二甲酸

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用"一勺烩"方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

In result, formic, acetic, methanesulfonic, oxalic, malonic, succinic and glutaric acids were detected notably. Formic, acetic and oxalic acids were the most abundant organic acids, and the sum of their concentrations averagely accounted for 89% of the total detected organic acids and 13% of the total anions, respectively.

结果表明，甲酸、乙酸、甲磺酸、乙二酸、丙二酸、丁二酸、戊二酸均有不同程度检出，一元有机酸中甲酸和乙酸在每场降水中均有检出；二元有机酸中，乙二酸和丁二酸检出率很高，其他有机酸检出率较低。

Five of their single crystals were obtained and their structures were determined by X-ray diffraction. By comparison, it was found that dithiocabamate complexes often formed an exactly planar MS4 unit, such as [Mo(R2dtc)2]; and also formed a special MS 5 unit, such as [Cu2(R2dtc)4], the copper atom lies in a distorted square-pyramidal environment.Four kinds of heteropoly acids were prepared and characterized; a series of solid superacid catalyst of supported heteropoly acid were prepared and characterized; regioselectivites of chlorobenzene mononitration with nitric acid with different heteropoly acid on different supports and reaction conditions have been investigated.

培养并解析了5个该类配合物的单晶结构，通过比较，发现二硫代氨基甲酸盐与过渡金属容易形成四配位结构，金属原子与4个硫原子共平面，比如二乙基二硫代氨基甲酸钼；也能形成比较特殊的五配位结构，比如二乙基二硫代氨基甲酸双核铜，Cu原子与5个S原子相连，处于一个变形的四方锥结构的配位环境。

Two new kind of energy transfer donor-acceptor dyads consisting of α-naphthoic acid moiety and 9-aminoacridine units linked by tetraethylene glycol or triethylene glycol flexible chain have been synthesized.

本工作分别用聚三乙二醇及聚四乙二醇柔性链将α-萘甲酸酯与9-氨基吖啶连接起来，合成了两种新型二元发色团分子体系，在两个体系中，选择激发α-萘甲酸酯，都可以发生从α-萘甲酸酯到9-氨基吖啶的高效率的单重态-单重态能量传递。

Tgs are about 573 K for copolyimides based on pyromellitic dianhydride and 533—543 K for those based on 3,3′,4,4′-diphenylethertetra-carboxylic dianhydride and are almost independent of the chromophore loading level.

以刚性相对较大的均苯四甲酸二酐为二酐单体的PPI 的Tg在573 K左右；以二苯醚-3，3′，4，4′-四甲酸二酐为单体的OPI 的Tg在533～543 K之间，且基本与染料发色团含量无关。

It is necessary to carry out a thorough study on pest control technology with DMDS, with an expectation of obtaining a new fumigant of methyl bromide alternative.2. Investigation of the toxicity of fumigation on adult and mixed stages of the three most tolerant insect species -- Sitophilus oryzae, Rhyzopertha dominica and Tribolium castaneum -- under a range of EtF、DMS and DMDS doses in a Flow-through Fumigation System shows that the FTFS procedure offers a constant concentration of fumigant with low CO2 concentrations and ensures that the fumigant toxicity is effectively not compromised by CO2. In comparison with chamber fumigation method, the toxicity data of EtF、DMS and DMDS obtained from this experiment is more accurate by using FTFS.

主要研究结果如下：1、甲酸乙酯和二甲基二硫对仓储害虫具有良好的控制作用，应加快甲酸乙酯替代溴甲烷防治仓储害虫开发应用，同时，二甲基二硫是很有潜力的仓储害虫防治熏蒸剂，要深入进行二甲基二硫控制有害生物的技术研究，以期获得新的溴甲烷替代熏蒸剂。2、利用循环熏蒸系统测定了甲酸乙酯、二甲基二硫和甲硫醚对米象Sitophilus oryzaeL。

A four-ball tester was used to evaluate the load carrying and antiwear properties of bismuth dibutyldithiocarbamate,bis-dibutyldithiocarbamates(V7723),sulfurized isobutylene,molybdenum ester non sulfur and phosphorus in a mineral oil respectively and their synergistic effects.

利用四球试验机评价了二丁基二硫代氨基甲酸铋与二丁基二硫代氨基甲酸酯(V7723)、硫化异丁烯和非硫磷钼酸酯添加剂的极压和抗磨性能，以及它们之间的极压和抗磨协同作用。

The main contents and conclusions are as follows:(1) Synthesis of 1,6-hexamethylenedicarbamate catalyzed by yttrium nitrate Yttrium nitrate was employed as the catalyst in the synthesis of 1,6-hexamethylenedicarbamate from alkyl carbamates.

主要内容和结论如下：(1)硝酸钇为催化剂合成1，6-己二氨基甲酸酯采用硝酸钇作为小分子氨基甲酸烷基酯和1，6-己二胺合成1，6-己二氨基甲酸酯的催化剂。

Zinc diamyl dithiocarbamate antioxidant showed good synergism with antimony diakyl dithiocarbamate antiwear additive in improving the oxidation stability of modified soybean oils. The incipient oxidation temperature and induction period time of genetically modified soybean oils were improved significantly by adding polyalphaolefin and additives, and they were even better than that of the synthetic base oil PAO with the same additive formulation.

结果表明，改性大豆油的不饱和脂肪酸含量越高，其氧化安定性越差；抗氧剂二戊基二硫代氨基甲酸锌和抗磨剂二烷基二硫代氨基甲酸锑在改性大豆油中均表现出了良好的抗氧协同性能，尤其在基因改性大豆油中，聚-α-烯烃和添加剂的复配使其起始氧化温度和氧化诱导时间均超过了相同配方的聚-α-烯烃油样。

German Research Association, said a press release issued a few days ago, the association funded the University of Nuremberg, Germany Erlanger special studies have shown that men the world over the past few decades to reduce the number of sperm may be related to light in a wide range of chemicals used as softeners o of the acid esters.

德国研究协会日前发布的新闻公报说，该协会资助德国厄兰格·纽伦堡大学进行的专项研究表明，过去几十年全球男性精子数量的减少可能与轻工业中广泛用作软化剂的化学品邻苯二甲酸酯有关。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。