out under some catalyst, for example, Triethylene diamine , Dibutyltin dilaurate and Tin octoate were used.

首先采用滴定分析方法对WRPU预聚反应的影响因素进行了研究：芳香族二异氰酸酯TDI、MDI比脂肪族二异氰酸酯HDI反应活性高，其中TDI在反应初始阶段的反应速率比MDI快，不过随着反应的进行，MDI比TDI反应速率加快，这主要是因为TDI分子中的两个-NCO反应活性差异大所致；二元醇分子量越大，反应速度越慢；聚醚二元醇比聚酯二元醇的反应速度快；当分子量超过2000的二元醇与HDI进行预聚反应时，需借助适当的催化剂来加快反应速度，从而使预聚反应能够顺利进行，分别选择DABCO、TOA和DBDTL三种催化剂进行催化反应，发现不同的催化剂，其催化效果相差较大。

The preparation of the membrane is that the phthalazine polyether-sulfone-ketone polymer is mixed with chloroform, Ethanol or butanol according to certain quality proportion; after the magnetic stirring, the evenly mixed casting solution is obtained, filtered and carried out with vacuum deaeration; The casting solution is scraped into membrane of certain thickness on the non-woven fabric by adopting the scraper; the membrane is standed for 24 hours in the air of certain humidity and temperature to obtain the plate ultrafiltration membrane of phthalazine polyether-sulfone-ketone.

本发明公开了属于高分子膜分离技术领域的一种二氮杂萘聚醚砜酮类聚合物平板超滤膜的制备方法，所述膜的制备方法为：用二氮杂萘聚醚砜酮类聚合物与氯仿、无水乙醇或正丁醇按照一定的质量比混合，磁力搅拌后得到混合均匀的铸膜液，过滤并真空脱泡；将铸膜液采用刮刀在无纺布上刮制成一定厚度的膜，该膜在一定湿度和温度的空气中静置24h后即得到二氮杂萘聚醚砜酮类平板超滤膜。

Amino-monomethoxypoly(ethy1ene glycol)(mPEG-NH2) was synthesized based on the principle of Gabriel synthesis.Monomethoxypoly(ethy1ene glycol) tosylate was prepared at first,and then reaction with potassium salt of phthalimide as nucleophile to produce the monomethoxypoly(ethy1ene glycol)phthalimide derivative.

摘 要：首先合成了单甲氧基聚乙二醇对甲苯磺酸酯，然后根据盖布瑞尔合成法原理，以邻苯二甲酰亚胺钾盐为亲核试剂与mPEG-OTs反应，生成单甲氧基聚乙二醇的邻苯二甲酰亚胺衍生物，mPEG-PI与水合肼反应肼解生成伯胺，合成了一端为氨基的单甲氧基聚乙二醇(mPEG-NH2)。

DSC measurements indicate that the crystallizing temperature and the melting temperature of the three-arm star-shaped polyethylene glycol were different from those of the corresponding linear PEG because the existing of TMP-SK3 altered its crystallizing velocity and the perfect degree of crystals.

DSC测试结果表明，与线型聚乙二醇相比，三臂星型聚乙二醇由于TMP-SK3核的存在，不仅影响聚乙二醇的结晶速度，同时也影响结晶的完善程度，导致其结晶温度和结晶熔融温度发生变化。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。