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二羧酸

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From the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonylmethylate, the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonyl- methylate followed by cycloaddition reaction, was tentatively proposed.

通过研究反应过程中分离出的副产物反丁烯酸二乙酯III和4,5-二氢吡唑-3,4,5-三羧酸乙酯IV,初步提出了反应经过乙氧羰基甲基化苯并二氮杂卓翁中间体V再发生环加成反应的机制。

Durable formaldehyde-free phosphorus flame retardant for cotton,FRC-F,was synthesized with dimethyl methylphosphonate,phosphoric pentaoxide and ethylene glycol-glycerol mixt.

利用甲基膦酸二甲酯、五氧化二磷、乙二醇、丙三醇的混合物成功地合成了一种无甲醛棉用耐久性膦系阻燃剂,探讨了阻燃剂FRC-F、多元羧酸交联剂BTCA、催化剂NaH2PO2、柔软剂等应用于棉织物的工艺。研究结果表明:阻燃剂FRC-F是一种值得研究和开发的无甲醛棉用阻燃剂

Free tryptophane, docosoic acid and methyl 14-methy pentadecanate were isolated and identified as monomeric compounds also for the first time from Panax plants. Malonyl-ginsenoside 〓, ginsenoside Ro,〓, Re,〓,〓,〓(8 saponins) and stigmasterol were isolated and identified for the first time from the fruits and molonyl- ginsenoside 〓 was also the first from the plant of panax quinquefolium.

游离色氨酸、二十二碳酸及14-甲基-十五碳酸甲酯是首次从人参属植物中分离鉴定的杂环α-氨基酸和脂肪羧酸类单体化合物;丙二酸单酰基人参皂甙〓、人参皂甙〓及豆甾醇是西洋参果中首次分离鉴定的8种单体皂甙和1种甾醇化合物,M-〓亦为西洋参中首次分离鉴定的皂甙化合物。

Methacryloyloxydecyl-2-thiouracil-5-carboxylate was synthesized from the reaction of thiouracil with diethyl ethoxymethylene malonate and ω-hydroxy-decyl-methacrylate.

以硫脲、乙氧基次甲基丙二酸二乙酯和甲基丙烯酸ω-羟癸酯为主要原料合成了一种新的粘接性单体10-甲基丙烯酰氧癸基-2-硫脲嘧啶-5-羧酸酯。

ABSTRACT In this paper, by employing dicarboxylic acids with special conformation, i.

利用几个结构上有特点的二元羧酸,即2,6-吡啶二甲酸、三个异构体苯二甲酸,顺丁烯二酸和4,4'-联苯甲酸作为首要桥基配体,并结合使用含氮中性配。。。

The article adopted the method of orthogonal design using Polyethylene Glycol and Methacrylic Acid to esterify Polythylene-glycol-mono Methacrylate, then using PMA, MAA and Methacrylic Acid Sulfonic Sodium as raw material to synthesize Polycarboxylic type water-reducer.

用正交实验法研究了聚乙二醇和甲基丙烯酸酯化合成聚乙二醇单甲基丙烯酸酯的合成工艺,以该酯化物与MAA和甲基丙烯酸磺酸钠为原料,在引发剂的作用下合成聚羧酸系减水剂。

Distribution ratios of complex extraction for different operation conditions were forecasted. Using mass action law, the liquid-liquid equilibrium models of complex extraction of monobasic and polybasic carboxylic acid have been successfully induced, and physical extraction were also considered in the model. On the basis of orthogonal experiments, the models of equilibrium distribution ratios were established. The processes of complex extraction were tested and verified. Comparing experimental data with model values, it could be held that the regression precision of model was rather high and the model supplied fundamental data for industrial amplification and practical use of complex extraction.

采用质量作用定律分析方法,成功地推导了同时考虑物理萃取的一元及多元羧酸络合萃取通用液-液平衡数学模型,并在正交试验基础上建立了磷酸三丁酯络合萃取丁酸、三烷基胺(7301)萃取丁酸、丁二酸、柠檬酸的平衡分配系数模型,从平衡角度对络合萃取过程进行了验证与预测,通过实验数据与模型计算值比较,表明模型的拟合精度较好,从而为络合萃取技术的工业放大与实际应用提供了重要依据。

The combination of chemicals includes a catalyst, such as, dibutyl tin dilaurate; carboxylic or sulfonic acid; and an extender compound, such as 2,4 pentanedione.

该化学试剂混合物包括催化剂,如二月桂酸二丁基锡;羧酸或磺酸;和增量化合物,如2,4-戊二酮。

The synthesization technics of MPEG- MAA was studied in this paper,which is an important intermediate used for preparation of polycarboxylate superplasticizer.

本文对制备聚羧酸系减水剂的重要中间体——甲基丙烯酸聚乙二醇单甲醚酯的合成工艺进行了研究,考察了反应时间、催化剂对甲苯磺酸的用量、阻聚剂对苯二酚的用量、反应温度及甲基丙烯酸与聚乙二醇单甲醚的用量比对酯化率的影响。

The degradation of 2, 4-dichiorophoxyacetic acid (2, 4-D) by ozonation combined with sonication (03/US) was investigated. Based on the authors' first paper about the synergistic effect of ozone and US, this paper presents intermediate products of 2, 4-D degradation. The main intermediates were 2, 4-dichiorophenol, benzopuinone, hydroquinone and organic acids, such as maleic acid and oxalic acid and soon.

利用臭氧超声波联合工艺对苯氧羧酸类除草剂2,4-D进行降解研究,在前文探讨臭氧超声波之间协同效应的基础上,确定其中间产物种类主要有2,4-二氯苯酚、苯醌、氢醌以及小分子酸如顺丁烯二酸、草酸、甲酸、乙酸等。

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