二羟基苯

Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.

结果 从该植物中分离得到12个酚性化合物，其结构分别为二氢松柏醇二氢对羟基桂皮酸酯，香草醛，罗布麻宁，对羟基苯甲醛，丁香醛，丁香酸，丁香乙酮，α-羟基丁香丙酮，松柏醛，二氢松柏醇，2-羟基苯丙醇和3-羟基－4-甲氧基苯乙醇。

They are 4-(2- hydroxy-3-butynlenoxy) benzoic acid (1, WA), 5-chloro-7, 8-dihydroxy-7-methyl- 6-oxo-3- [ -3, 4-dihydroxy-3, 5-dimethyl-l-heptylene] -1H-8, 8a-dihydrobenzo [2, 3-c] pyran (2, WB),-2-(2-methyl-2-dibutene diamido)-2-butenoic acid (3, B5262), 3, 4-dihydro-9, 10-dihydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3- c] pyran-1-one (4, A73 semi-Vioxanthin), 8, 8'-bis (6, 9-dioxo-3,4-dihydro-10- hydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3-c] pyran-1-one)(5, A122 Xanthomegnin), 2, 5-dioxo-3a-hydroxymethyl-3, 3a, 6, 6a-tetrahydro-furo [2, 3-b] furan (6, 1003-2), 7-acety1-5-chloro-6, 8-dioxo-7-methyl-3- [ -3, 5-dimethyl-1, 3- diheptylene] -4aH-benzo [2, 3-c] pyran (7, M2-2 sclerotiorin), respectively.

它们分别被命名为4-（2-羟基-3-丁炔氧基）苯甲酸（1，WA）、5-氯-7，8-二羟基-7-甲基-6-氧代-3-[-3，4-二羟基-3，5-二甲基-1-庚烯基]-1H-8，8a-二氢苯并[2，3-c]吡喃（2，WB）、-2-（2-甲基-2-丁烯二酰亚胺基）-2-丁烯酸（3，B5262）、3，4-氢-9，10-二羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮（semi-Vioxanthin，4，A73）、8，8'-双（6，9-二氧代-3，4-二氢-10-羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮）（Xanthomegnin，5，A122）、2，5-二氧代-3a-羟甲基-3，3a，6，6a-四氢-呋喃并［2，3-b］呋喃（6，1003-2），7-乙酰基-5-氯-6，8-二氧代-7-甲基-3-［-3，5-二甲基-1，3-庚二烯基］-4aH-苯并2，3-c］吡喃（Sclerotiorin，7，M2-2）。

The total synthese three natural compounds to explore enantioselective synthesis of flavanol: We use phloroglucin and 2, 4, 6-trihydroxyacetophone as starting materials to synthesis distenin in two ways; Resorcin was used to synthsis 2, 5-dimethoxymethoxyacetophone though 3 steps.

对黄烷醇化合物的立体选择性全合成进行了探索：以间苯三酚和2，4，6-三羟基苯乙酮为原料，尝试用两条路线对Distenin化合物进行了全合成研究；以对苯二酚为原料，经三步制得2，5-二甲氧甲氧基苯乙酮，与2，4，6-三甲氧甲氧基苯甲醛反应，经四步反应得到天然产物3，5，7，2′，5′-二五羟基黄烷关键中间体1-（2′，6′-二甲氧甲氧基苯）-3-（2"，4"，6-三甲氧甲氧基苯）丙烷-1R，2R-二醇83及其对映体84；简要介绍了EGCg类化合物的生物活性和研究概况。

C. I. Reactive blue KN-R, Alizarin brilliant green G and Hostlam blue R could not be degraded by Zoogloea HP3. Furthermore, ABAS degradation was regressed under the exisitence of the above dyes. 1-Aminoanthraquinone-2sulfonic sodium, 1, 4-dihydroxylanthraquinone-2-sulfonic sodium, 1, 4, 5, 8tetrahydroxylanthraquinone, anthraquinone, aniline, phenol, catechol and ophthalic acid could be degraded by Zoogloea HP3. Aniline was the most degradable substrate among ABAS, aniline, phenol, catechol and o-phthalic acid. However, benzenesulfonic sodium and p-amino benzenesulfonic sodium were not degraded by it.

动胶菌HP3不能降解活性艳蓝KN-R、弱酸性绿GS及毛用活性蓝HW-R等蒽醌型染料，且染料的存在对菌体降解溴胺酸有不同程度的抑制作用；动胶菌HP3可以降解1-氨基蒽醌-2-磺酸钠、1，4-二羟基蒽醌-2-磺酸钠、1，4，5，8-四羟基蒽醌、蒽醌及苯酚、邻苯二酚、苯胺、邻苯二甲酸等苯系化合物，而不降解苯磺酸钠、对氨基苯磺酸钠；在溴胺酸、苯酚、邻苯二酚、苯胺、邻苯二甲酸中，苯胺是动胶菌HP3的天然底物。

A series of sulfonated poly(arylene thioether/ether phosphine oxide)s was prepared by direct polycondensation of sBFPPO and BFPPO with the diphenol-type or dimercapto-type monomers such as hydroquinone, bisphenol-A, 4,4'-biphenol, 4,4'-diphenol (6F), 1,5-dihydroxynaphthalene, 4,4'-dihydroxybiphenyl, and 4,4'-thiobisbenzenethiol, respectively.

将BFPPO与sBFPPO分别与多种二羟基或二巯基单体，如对苯二酚、双酚A、4，4'-二苯酚、双酚F、1，5'-二羟基萘、4， 4'-二羟基二苯硫醚和4，4'-二巯基二苯硫醚，直接共聚制备了一系列磺化聚芳醚三苯基氧膦，侧重考察了二羟基和二巯基单体结构单元对产物的耐氧化性能的影响。

Inorganic chemistry ; hydrogen peroxide ; review ; sodium percarbonate ; percarbamide ; 4Na 2SO 4·2H 2O 2·NaCl adduct ; tertiary amine oxides ; hydrazine hydrate ; dihydroxy benzene ; quaternary ammonium salts hydrogen peroxide ; methylethyl ketone oxim

无机化学；过氧化氢；综述；过碳酸钠；过碳酰胺； 4Na2SO4·2H2O2·NaCl加合物；叔胺氧化物；水合肼；二羟基苯；季铵盐过氧化氢；甲乙酮肟；合成；催化剂；质量；安定性；收率

The total synthese three natural compounds to explore enantioselective synthesis of flavanol: We use phloroglucin and 2, 4, 6-trihydroxyacetophone as starting materials to synthesis distenin in two ways; Resorcin was used to synthsis 2, 5-dimethoxymethoxyacetophone though 3 steps.

对黄烷醇化合物的立体选择性全合成进行了探索：以间苯三酚和2，4，6-三羟基苯乙酮为原料，尝试用两条路线对Distenin化合物进行了全合成研究；以对苯二酚为原料，经三步制得2，5-二甲氧甲氧基苯乙酮，与2，4，6-三甲氧甲氧基苯甲醛反应，经四步反应得到天然产物3，5，7，2′，5′-二五羟基黄烷关键中间体1-（2′，6′-二甲氧甲氧基苯）-3-（2&，4&，6-三甲氧甲氧基苯）丙烷-1R，2R-二醇83及其对映体84；简要介绍了EGCg类化合物的生物活性和研究概况。

A synthesis method of 2-(2'-hydroxyl-4'-benzoyloxy-phenyl)-2H-benzotriazole and derivatives thereof is provided, and is characterized in that 2-(2', 4'-dihydroxyphenyl)-5-X-2H-benzotriazole and benzoyl chloride are taken as raw materials for reaction in solvent for 1-8 hours under the temperature of 50-140 DEC C with the mole ratio of 1 to 0.95-1.1, wherein, the amount of the solvent is 2 to 20 times that of the 2-(2', 4'-dihydroxyphenyl)-5-X-2H-benzotriazole and X represents H, F, Cl, Br.

一种2-(2′-羟基-4′-苯甲酸基苯基)-2H-苯并三唑及其衍生物的合成方法，其特征是，以2-(2′，4′-二羟基苯基)-5-X-2H-苯并三唑和苯甲酰氯为原料，在溶剂中进行反应，反应温度50℃～140℃，反应时间1～8小时，反应原料摩尔比2-(2′，4′-二羟基苯基)-5-X-2H-苯并三唑∶苯甲酰氯为1∶0.95～1.1，溶剂用量为2-(2′，4′-二羟基苯基)-5-X-2H-苯并三唑重量的2～20倍，其中X代表H、F、Cl、Br，具有反应条件温和、反应收率高和产物纯度高的特点。

They are 2,7-dihydroxy-1,5,6-trimethoxy-9,10-phenanthrene,p-hydroxy phenyl aldehyde, 4-Hydroxybenzyl alcohol, Protocatechuic aldehyde, Gastrodin, 4,4'-Dihydroxydiphenylmethane,4-(4-(hydroxym-ethyl)phenoxymethylphenol,Isorhamnetin-3-O-glucoside,Isorhamnetin-3,7-di-O–glucoside, Imbricatin,2,3-dihydroxy-7-methoxy-9,10-dihydrophenanthropyrone, Cyclopholidone,Cyclopholidonol and β-daucosterol.

分别为：2，7-二羟基-1，5，6-三甲氧基-9，10-二氢菲，对羟基苯甲醛、天麻苷元、原儿茶醛、天麻素、4-（4-羟基-苄基）苯酚、4(4-苯氧基甲基苯酚、异鼠李素-3-O-葡萄糖苷、异鼠李素-3-O-7-O-二葡萄糖苷、Imbricatin、2，7-二羟基-3-甲氧基-9，10-二氢菲吡喃酮、Cyclopholidone、Cyclopholidonol和β-胡萝卜苷。

Firstly, phenyliodine diacetate was immobilized to the 2% cross-linked polystyrene or the liner polystyrene resin. The more iodine the resin had, the lower conversion to phenyliodine diacetate. We made our endeavor to extend the range of useful application of polystyrene supported phenyliodine diacetate in organic synthesis:(1) the reagent was used as an effective reagent of carbonyl regeneration from oximes and semicarbazones of ketones.(2) the reagent was also applied to the synthesis of 1, 3, 4-oxadiazoles, 1, 3-disubstituted-2-pyrazoline, 2-arylbenzoxazole from aldehyde N-acylhydrazones, aldehyde hydoazones and phenolic Schiff's bases respectively.

首先，我们以2％交联的聚苯乙烯和线性的聚苯乙烯树脂为载体，制备了聚合物负载的二醋酸碘苯，通过研究发现：(1)聚苯乙烯二醋酸碘苯是酮肟、缩氨脲有效的去保护试剂，不仅芳香酮，脂肪酮和α，β不饱和酮的肟、缩氨脲也能顺利转化为相应的酮，实现酮基的再生；(2)我们还利用此试剂，分别与醛的N-酰基苯、N-酰基苯腙及邻羟基芳亚胺反应，在温和的条件下发生成环反应，以良好的产率生成1，3，4-噁二唑、吡唑啉和二取代苯并噁唑等杂环化合物；(3)聚苯乙烯二醋酸碘苯还可有效地将邻羟基芳酮的酰腙经氧化、重排成1，2-二酰基苯。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。