二羟基苯

The new methods to synthesize 6-hydroxy-3, 8-dioxabicyclo[3.2.1]octane, dihydrobenzofuran and benzofuran derivatives are described in this thesis.

本文主要论述了(5R)-6-羟基-3，8-二氧二环[3.2.1]辛烷，苯并二氢呋喃和苯并呋喃类衍生物的合成新方法。

In the precence of the base catalyst KF/Al2O3, the one - pot reaction of 2 -hydroxybenzaldehyde or 2 - hydroxynaphthaldehyde with ethyl α- bromoacetate,α-bromoacetophenone , 1,4 - dichloromethylbenzene , 4,4'- dichloromethylbiphenyl and 1,5 -dichloromethylnaphthalene gave the benzofuran compounds in 38-89% yield.

本文报道用 KF/Al_2O_3作为碱催化剂，由水杨醛或2-羟基-1-萘醛分别和α-溴代乙酸酯、α-溴代苯乙酮、苄基氯、4，4'-二氯甲基联苯和1，5-二氯甲基萘等进行一锅化缩合反应，以38～89％的产率合成了14种芳并呋喃化合物。

Ethyl 4-[(1-hydroxy-1-methyl)ethyl]-2-propyl-1H-imidazole-5-carboxylate,the key intermediate of Olmesartan ,was synthesized from butanoic acid and o-phenylenediamine via condensation under microwave-irradiation,oxidation,esterification and the Gringard reaction.

用正丁酸与邻苯二胺为原料，在微波照射下缩合成2-丙基苯并咪唑，再氧化开环制得2-丙基咪唑二羧酸，再经酯化、Gringard反应制得抗高血压药物奥美沙坦的关键中间体2-丙基-4-[(1-羟基-1-甲基)乙基]-1H-咪唑-5-羧酸乙酯，总收率32.2%。

In the presence of O〓, peroxyl radicals formed under neutral condition are either directly oxidized to non-aromatic acids, or forms aromatic intermediates, which are further oxidized to non-aromatic acids; peroxyl radicals formed under alkaline conditions are directly oxidized to non-aromatic acids.

有氧状态下的羟基自由基氧化体系中，过氧自由基在氧气的催化作用下既可开环形成有机酸，也可形成4-氯邻苯二酚和对苯二酚，进而氧化开环成有机酸，并最终矿化；碱性条件下的过氧自由基则直接开环降解。

Two new active esters of acrylic acids monomers, N-p-acryloxybenzoyloxy succini-mide and N-p-methacryloxybenzoyloxy succinimide have been synthesized and polymerized.ABOSu and MBOSu were prepared by coupling of p-acryloxybenzoic acid or p-methacryloxybenzoie acid with N-hydroxy succinimide in the presence of dicyclohexylcarbodimide.

新的丙烯酸活性酯，N-(对甲基丙烯酰氧苯甲酰氧基)丁二酰亚胺及N-丁二酰亚胺单体分别由对甲基丙烯酰氧基苯甲酸、对丙烯酰氧基苯甲酸与N-羟基丁二酰亚胺在环已基羰二亚胺存在下经偶联反应合成。

The aromatizing agent is prepared with ethanol, propanediol, triethanolamine, trichlorohydrocarbon diphenyl ether, biphenyl benzylazole, essence and additive and through certain technological process.

该清馨剂由乙醇、丙二醇、三乙醇胺、三氯羟基二苯醚、联苯苄唑、香精及附加剂所组成，经相应的生产工艺而制成。

Diamino-dipenylamine-2-sulfonicacid was used as an alternative of benzidine,and reacted withl-hy droxy-8-aminonaphthalene-3,6-dusuifonicacid,m-benzioc-diamine and aniline to synthesize eco-friendly black direct dye s.

报道了以4，4'-酸(4，4'-二氨基-二苯胺-2-磺酸)代替联苯胺，与H酸(1-羟基-8-氨基-3，6-二萘磺酸)、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

The environmental black direct dye stuff without carcinogensis was prepared by 4,4'-diamino-dibenzidine-2-sulfonicacid,1-hydroxy-7-aminonaphthalene-3,6-dusuifonicacid,m-benzoic-diamine and aniline.

以4，4'-二氨基-二苯胺-2-磺酸代替苯胺，与1-羟基-7-氨基-3，6-二萘磺酸、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

The environmental black direct dyestuff without carcinogensis was prepared by 4,4＇- diamino - dibenzidine - 2 - sulfonicacid, 1 - hydroxy - 7 - aminonaphthalene - 3,6 - dusuifonicacid, m - benzoic - diamine and aniline.

以4，4'-二氨基-二苯胺-2-磺酸代替苯胺，与1-羟基-7-氨基-3，6-二萘磺酸、间苯二胺、苯胺等合成无致癌作用的环保型黑色直接染料。

Kinetics of hydroxyl-terminated polybutadiene/ phenyl isocyanate, bonding agent (BA-5)/PI and antioxidant H/PI were studied in toluene/dimethyl sulphoxide solution. The rate constants and the activation parameters were calculated. The results show that the reactionary rate of these three active hydrogen components decreased in same condition.

分别对端羟基聚丁二烯/苯异氰酸酯，键合剂(BA-5)/PI和防老剂H（N，N'-二苯基对苯二胺）／PI在甲苯／二甲基亚砜混合溶液体系中进行了反应动力学研究，计算了相应体系的反应速率和活化能。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐