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The company researches and develops dimer acid synthesis technology by the Sichuan bentonite primarily catalyst, receives in the product quality and the product rate on greatly surpasses the domestic same profession (dimmer acid color ≤7#, viscosity between 5000~10000cp/250C adjustable, receives rate is higher than same profession 10%); serialized product plan: dimer acid, the monomer acid, the benzene dissolves the polyamide resins, alcohol dissolves the polyamide resins, the liquid polyamide resins mellowly and polyamine hotmelt adhesive, lets the enterprise in the intense market competition, adjusts the product mix nimbly, achieves should accomplish a task with ease to the market.

公司研发的以四川膨润土为主催化剂的二聚酸合成技术,在产品质量和产品收率上均大大优于国内同行业(二聚酸色泽≤7#,粘度在5000~10000cp/250C 之间可调,收率高于同行业10%);系列化的产品方案:二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热熔胶,让企业在激烈的市场竞争中,灵活调整产品结构,做到应对市场游刃有余。

The tryptophan residues play important roles in DNA photoreactivation catalyzed by CPD photolyases. We have investigated the action mechanism concerning Trp in DNA photoreactivation, and obtained the results as follows: 1 We proposed a mechanism of photosensitized splitting of CPDs by Trp and Trp-containing peptides. 2 Quantum yields of splitting of the model compounds that a Trp linked covalently a CPD were obtained under 290 nm light in various solvents, these values changing with solvent, range from 0.01 to 0.5. 3 Utilizing pulse radiolysis technique, splitting processes were observed in aqueous solution of the CPDs with hydrated electron and some oxidative species (such as hydroxyl radical, bromic radical and azide radical), and obtained their rate constants. In the case of interaction between CPD and hydrated electron, splitting of the CPD anion, and pyrimidine anion transfer an electron to FAD or Rf, were observed. The process rate was slower one order more than that in photolyase. Minor, but highly mutagenic UV-light-induced lesions are (6-4) photoproducts, which are repaired by (6-4) photolyases. These enzymes, discovered in 1993, are not well characterized and their mechanism is still under investigation.

我们研究它的作用机理,获得以下结果:1)建立了色氨酸及其肽对嘧啶二聚体光敏化裂解的直接修复作用机理模型;2)获得了色氨酸共价键连接于嘧啶二聚体的化合物在多种溶剂中290nm光辐照裂解的量子效率,其值随溶剂而变化,范围在0.01-0.5;3)运用脉冲辐解观察到嘧啶二聚体与水合电子和一些氧化性的自由基作用裂解过程,得到相应速率常数;对二聚体与水合电子作用发生裂解以及向FAD返还电子的过程进行了体外模拟;4)(6-4)光解酶的作用机理中一个关键假定是氧杂环丁烷中间体在接受电子后能自发裂解,恢复二嘧啶的结构。

In this paper, the synthesis, performance and kinetics of C_(36) DFAbased di-polyester or tri-polyester and its derivant, their polyesters were synthesizewith DFA and EG or PEG and PPG, were systemically and roundly studied.

本文以天然油脂加工产物——二聚脂肪酸为主要原料,系统地研究了二聚脂肪酸与乙二醇、聚乙二醇、聚丙二醇之间二元或三元缩聚反应的理论问题及合成物应用性能。

In order to decrease copolymerization loss of isoprene during thermal dimerization of cyclopentadiene in C5-fraction,the effect of three inhibitors,diethylhydroxylamine,p-tert-butylcatechol and o-nitrophenol,on dienes' polymerization in the process was investigated by experiment with sealed glasstube.

为减少C5馏分环戊二烯热二聚过程中异戊二烯的聚合损失,采用封管实验方法考察了添加阻聚剂二乙基羟胺、对叔丁基邻苯二酚、邻硝基苯酚对热二聚过程中各二烯烃组分聚合程度的影响。

The company developeddmmer acid synthesis technology in Sichuan bentonite mainly catalyst , the product quality and finished product rate both were much better than the internal industry(dimmer acid color:≤7#, viscosity : between 5000~10000 cp/250C adjustable , finished product rate :≥10% internal industry); a series products project : dimer acid 、 monomer acid 、 benzene dissolved polyamide resin 、 alcohol dissolved polyamine resin and polyamine hotmelt adhesive , let enterprises in the fierce market competition , flexible adjustment product structure , to cope with the market with facility .

公司研发的以四川膨润土为主催化剂的二聚酸合成技术,在产品质量和产品收率上均大大优于国内同行业(二聚酸色泽≤7#,粘度在5000~10000cp/250C之间可调,收率高于同行业10%);系列化的产品方案:二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热溶胶,让企业在激烈的市场竞争中,灵活调整产品结构,做到应对市场游刃有余。

The company developed dmmer acid synthesis technology in Sichuan bentonite mainly catalyst,the product quality and finished product rate both were much better than the internal industry(dimmer acid color:≤7#,viscosity:between 5000~10000cp/250C adjustable,finished product rate:≥10% internal industry);a series products project:dimer acid、monomer acid、benzene dissolved polyamide resin、alcohol dissolved polyamine resin and polyamine hotmelt adhesive,let enterprises in the fierce market competition,flexible adjustment product structure,to cope with the market with facility.

公司研发的以四川膨润土为主催化剂的二聚酸合成技术,在产品质量和产品收率上均大大优于国内同行业(二聚酸色泽≤7#,粘度在5000~10000cp/250C之间可调,收率高于同行业10%);系列化的产品方案:二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热溶胶,让企业在激烈的市场竞争中,灵活调整产品结构,做到应对市场游刃有余。

The dimer acid and polyamide resin synthesis technology which use Sichuan bentonite as primarily catalyst by our company researched and developed greatly surpassed the domestic same industry on product quality and product yield (dimer acid colour:≤7#, viscosity: 5000~10000 cp/250C can control at will, the yield is higher than the same industry 8~10%). Serialized product plan: dimer acid, monomer acid, co-soluble polyamide resin, alcohol soluble polyamide resin, liquid polyamide resin and polyamide hotmelt adhesive, let the enterprise can adjust the product mix nimbly and can respond to market easily in the intense market competition.

公司研发的以四川膨润土为主催化剂的二聚酸合成技术,在产品质量和产品收率上均大大优于国内同行业(二聚酸色泽≤7#,粘度在5000~10000cp/250C之间可调,收率高于同行业8~10%);系列化的产品方案:二聚酸、单体酸、共溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热溶胶,让企业在激烈的市场竞争中,可灵活调整产品结构,做到应对市场游刃有余。

The company developeddmmer acid synthesis technology in Sichuan bentonite mainly catalyst , the product quality and finished product rate both were much better than the internal industry(dimmer acid color:≤7#, viscosity : between 5000~10000 cp/250C adjustable , finished product rate :≥10% internal industry); a series products project : dimer acid 、 monomer acid 、 benzene dissolved polyamide resin 、 alcohol dissolved polyamine resin and polyamine hotmelt adhesive , let enterprises in the fierce market competition , flexible adjustment product structure , to cope with the market with facility .

本公司自行研发出的以四川膨润土为主催化剂的二聚酸合成技术,在产品质量和产品收率上均大大优于国内同行业产品(二聚酸色泽≤7#,粘度在5000~10000cp/250C之间可调,收率≥10%同行业。):二聚酸、单体酸、苯溶聚酰胺树脂、醇溶聚酰胺树脂、液体聚酰胺树脂及聚酰胺热溶胶。

Calcium dimer acids and zinc dimer acids were prepared by double decomposition reaction,and their structures were identified by IR.Their effects on heat stability of PVC were tested by way of Congo Red Method and Heating Method.Calcium dimmer acids and zinc dimmer acids were compared with traditional calcium stearate and zinc stearate.

通过复分解法制备了二聚酸钙和二聚酸锌,并通过红外检测证明了其结构;采用刚果红法、热烘法研究了二聚酸钙和二聚酸锌对PVC的热稳定作用,并与传统的硬脂酸钙、硬脂酸锌热稳定剂作了比较。

The catalyst for IB dimerization, reactive site, reactive mechanism and dynamics research date was reviewed in this paper and try to explain the mechanism of selectivity enhancing by adding Tertiary butyl alcohol during IB dimerization and provide reference for the study of dimerization afterwards.

本文对异丁烯二聚催化剂、反应活性位、机理及动力学研究成果进行了综述,试图解释在异丁烯二聚时,加入的叔丁醇对二聚反应选择性提高的作用机理,为今后二聚反应的研究提供参考。

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