二羟基苯

A series of organic reversible thermochromic materials are prepared using bromocresolpurple as chromophoric reagent,aromatic compound with hydroxyl(hydroquinone,bisphenol A,1-naphthol)as delomorphic rea- gent and hexadecanol as solvent.

以溴甲酚紫为发色剂，含羟基的芳香族化合物(对苯二酚、双酚A和1-萘酚)为显色剂，十六醇为溶荆制备了有机可逆热变色材料。

In a similar way, using N,N\'-dibenzyl tartamide as auxiliary,-(2-methyl)allyl-2-chloro-phenyl-methyl azide, a vital intermediate of Repaglinide, can be prepared via asymmetric allylation of o-chlorobenzaldehyde in

产物经氧化和碘加成内酯化反应得到阿伐他汀中间体(3R，5S)-3-羟基-5-碘甲基戊内酯(10)；将N-苄基酒石酸二酰胺用于邻氯苯甲醛的不对称烯丙基化反应以较高光学收率得-甲基烯丙基-2-氯苯基-甲基醇

As we know, spiro-conjugated compound 1',3',3'-trimethyl-6-hydroxyspiro[2H-1-benzopyran-2,2'-indoline] is one of thesignificant photochromic species, the structure and spectrum ofthe compounds 1',3',3'-trimethyl-6- hydroxyspiro[2H-1-benzopyran-2,2'-indoline] and its isomers have studied.

三。研究了一类重要的光致变色物质之一螺旋共轭化合物1′，3′，3′-三甲基-6-羟基螺旋[2H-1-苯并吡喃-2，2'-二氢吲哚]及其光异构化产物的结构、光谱，并在此基础上，用完全态求和公式自编程序计算了非线性光学系数。

A high ordered ladderlike polyhydrosiloxane was successfully synthesized by the strong H-bonding template of N〓, N〓-bis (1-hydroxy-2-methylpropan-2-yl) terephthalamide.

通过强的酰胺氢键模板作用首次合成了高规整性、可溶的反应性有机桥基N，N-二（2-羟基-2-甲基丙基）对苯二甲酰胺聚氢基硅氧烷高分子。

Bone marrow mesenchymal stem cells could differentiate into osteoblasts, adipocytes and neural like cells with osteoblast inductor (β-sodium glycerophosphate, dexamethasone, vitamin C), lipoblast inductor (dexamethasone, 3-isobutyl-1-methylxanthine, bovine insulin, indometacin) and serum-free medium inductor (dimethyl sulphoxide, butylated hydroxyanisole) respectively. Osteoblast marker (alkaline phosphatase, osteocalcin mRNA, calcium node), adipocyte marker (lipid droplet, PPAR γ-2mRNA) and neural cell-like marker (nissl body, neuron specific enolase, neurofilament protein) were respectively determined by the immunohistochemical method, polymerase chain reaction and immunocytochemical method.

分别采用成骨细胞诱导剂（β-甘油磷酸钠，地塞米松，维生素C）、成脂肪细胞诱导液（地塞米松，甲基异丁酸黄嘌呤，牛胰岛素，吲哚美辛）及二甲基亚砜和羟基丁酸苯甲醚无血清培养基诱导剂干预细胞向成骨、脂肪、神经细胞分化，经免疫组织化学染色、PCR、免疫细胞染色方法检测成骨标志物（碱性磷酸酶、骨钙素mRNA、钙结节）、脂肪标志物（脂滴、PPARγ-2mRNA）、以及类神经标志物（尼克氏体、神经烯醇化酶、神经丝蛋白）。

The new oxalamide bridging ligands N, N'-bis (4-hydroxy-3-methoxy-benzyl) oxalamide (H4LB) was designed and synthesized.

设计合成一种新型对称的草酰胺桥联配体：N，N'-二（4-羟基－3-甲氧基苯甲基）草酰胺配体(H4LB)。

The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶体结构研究表明配体H4L为顺式桥联分子，晶体中存在两种氢键，一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2)，∠O-H…O=151.8°]；另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2)，∠N-H…O=158.7°]，通过上述两种氢键将化合物H4LB连接成二维网络结构。

Several types of ligand reactions observed under hydrothermal condition were summed up:(1) hydrolysis of pyridine nitrile, aldehyde and ester in mixed water and alcohol into pyridine-carboxylate;(2) replacement of carboxylate group with sulfonic group;(3) coupling of phenanthroline by dehydrogen;(4) oxidative coupling of methanol into oxalic acid;(5) hydroxylation of isophthalate.

总结了以往在水热条件下观察到的几类配体反应：（1）吡啶腈、醛和酯在醇和水混合溶液中水解成吡啶羧酸；（2）磺基取代羧基反应；（3）邻菲啰啉的脱氢的聚合：（4）甲醇被氧化偶合生成草酸：（5）间苯二甲酸的羟基化反应。

"Half-water-hydrolysis"method is used to modify the preaminolysis of phenylenediamine in"step coupling polymerization". First, dehydrochlorination polycondensation between Si-OH and Si-Cl group during polycondensation reaction is employed instead of dehydration reaction between Si-OH groups before, which avoids the disconnection of Si-N bond destreyed by isolated water and improves the H-bonding template effect of the bridged-phenylenediamine.

探索用&半水水解-脱氯化氢缩聚&法对我组过去提出的&全水水解法&的预胺解法加以改进，经&半水水解&得到的含硅羟基和硅氯基的单体再以脱氯化氢代替脱水的方法减少了极性溶剂存在下游离水断裂梯撑模板的硅-氮键的可能性，有效地提高了对苯二胺梯撑中氢键的模板作用。

In this work,the new kind of polyurethane have been prepared from Bis(4—β—hydroxyphnyl)sulphone,polyhydrofuran, 4,4′—di—phenylmethane diisocyanate,by one—step reaction metho -d and block copolymerizatiano.

本文用一步反应法，由双(4-β-羟基乙氧基苯)砜，聚四氢呋喃，4，4′—双苯基甲烷二异氰酸，采用嵌段共聚法，制成了一种新型聚氨酯。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。