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Urethane adduct was synthesized from decarboxylated cashew nut shell liquid,hexamethylenediisocynate and polyethylglycol,which was then reacted with melamineformaldehyde resin to form aqueous coating material.

采用天然植物油、己二异氰酸酯和聚乙二醇在较温和的条件下反应,制得了水溶性的氨基甲酸酯加成物,以此和低醚化度甲醚化三聚氰氨甲醚甲醛树脂制备了水性涂料。

In this dissertation, two derivatives of aniline containing polyoxyethylene substituent m-phenylene diamino formyl alkylenediamine poly acetate and poly-3-aminobenzoate were designed and synthesized. And then, comb-shaped polyaniline grafted by PEO were prepared by chemical oxidation copolymerization. The structure of copolymers were characterized by FTIR, ultraviolet-visible spectrum, elemental analysis and TEM etc..

本文在设计并合成两种含聚氧乙烯取代基的苯胺衍生物——间苯二氨基甲酰己二氨基甲酸聚氧乙烯乙酸酯和3-聚氧化乙烯单甲醚基苯胺的基础上,采用化学氧化法将它们与苯胺进行共聚,制备出了聚氧乙烯接枝聚苯胺的梳型共聚物。

Using ethylenediamine, urea, methanal and formic acid as base material, 1, 3-dimethyl-2-imidazolidinone was prepared via cyclization reaction and methylation.

以乙二胺、尿素、甲醛和甲酸为原料,经过环化和甲基化反应制得目标产物1,3-二甲基-2-咪唑啉酮(1,3-DMI)。

Methylene bis is an ashless antioxidation and EP additive for lubricant.

亚甲基双二烷基二硫代氨基甲酸酯为无灰型润滑油抗氧和极压多功能添加剂。

Ethoxycarbonyl-4,5-dimethyl-pyrrole (7) was prepared from ethylacetoacetate, ethyl formate and methyl ethyl ketone via oximination, Claisen condensation, and reductive condensation. The bromization of compound 7 gave 2-ethoxycarbonyl-3-bromo-4,5-dimethyl-pyrrole(8), which could be transferred to 2-ethoxy-carbonyl-3-brome-4-methyl-5-formyl-pyrrole (9) by the formolation.

由乙酰乙酸乙酯、甲酸乙酯及丁酮等原料经过肟化、Claisen缩合、还原缩合成环得到2-乙氧羰基-4,5-二甲基-吡咯(7),溴化生成2-乙氧羰基-3-溴4,5-二甲基-吡咯(8),最后经过甲酰化反应得到目标产物2-乙氧羰基-3-溴-4-甲基-5-甲酰基-吡咯(9)。

To investigate the relationships between the tolerance difference to high temperature stress and superoxide dismutases in different cultivars of Celosia cristata, ten-leaf stage seedlings of the heat-tolerant cultivar, Century Green and the heat-sensitive cultivar, Century copper were pulsed for 48 h with diethyldithiocarbamate pretreatment and subjected to high temperature stress under controlled conditions of relative humidity of 75%~90%, 12 h/24 h photoperiod with 1 500 lx and 45 ℃, to research the changes of external morphology and interior physiology.

李永红;魏玉香深圳职业技术学院应用化学与生物技术学院,深圳 518055摘要为研究鸡冠花品种间耐热差异与超氧化物歧化酶之间的关联,选用鸡冠花耐热品种世纪绿叶和热敏品种世纪铜叶的10叶期幼苗为试材,用二乙基二硫代氨基甲酸钠进行48 h预处理之后,在45 ℃、相对湿度75%~90%,、光照1 500 1x (12 h/d)条件下进行热胁迫处理,研究其形态和生理生化的变化。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物,通过2-氨基-5-(3-吡啶基)-1,3,4-噻二唑与酰基叠氮化物反应,设计合成了7个新的N-[5-(3-吡啶基)-1,3,4-噻二唑-2-基]-N'-取代苯基脲,其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

The silk-protein-like polymers could be dissolved in hexafluroisopropanol and strong organic acid (e. g., formic acid, dichloroacetic acid and trifluroacetic acid), while they showed a poor solubility in common solvents.

所合成的模拟聚合物难溶于通常溶剂,但可以溶解在强酸溶剂(甲酸、二氯乙酸及三氟乙酸)和六氟异丙醇中;通过在二氯乙酸中25℃下的特性粘度测定而估算出聚合物的分子量在2~5万之间。

A method for the preparation of microcellular elastomeric polyurethane foams from a reaction mixture comprising a polyisocyanate component containing at least 85% by weight of 4,4'-diphenylmethane diisocyanate or a variant thereof, a polyol composition comprising at least one polyoxyalkylene polyol having an average nominal hydroxyl functionality of from 2 to 6, an average hydroxyl equivalent weight of at least 1300 and an average oxyethylene content of between 50 and 85% by weight, water, a chain extender having an average hydroxyl equivalent weight of from 15 to 250 and optionally a crosslinking agent, the hardblock-content being more than 45% by weight.

本发明是有关一种制备微孔弹性聚氨基甲酸酯泡沫体的方法,其反应混合物包括:一种含至少85重量%的4,4′-二苯甲烷二异氰酸酯或其变体的聚异氰酸酯组分,一种多元醇组合物,其包含至少一种平均标称羟基官能度从2至6、平均羟基当量至少1300且平均氧乙烯含量介于50至85重量%之间的聚氧亚烷基多元醇,水,一种平均羟基当量为15至250之增链剂,以及视需要使用的交联剂,该硬性嵌段-含量(hardblock-content)大于45重量%。

The isocyanate-terminated polyurethane prepolymer was also synthesized form polytetramethylene glycol and 4,4'-diphenylmethane diisocyanate in N,N-Dimethylformamide.

另外,将聚醚双醇与量之4,4'-二苯甲基二异氰酸酯行预聚合反应,形成具-NCO末端基之聚氨基甲酸酯预聚合体。

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