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To explore the application of capillary gas chromatography in the determination of dicyclopentadiene in the Air.

目的 探讨以毛细管气相色谱法测定工作场所空气中的二聚环戊二烯。

Objective To explore the two methods in detecting the D-dipolymer and compare whether the two results being conformable.

目的 探讨二种方法对同一标本D-二聚体的测定结果是否具有可比性。

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解,随着烯烃配体上取代基的不同,而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

A novel isomer of furazano energetic compound 3,4-diaminofurazanofuroxan was synthesized by the dimeric ring-close reaction of transitional intermediate 3-amino-4-cyanofurazan oxide after the energetic compound 3-amino-4-chloroximinofurazan was treated with diluent alkali at low temperature, The yield of DAFF isomer could be over 66.3% and its single crystal was cultivated.

将含能化合物3-氨基-4-氯肟基呋咱在低温下用稀碱处理后发生过渡中间体3-氨基-4-氰基呋咱氧化物的二聚关环反应合成了新型呋咱类含能化合物3,4-二氨基呋咱基氧化呋咱异构体,产率达66.3%。

These findings are consistent with functional NMDA receptors being arranged as a dimer of dimers.

这一结果也进一步支持NMDA受体的装配是一个二聚体的二聚化过程。

A series of the ligands including 6-bromo-piperonal dimethyl acetal, bis (9-fluorenyl) silane, and the dimer of indene have been synthesized and characterized.

合成了溴代胡椒醛二甲基缩醛基配体,合成了手性配体甲基苯基双芴基硅烷,合成了茚的二聚体,对其进行表征,培养单晶并测定了晶体结构。

The process can convert over 95% isobutylene in C 4 olefin into diisobutylene or isooctene in the present of acid cation exchange resin catalyst,and partial 1-butylene also take part in the reaction.

介绍了一种混合碳四烯烃叠合利用的预反和催化蒸馏组合技术,该技术以酸性阳离子交换树脂为催化剂,可以将混合碳四烯烃中的95%以上的异丁烯叠合反应生成二异丁烯和异辛烯,且部分正丁烯也参与二聚或共聚。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构,化合物8是白花丹素的Na盐,以离子化合物形式存在;化合物9~16为白花丹素的La,Y,Dy,Sm,Gd,Nd,Er,Eu的稀土金属配合物;化合物17是白花丹素的双核钇结构;化合物18为白花丹素的单核钇结构,该配合物除了含白花丹素外,还有来自白花丹植物中的另一个单体化合物也参与配位;化合物19~21是以2,2\'-联吡啶和邻菲咯啉等含N配体为辅助配体,具有白花丹素—含N配体—金属离子的三元配合物,化合物19是白花丹素和2,2\'-联吡啶与Cu的配合物,具有五配位的四方锥构型,通过Cu…O弱的成键作用形成二聚体,再通过分子间的氢键作用进一步形成一维链状结构,化合物20和化合物21是白花丹素分别与2,2\'-联吡啶和邻菲咯啉的Zn配合物,都具有六配位八面体构型的双核锌配合物,呈一维链状结构,化合物20中链与链之间的大量氢键将一维链扩展成二维层,分子间的π-π堆积作用进一步形成三维结构。

The one electron oxidative splitting reaction mechanism between 9,10-anthraquinone-2-sulfonate and cyclobutane dimethylthymine dimer was acquired.

研究了蒽醌-2-磺酸盐与环丁烷型二甲基胸腺嘧啶二聚体发生的单电子氧化裂解反应机理。

R-1,c-2, t-3, t-4-1,3-bis(4-biphenyl)-2,4-di(4-pyridyl)cyclobutane was obtained in diluted sulfuric acid by photodimerization reaction.

通过反-1-(4-联苯基)-2-(4-吡啶基)乙烯在稀硫酸中的光二聚反应合成了r-1,c-2,t-3,t-4-1,3-双(4-联苯基)-2,4-二(4-吡啶基)环丁烷。

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