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The regulative sequence of ribulose-1 ,5-bisphosphate carboxylase small subunit genes of rice was cloned by PCR amplification.

利用PCR法克隆了水稻日本晴来源的核酮糖-1、5-二磷酸羧化酶小亚基基因5'上游调控区,命名为Posrbcs。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺;NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢;NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

The most commonly used method for the covalent binding of biomolecules onto 1-D nanostructures is through the diimide-activated amidation of carboxylic acid terminated nanostructures.

最常用的方法是通过端羧酸基纳米结构的二酰亚胺活化氨基化合物来进行生物分子与1-D纳米结构的共价结合。

In addition,α-alkenoyl ketene--acetals mainly used as the synthons of 3C and 5C, theα-functionalized reactions of which just limited on some simple reactions, as bromination, nitration, acetylation. However, the understanding of the forming of C-C bond atα-position is far from enough.

另外,对于α-烯酰基二硫缩烯酮的研究则主要集中在其作为3C或5C合成子的研究上,其α-位的官能化研究只是停留在溴化、硝化、脱羧等简单的反应之上,而对α-位C-C键的形成还缺乏足够的认识。

Analyse and compare what adopt a variety of pair of methods, the Michael addition reaction of ester of acerbity second of second of hydroxyl of protection of benzyl of the response of close nucleus addition that uses second nitrile and ester of formic acid second certainly, chloridize, cyanogen, reaction that take off carboxyl generates 3- benzyl oxygen radical the fifth of the ten Heavenly Stem the method of 2 nitrile, detailed discussion the action that wait and the by-product that arise possibly reach the reactant in each pace reaction, activator, dissolvent avoid a method.

通过对多种方法的分析和比较,确定采用乙腈和甲酸乙酯的亲核加成反应、氯化苄保护羟基、氰乙酸乙酯的Michael加成反应、脱羧反应生成3-苄氧基戊二腈的方法,并具体的讨论了每一步反应中反应物、催化剂、溶剂等的功能和可能产生的副产物及避免方法。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料,依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程,合成了系列未见报道的ABEPS。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用,烯烃的硼氢化物在PTC条件下,插入∶CCl2 ,可得饱和羧酸;炔烃则难以与之硼氢化。

Experimental results showed that aerosol created by 1,3,5-trimethylbenzene photooxidation can be classify with five distinct chemical particle classes, the predominant components of these five particles are aromatic aldehyde, phenol, nitrophenol and carboxylic acid compounds.

利用该算法对OH自由基启动1,3,5-三甲苯光氧化形成的二次有机气溶胶单粒子质谱数据进行了聚类分析,在得到的五个聚类中包含了芳香醛、酚类化合物、硝基酚和羧酸等重要的光氧化产物,为研究苯系物光氧化机理提供了新的信息。

According to the experience of the research of the indoles alkaloid, we designed a series of novel compounds which contained indoles heterocyclic as the flat aromatic group, benzyloxy substituent at indoles 6 site as the nonhydrophilic group tail, carboxylic derivatives and TZDs bioisosterism substituent at indoles 2 site or 3 site as the hydrophilic group head.

于是根据我们课题组多年来对吲哚生物碱研究的经验,我们设计了以吲哚作为中间平面芳环体系,6位连接苄氧基作为疏水尾部,2位或3位连接羧酸及其衍生物、噻唑烷二酮及其电子等排体的一系列化合物。

ABSTRACT: In the presence of sodium t-butoxide and DMSO,ethyl 2-oxocyclopentanecarboxylate was subjected to C-alkylation with 2-(4-bromomethylphenyl)propanoic acid with high regioselectivity to give 2-[4-(1-ethoxycarbonyl-2-oxo-1-cyclopentanylmethyl)phenyl]propanoic acid (4) which was followed by hydrolysis,decarboxylation and salt formation to afford loxoprofen sodium in about 72% overall yield.

在叔丁醇钠和二甲基亚砜的存在下,2-丙酸对2-乙氧羰基环戊酮进行C-烷基化,再经水解脱羧,成盐即得洛索洛芬钠,以2-丙酸计算,总收率为72%。

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Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书,王祥生,李德昌。安徽省首次发现嗜群血蜱。

Chapter Three: Type classification of DE structure in Sino-Tibetan languages.

第三章汉藏语&的&字结构的类型划分。